Arkansas Cotton Variety Test 2008

The primary goal of the Arkansas Cotton Variety Test is to provide unbiased data regarding the agronomic performance of cotton varieties and advanced breeding lines in the major cotton-growing areas of Arkansas. This information helps seed companies establish marketing strategies and assists producers in choosing varieties to plant

Arkansas Cotton Variety Test 2007

The primary goal of the Arkansas Cotton Variety Test is to provide unbiased data regarding the agronomic performance of cotton varieties and advanced breeding lines in the major cotton-growing areas of Arkansas. This information helps seed companies establish marketing strategies and assists producers in choosing varieties to plant

Conditional evolution in single-atom cavity QED

We consider a typical setup of cavity QED consisting of a two-level atom interacting strongly with a single resonant electromagnetic field mode inside a cavity. The cavity is resonantly driven and the output undergoes continuous homodyne measurements. We derive an explicit expression for the state of the system conditional on a discrete photocount record. This expression takes a particularly simple form if the system is initially in the steady state. As a byproduct, we derive a general formula for the steady state that had been conjectured before in the strong driving limit.Comment: 15 pages, 1 postscript figure, added discussion of mode

Surface spin-flop phases and bulk discommensurations in antiferromagnets

Phase diagrams as a function of anisotropy D and magnetic field H are obtained for discommensurations and surface states for a model antiferromagnet in which $H$ is parallel to the easy axis. The surface spin-flop phase exists for all $D$. We show that there is a region where the penetration length of the surface spin-flop phase diverges. Introducing a discommensuration of even length then becomes preferable to reconstructing the surface. The results are used to clarify and correct previous studies in which discommensurations have been confused with genuine surface spin-flop states.Comment: 4 pages, RevTeX, 2 Postscript figure

A convenient method for the generation of {Rh(PNP)}+ and {Rh(PONOP)}+ fragments : reversible formation of vinylidene derivatives

The substitution reactions of [Rh(COD)2][BArF4] with PNP and PONOP pincer ligands 2,6-bis(di-tert-butylphosphinomethyl)pyridine and 2,6-bis(di-tert-butylphosphinito)pyridine in the weakly coordinating solvent 1,2-F2C6H4 are shown to be an operationally simple method for the generation of reactive formally 14 VE rhodium(I) adducts in solution. Application of this methodology enables synthesis of known adducts of CO, N2, H2, previously unknown water complexes, and novel vinylidene derivatives [Rh(pincer)(CCHR)][BArF4] (R = tBu, 3,5-tBu2C6H3), through reversible reactions with terminal alkynes

Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands

The synthesis of macrocyclic variants of commonly employed phosphine-based pincer ligands derived from lutidine (PNP-14) and 2,6-dihydroxypyridine (PONOP-14) is described, where the P-donors are trans-substituted with a tetradecamethylene linker. This was accomplished using an eight-step procedure involving borane protection, ring-closing olefin metathesis, chromatographic separation from the cis-substituted diastereomers, and borane deprotection. The rhodium coordination chemistry of these ligands has been explored, aided by the facile synthesis of 2,2′-biphenyl (biph) adducts [Rh(PNP-14)(biph)][BArF4] and [Rh(PONOP-14)(biph)][BArF4] (ArF = 3,5-(CF3)2C6H3). Subsequent hydrogenolysis enabled generation of dihydrogen, ethylene and carbonyl derivatives; notably the ν(CO) bands of the carbonyl complexes provide a means to compare the donor properties of the new pincer ligands with established acyclic congeners

Identification of a novel retroviral gene unique to human immunodeficiency virus type 2 and simian immunodeficiency virus SIVMAC

Human and simian immunodeficiency-associated retroviruses are extraordinarily complex, containing at least five genes, tat, art, sor, R, and 3' orf, in addition to the structural genes gag, pol, and env. Recently, nucleotide sequence analysis of human immunodeficiency virus type 2 (HIV-2) and simian immunodeficiency virus SIVMAC revealed the existence of still another open reading frame, termed X, which is highly conserved between these two viruses but absent from HIV-1. In this report, we demonstrate for the first time that the X open reading frame represents a functional retroviral gene in both HIV-2 and SIVMAC and that it encodes a virion-associated protein of 14 and 12 kilodaltons, respectively. We also describe the production of recombinant TrpE/X fusion proteins in Escherichia coli and show that sera from some HIV-2-infected individuals specifically recognize these proteins

Collective Sideband Cooling in an Optical Ring Cavity

We propose a cavity based laser cooling and trapping scheme, providing tight confinement and cooling to very low temperatures, without degradation at high particle densities. A bidirectionally pumped ring cavity builds up a resonantly enhanced optical standing wave which acts to confine polarizable particles in deep potential wells. The particle localization yields a coupling of the degenerate travelling wave modes via coherent photon redistribution. This induces a splitting of the cavity resonances with a high frequency component, that is tuned to the anti-Stokes Raman sideband of the particles oscillating in the potential wells, yielding cooling due to excess anti-Stokes scattering. Tight confinement in the optical lattice together with the prediction, that more than 50% of the trapped particles can be cooled into the motional ground state, promise high phase space densities.Comment: 4 pages, 1 figur

Reactions of Rh(PNP) pincer complexes with terminal alkynes : homocoupling through a ring or not at all

Through use of a bespoke macrocyclic variant, we demonstrate a novel approach for tuning the reactivity of rhodium PNP pincer complexes that enables formation of conjugated enynes from terminal alkynes, rather than vinylidene derivates. This concept is illustrated using tert-butylacetylene as the substrate and rationalised by a ring-induced switch in mechanism

Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand

Having recently reported on the synthesis and rhodium complexes of the novel macrocyclic pincer ligand PNP-14, which is derived from lutidine and features terminal phosphine donors trans-substituted with a tetradecamethylene linker (Dalton Trans., 2020, 49, 2077–2086 and Dalton Trans., 2020, 49, 16649–16652), we herein describe our findings critically examining the chemistry of iridium homologues. The five-coordinate iridium(I) and iridium(III) complexes [Ir(PNP-14)(η2:η2-cyclooctadiene)][BArF4] and [Ir(PNP-14)(2,2′-biphenyl)][BArF4] are readily prepared and shown to be effective precursors for the generation of iridium(III) dihydride dihydrogen, iridium(I) bis(ethylene), and iridium(I) carbonyl derivatives that highlight important periodic trends by comparison to rhodium counterparts. Reaction of [Ir(PNP-14)H2(H2)][BArF4] with 3,3-dimethylbutene induced triple C–H bond activation of the methylene chain, yielding an iridium(III) allyl hydride derivative [Ir(PNP-14*)H][BArF4], whilst catalytic homocoupling of 3,3-dimethylbutyne into Z-tBuC[triple bond, length as m-dash]CCHCHtBu could be promoted at RT by [Ir(PNP-14)(η2:η2-cyclooctadiene)][BArF4] (TOFinitial = 28 h−1). The mechanism of the latter is proposed to involve formation and direct reaction of a vinylidene derivative with HC[triple bond, length as m-dash]CtBu outside of the macrocyclic ring and this suggestion is supported experimentally by isolation and crystallographic characterisation of a catalyst deactivation product