452 research outputs found
Reply to the comment of Chudnovsky&Garanin on "Spin relaxation in Mn12-acetate"
Reply to the comment of E.M. Chudnovsky and D.A. Garanin on Europhys. Lett.
46, 692 (1999).Comment: 2 pages, Latex (europhys.sty
Spin tunneling and topological selection rules for integer spins
We present topological interference effects for the tunneling of a single
large spin, which are caused by the symmetry of a general class of magnetic
anisotropies. The interference originates from spin Berry phases associated
with different tunneling paths exposed to the same dynamics. Introducing a
generalized path integral for coherent spin states, we evaluate transition
amplitudes between ground as well as low-lying excited states. We show that
these interference effects lead to topological selection rules and spin-parity
effects for integer spins that agree with quantum selection rules and which
thus provide a generalization of the Kramers degeneracy to integer spins. Our
results apply to the molecular magnets Mn12 and Fe8.Comment: 4 pages, 3 EPS figures, REVTe
Quantum analogue of the spin-flop transition for a spin pair
Quantum (step-like) magnetization curves are studies for a spin pair with
antiferromagnetic coupling in the presence of a magnetic field parallel to the
easy axis of the magnetic anisotropy. The consideration is done both
analytically and numerically for a wide range of the anisotropy constants and
spins up to . Depending on the origin of the anisotropy
(exchange or single-ion), the magnetization curve can demonstrate the jumps
more than unity and the concentration of the unit jumps in a narrow range of
the field. We also point the region of the problem parameters, where the
behavior is quasiclassical for , and where system is substantially
quantum in the limit .Comment: 5 pages, 5 figure
Erythroferrone as a sensitive biomarker to detect stimulation of erythropoiesis.
Erythroferrone (ERFE) is a glycoprotein hormone secreted by erythroblasts in response to erythropoietin stimulation. ERFE suppresses the hepatic synthesis of the master iron-regulatory hormone, hepcidin. The impact of erythropoiesis stimulation on ERFE secretion in humans is poorly understood. This paucity of information is due in part to the lack of available means for ERFE quantification in serum samples. The present study tested a new sensitive sandwich immunoassay for human ERFE. This assay was used to demonstrate that injection of various erythropoiesis stimulating agents (ESAs) increased the blood ERFE levels in healthy volunteers. After exogenous stimulation of erythropoiesis, ERFE increased up to 8-fold with a detection window of 13 days. The impact of one unit of blood withdrawal on erythropoiesis stimulation of ERFE was also tested. ERFE significantly increased after blood withdrawal in subjects injected with both iron and saline solution, suggesting that iron supplementation did not mask the ERFE increase after blood withdrawal. The effects of exercise-induced muscle damage on ERFE was assessed by comparing ERFE levels with creatine kinase levels in samples from subjects with heavy exercise loads, and determined that this was not a confounder. The ERFE assay is a sensitive means to investigate the connection between iron metabolism and erythropoiesis in humans, and to detect ESA abuse in the antidoping field
Dislocation-induced spin tunneling in Mn-12 acetate
Comprehensive theory of quantum spin relaxation in Mn-12 acetate crystals is
developed, that takes into account imperfections of the crystal structure and
is based upon the generalization of the Landau-Zener effect for incoherent
tunneling from excited energy levels. It is shown that linear dislocations at
plausible concentrations provide the transverse anisotropy which is the main
source of tunneling in Mn-12. Local rotations of the easy axis due to
dislocations result in a transverse magnetic field generated by the field
applied along the c-axis of the crystal, which explains the presence of odd
tunneling resonances. Long-range deformations due to dislocations produce a
broad distribution of tunnel splittings. The theory predicts that at subkelvin
temperatures the relaxation curves for different tunneling resonances can be
scaled onto a single master curve. The magnetic relaxation in the thermally
activated regime follows the stretched-exponential law with the exponent
depending on the field, temperature, and concentration of defects.Comment: 17 pages, 14 figures, 1 table, submitted to PR
Spin Tunneling and Phonon-assisted Relaxation in Mn12-acetate
We present a comprehensive theory of the magnetization relaxation in a
Mn12-acetate crystal in the high-temperature regime (T>1 K), which is based on
phonon-assisted spin tunneling induced by quartic magnetic anisotropy and weak
transverse magnetic fields. The overall relaxation rate as function of the
longitudinal magnetic field is calculated and shown to agree well with
experimental data including all resonance peaks measured so far. The Lorentzian
shape of the resonances, which we obtain via a generalized master equation that
includes spin tunneling, is also in good agreement with recent data. We derive
a general formula for the tunnel splitting energy of these resonances. We show
that fourth-order diagonal terms in the Hamiltonian lead to satellite peaks. A
derivation of the effective linewidth of a resonance peak is given and shown to
agree well with experimental data. In addition, previously unknown spin-phonon
coupling constants are calculated explicitly. The values obtained for these
constants and for the sound velocity are also in good agreement with recent
data. We show that the spin relaxation in Mn12-acetate takes place via several
transition paths of comparable weight. These transition paths are expressed in
terms of intermediate relaxation times, which are calculated and which can be
tested experimentally.Comment: 18 pages, 22 EPS figures, REVTe
Quantum tunneling of two coupled single-molecular magnets
Two single-molecule magnets are coupled antiferromagnetically to form a
supramolecule dimer. We study the coupling effect and tunneling process by
means of the numerical exact diagonalization method, and apply them to the
recently synthesized supramoleculer dimer [Mn4]2 The model parameters are
calculated for the dimer based on the tunneling process. The absence of
tunneling at zero field and sweeping rate effect on the step height in the
hysterisis loops are understood very well in this theory.Comment: 4 pages including 3 figure and 1 tabl
Quantum computing with antiferromagnetic spin clusters
We show that a wide range of spin clusters with antiferromagnetic
intracluster exchange interaction allows one to define a qubit. For these spin
cluster qubits, initialization, quantum gate operation, and readout are
possible using the same techniques as for single spins. Quantum gate operation
for the spin cluster qubit does not require control over the intracluster
exchange interaction. Electric and magnetic fields necessary to effect quantum
gates need only be controlled on the length scale of the spin cluster rather
than the scale for a single spin. Here, we calculate the energy gap separating
the logical qubit states from the next excited state and the matrix elements
which determine quantum gate operation times. We discuss spin cluster qubits
formed by one- and two-dimensional arrays of s=1/2 spins as well as clusters
formed by spins s>1/2. We illustrate the advantages of spin cluster qubits for
various suggested implementations of spin qubits and analyze the scaling of
decoherence time with spin cluster size.Comment: 15 pages, 7 figures; minor change
Magnetic Field Effects on the Far-Infrared Absorption in Mn_12-acetate
We report the far-infrared spectra of the molecular nanomagnet Mn_12-acetate
(Mn_12) as a function of temperature (5-300 K) and magnetic field (0-17 T). The
large number of observed vibrational modes is related to the low symmetry of
the molecule, and they are grouped together in clusters. Analysis of the mode
character based on molecular dynamics simulations and model compound studies
shows that all vibrations are complex; motion from a majority of atoms in the
molecule contribute to most modes. Three features involving intramolecular
vibrations of the Mn_12 molecule centered at 284, 306 and 409 cm-1 show changes
with applied magnetic field. The structure near 284 cm displays the
largest deviation with field and is mainly intensity related. A comparison
between the temperature dependent absorption difference spectra, the gradual
low-temperature cluster framework distortion as assessed by neutron diffraction
data, and field dependent absorption difference spectra suggests that this mode
may involve Mn motion in the crown.Comment: 5 pages, 4 figures, PRB accepte
Suppression of Quantum Phase Interference in Molecular Magnets Fe₈ with Dipolar-Dipolar Interaction
Renormalized tunnel splitting with a finite distribution in the biaxial spin
model for molecular magnets is obtained by taking into account the dipolar
interaction of enviromental spins. Oscillation of the resonant tunnel splitting
with a transverse magnetic field along the hard axis is smeared by the finite
distribution which subsequently affects the quantum steps of hysteresis curve
evaluated in terms of the modified Landau-Zener model of spin flipping induced
by the sweeping field. We conclude that the dipolar-dipolar interaction drives
decoherence of quantum tunnelling in molcular magnets Fe₈, which explains
why the quenching points of tunnel spliting between odd and even resonant
tunnelling predcited theoretically were not observed experimentally.Comment: 5 pages including 3 figure and 1 table. To appear in Physical Review
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