An investigation into the availability and role of oxygen gas in gold tailings dams of the Witwatersrand basin with reference to their acid mine drainage potential

The oxygen content of tailings dams around the Witwatersrand Basin was quantitatively measured over a period of 2 months using a multi-level gas sampling device (MLGS) in an attempt to understand the diffusion of oxygen in tailings dams as a result of acid mine drainage. The measured oxygen showed that the diffusion of oxygen in some Witwatersrand tailings dams is up to a depth of 4 m. In some instances the oxygen content in the layer 1m below the tailings surface decreased by a factor of more than 97% compared to the atmospheric content. The findings show that the development of oxidation zones in the tailings dams of Witwatersrand Basin which subsequently leads to acid mine drainage is limited by the amount of available oxygen in the tailings materials

Characterisation of gold tailings dams of the Witwatersrand Basin with reference to their acid mine drainage potential,Johannesburg, South Africa

Factors which play a role in acid mine drainage (AMD) formation were investigated over a period of 12 months. These include climatic, mineralogical, hydrological and oxygen diffusion parameters. The oxygen diffusion data reveal that the flow of oxygen in the Witwatersrand tailings dams is controlled by secondary porosity (i.e. cracks caused by roots on the dam surface). The age of the dam does not have a significant bearing on the extent to which the oxidised zone development and subsequently AMD can progress. Most of these processes take place within the first 3 m of the dams. The amount of rainfall plays a crucial role in determining the extent to which an oxidised zone progresses. The average oxidised zone in the 5 sites is 2.4 m ranging from 2.2 to 3.5 m. Water SA Vol.32 (4) 2006: pp.499-50

The tectonostratigraphy, granitoid geochronology and geological evolution of the Precambrian of southern Ethiopia

Two distinct tectonostratigraphic terranes, separated by repeatedly reactivated deformation zones, are recognised in the Precambrian of southern Ethiopia: (1) granite-gneiss terrane, which is classified into sub-terranes and complexes, and (2) ophioliti

The Mantle Section of Neoproterozoic Ophiolites from the Pan-African Belt, Eastern Desert, Egypt: Tectonomagmatic Evolution, Metamorphism, and Mineralization

The Eastern Desert (ED) Neoproterozoic ophiolites are tectonically important elements of the Arabian–Nubian Shield. Although affected by various degrees of dismemberment, metamorphism, and alteration, almost all of the diagnostic Penrose-type ophiolite components can be found, namely, lower units of serpentinized peridotite tectonite and cumulate ultramafics and upper units of layered and isotropic gabbros, plagiogranites, sheeted dykes and pillow lavas. The contacts between the lower unit (mantle section) and the upper unit (crustal section) were originally magmatic, but in all cases are now disrupted by tectonism. The mantle sections of the ED ophiolites are exposed as folded thrust sheets bearing important and distinctive lithologies of serpentinized peridotites of harzburgite and dunite protoliths with occasional podiform chromitites. The ED ophiolites show a spatial and temporal association with suture zones that indicate fossil subduction zone locations. Multiple episodes of regional metamorphism mostly reached greenschist facies with less common amphibolite facies localities. CO₂-metasomatism resulted in the development of talc–carbonate, listvenite, magnesite, and other carbonate-bearing meta-ultramafic rocks. Geochemical data from the ED serpentinites, despite some confounding effects of hydration and alteration, resemble modern oceanic peridotites. The ED serpentinites show high LOI (≤20 wt%); Mg# mostly higher than 0.89; enrichment of Ni, Cr, and Co; depletion of Al₂O₃ and CaO; and nearly flat, depleted, and unfractionated chondrite-normalized REE patterns. The modal abundance of clinopyroxene is very low if it is present at all. Chromian spinel survived metamorphism and is widely used as the most reliable petrogenetic and geotectonic indicator in the ED ophiolite mantle sections. The high-Cr# (mostly ~0.7) and low-TiO₂ (mostly ≤ 0.1 wt%) characters of chromian spinel indicate a high degree of partial melt extraction (≥30%), which is commonly associated with fore-arc settings and equilibration with boninite-like or high-Mg tholeiite melts. Based on the general petrological characteristics, the ED ophiolitic chromitites are largely similar to Phanerozoic examples that have been attributed to melt–peridotite interaction and subsequent melt mixing in fore-arc settings. The comparison between the ED Neoproterozoic mantle peridotites and Phanerozoic equivalents indicates considerable similarity in tectonomagmatic processes and does not support any major changes in the geothermal regime of subduction zones on Earth since the Neoproterozoic era. The mantle sections of ED ophiolites are worthy targets for mining and exploration, hosting a variety of ores (chromite, gold, and iron/nickel laterites) and industrial minerals (talc, asbestos, and serpentine)