Reduced complexity models for water management and anode purge scheduling in DEA operation of PEMFCs

In this work, the dynamic behavior of Fuel Cell operation under Dead-Ended Anode conditions is shown. A DEA can be fed with dry hydrogen, since water crossing through the membrane is sufficient to humidify the fuel. The reduced requirements for inlet humidification yield a system with lower cost and weight compared to FCs with flow-through or recirculated anodes. The accumulation of water and nitrogen in the anode channel is first observed near the outlet. A stratified pattern develops in the channel where a hydrogen-rich area sits above a depleted region and is stabilized by the effect of gravity. A model is presented which describes the dynamic evolution of a blanketing N2 front in the anode channel and a hydrogen starved region. Understanding, modeling, and predicting the front evolution can reduce the H2 wasted during purges, avoid over drying the membrane, and mitigate degradation associated with hydrogen starved areas

Perfect valley filter in strained graphene with single barrier region

We present a single barrier system to generate pure valley-polarized current in monolayer graphene. A uniaxial strain is applied within the barrier region, which is delineated by localized magnetic field created by ferromagnetic stripes at the regions boundaries. We show that under the condition of matching magnetic field strength, strain potential, and Fermi energy, the transmitted current is composed of only one valley contribution. The desired valley current can transmit with zero reflection while the electrons from the other valley are totally reflected. Thus, the system generates pure valley-polarized current with maximum conductance. The chosen parameters of uniaxial strain and magnetic field are in the range of experimental feasibility, which suggests that the proposed scheme can be realized with current technology

Klein tunneling in Weyl semimetals under the influence of magnetic field

Klein tunneling refers to the absence of normal backscattering of electrons even under the case of high potential barriers. At the barrier interface, the perfect matching of electron and hole wavefunctions enables a unit transmission probability for normally incident electrons. It is theoretically and experimentally well understood in two-dimensional relativistic materials such as graphene. Here we investigate the Klein tunneling effect in Weyl semimetals under the influence of magnetic field induced by anti-symmetric ferromagnetic stripes placed at barrier boundaries. Our results show that the resonance of Fermi wave vector at specific barrier lengths gives rise to perfect transmission rings, i.e., three-dimensional analogue of the so-called magic transmission angles in two-dimensional Dirac semimetals. Besides, the transmission profile can be shifted by application of magnetic field, a property which may be utilized in electro-optic applications. When the applied potential is close to the Fermi level, a particular incident vector can be selected for transmission by tuning the applied magnetic field, thus enabling highly selective transmission of electrons in the bulk of Weyl semimetals. Our analytical and numerical calculations obtained by considering Dirac electrons in three regions and using experimentally feasible parameters can pave the way for relativistic tunneling applications in Weyl semimetals

Nitrogen front evolution in purged polymer electrolyte membrane fuel cell with dead-ended anode

In this paper, we model and experimentally verify the evolution of liquid water and nitrogen fronts along the length of the anode channel in a proton exchange membrane fuel cell operating with a dead-ended anode that is fed by dry hydrogen. The accumulation of inert nitrogen and liquid water in the anode causes a voltage drop, which is recoverable by purging the anode. Experiments were designed to clarify the effect of N-2 blanketing, water plugging of the channels, and flooding of the gas diffusion layer. The observation of each phenomenon is facilitated by simultaneous gas chromatography measurements on samples extracted from the anode channel to measure the nitrogen content and neutron imaging to measure the liquid water distribution. A model of the accumulation is presented, which describes the dynamic evolution of a N-2 blanketing front in the anode channel leading to the development of a hydrogen starved region. The prediction of the voltage drop between purge cycles during nonwater plugging channel conditions is shown. The model is capable of describing both the two-sloped behavior of the voltage decay and the time at which the steeper slope begins by capturing the effect of H-2 concentration loss and the area of the H-2 starved region along the anode channel

Efficient Dual Spin-Valley Filter In Strained Silicene

We propose a highly efficient silicene device for dual spin and valley filtering. The device consists of two different barrier regions: the first is a region under uniaxial strain, with an exchange field induced by adjacent top and bottom magnetic insulators, while the second comprises of two ferromagnetic stripes which produces a delta-function fringe magnetic field, and a gate electrode to modify the electrochemical potential. For the first region, we investigated the effect of the uniaxial strain in inducing angular separation of the two valley spins in momentum-space, and further spin separation by the spin dependent electric potential induced by the exchange field. We then evaluated the delta-function magnetic field and electrochemical potential combination in the second region to yield the transverse displacement for the selection of the requisite spin-valley combination. We demonstrated the optimal conditions in the first barrier to induce a highly anisotropic transmission profile, which enables controllable and efficient filtering (> 90% efficiency) by the second region for all four spin-valley combinations. Based on the analytical results, we predict the feasibility of experimental realization of dual spin-valley silicene-based filtering device.Comment: 10 pages, 3 figure

Strain-controlled valley and spin separation in silicene heterojunctions

We adopt the tight-binding mode-matching method to study the strain effect on silicene heterojunctions. It is found that valley- and spin-dependent separation of electrons cannot be achieved by the electric field only. When a strain and an electric field are simultaneously applied to the central scattering region, not only are the electrons of valleys K and K' separated into two distinct transmission lobes in opposite transverse directions, but the up-spin and down-spin electrons will also move in the two opposite transverse directions. Therefore, one can realize an effective modulation of valley- and spin-dependent transport by changing the amplitude and the stretch direction of the strain. The phenomenon of the strain-induced valley and spin deflection can be exploited for silicene-based valleytronics devices.Comment: 6 pages, 6 figure

Ge/SiGe Quantum Well p-i-n Structures for Uncooled Infrared Bolometers

Cataloged from PDF version of article.The temperature dependence of current is investigated experimentally for silicon–germanium (Si-Ge) multi-quantum-well p-i-n devices on Si substrates as uncooled bolometer active layers. Temperature coefficient of resistance values as high as −5.8%/K are recorded. This value is considerably higher than that of even commercial bolometer materials in addition to being well above the previous efforts based on CMOS compatible materials