Effect of crystal structure and cationic order on phonon modes across ferroelectric phase transformation in Pb(Fe0.5-xScxNb0.5)O3 bulk ceramics

Pb(Fe0.5-xScxNb0.5)O3 [(PFSN) (0 ≤ x ≤ 0.5)] multiferroic relaxors were synthesized and the temperature dependence of phonon modes across ferroelectric to paraelectric transition was studied. With varying Sc content from x = 0 to 0.25 the structure remains monoclinic and with further addition (x = 0.3 - 0.5) the structure transforms into rhombohedral symmetry. Structural refinement studies showed that the change in crystal structure from monoclinic to rhombohedral symmetry involves a volume increment of 34-36%. Associated changes in the tolerance factor (1.024 ≤ t ≤ 0.976) and bond angles were observed. Structure assisted B′-B″ cation ordering was confirmed through the superlattice reflections in selected area electron diffraction (SAED) pattern of Pb(Sc0.5Nb0.5)O3 (x = 0.5). Cation ordering is also evident from the evolution of Pb-O phonon mode in Raman spectra of compositions with rhombohedral symmetry (x ≥ 0.3). The high temperature Raman scattering studies show that the B-localized mode [F1u, ∼250 cm−1] and BO6 octahedral rotational mode [F1g, ∼200 cm−1], both originating from polar nano regions (PNRs) behave like coupled phonon modes in rhombohedral symmetry. However, in monoclinic symmetry they behave independently across the transition. Softening of B localized mode across the transition followed by the hardening for all compositions confirms the diffusive nature of the ferroelectric transformation. The presence of correlation between the B localized and BO6 rotational modes introduces a weak relaxor feature for systems with rhombohedral symmetry in PFSN ceramics, which was confirmed from the macroscopic dielectric studies

Hype or Help? A Longitudinal Field Study of Virtual World Use for Team Collaboration

Despite increasing organizational interest and investment in virtual worlds (VWs), there is a lack of research on the benefits of VWs. When and how does the use of VW systems engender better organizational outcomes than traditional collaborative technologies? This paper investigates the value of VWs for team collaboration. Team collaboration is particularly relevant in studying VWs given the rich interactive nature of VWs and an increasing organizational reliance on virtual teamwork. To understand the value of VW use for team collaboration, we examine the relationship between a team’s disposition toward IT, their general disposition (personality) and VW use in influencing team cohesion and performance. We conducted a field study that compares two collaborative technology systems – one that is based on a traditional desktop metaphor and one that is grounded in the principles of a virtual world. We tracked the use of the systems for one year. We analyzed data at the team level and the results generally support our model, with agreeableness, conscientiousness, extraversion, openness, and computer self-efficacy interacting with time and technology type to positively influence team technology use. We also found that the use of the virtual world system positively influenced the relationship between technology use and team cohesion, which, in turn, predicts team performance. The model explains 57 percent, 21 percent, and 24 percent of the variance in team technology use, team cohesion, and team performance, respectively

A Method for Dynamic Characterization and Response Prediction Using Ground Vibration Test(GVT)Data for Unknown Structures.

The Objective Of This Proposed Work Is To Develop A Reliable Method For Dynamic Characterization And Prediction Of Dynamic Response Of Structures Of Known/Unknown Configurations, By Processing The Free Vibration Data Generated Experimentally From The Ground Vibration Tests (GVT)Of The Prototype Vehicles. The Methodology Would Make Use Of The Measured Dynamic Data In Terms Of Mode Shapes, Natural Frequencies, Modal Damping, Point Impedances Etc.And Generate Modal (Scaled) Stiffness And Inertia Information That Will Be Used For Prediction Of Response Characteristics Of The Prototype Structure . With These Objectives, The Present Work Develops The Mathematical Formulation Of The Method, And Demonstrates Its Reliability By Performing The Experiment On A Simple Cantilever Beam To Determine Its Dynamic Characteristics. Results On Scaled Modal Stiffness And Inertia, Generated Through The Method Using Experimental (GVT) Data Show Excellent Agreement With Those Generated By FE And Analytical Models .It Must Be Noted That A Valid Benchmarking Is Performed With The Condition That The Experimental Procedure Is 'Blind' To The Actual Stiffness And Inertia Distributions As Used In FEM Or Analytical Models . Agreement Of The Predicted Response Of The Structure With That From Direct Experiment And Those From The FE And Analytical Models Indicates That This Method Will Be A Promising Tool To Predict The Dynamic And Aeroelastic Characteristics Of Any Prototype Vehicle In The Future. Once The Reliability Of The Method Is Established,It Can Be Extended To Determine The Dynamic And Aeroelastic Characteristics Of All Aircraft For Which Dynamic Characteristics Are Available From A Ground -; Vibration Test (GVT)

Predicting the Growth of Two-Dimensional Nanostructures

The ability to predict the morphology of crystals formed by chemical reactions is of fundamental importance for the shape-controlled synthesis of nanostructures. Based on the atomistic mechanism for crystal growth under different driving forces, we have developed morphology diagrams to predict regimes for the growth of two-dimensional crystals. By using controlled reactions for crystal growth in the absence of surfactants/capping agents, we demonstrate the validity of this approach for the formation of 2-D structures of Au, Ag, Pt, Pd and hydroxyapatite.Comment: 31 pages, 10 figure

Stable manifolds and homoclinic points near resonances in the restricted three-body problem

The restricted three-body problem describes the motion of a massless particle under the influence of two primaries of masses $1-\mu$ and $\mu$ that circle each other with period equal to $2\pi$. For small $\mu$, a resonant periodic motion of the massless particle in the rotating frame can be described by relatively prime integers $p$ and $q$, if its period around the heavier primary is approximately $2\pi p/q$, and by its approximate eccentricity $e$. We give a method for the formal development of the stable and unstable manifolds associated with these resonant motions. We prove the validity of this formal development and the existence of homoclinic points in the resonant region. In the study of the Kirkwood gaps in the asteroid belt, the separatrices of the averaged equations of the restricted three-body problem are commonly used to derive analytical approximations to the boundaries of the resonances. We use the unaveraged equations to find values of asteroid eccentricity below which these approximations will not hold for the Kirkwood gaps with $q/p$ equal to 2/1, 7/3, 5/2, 3/1, and 4/1. Another application is to the existence of asymmetric librations in the exterior resonances. We give values of asteroid eccentricity below which asymmetric librations will not exist for the 1/7, 1/6, 1/5, 1/4, 1/3, and 1/2 resonances for any $\mu$ however small. But if the eccentricity exceeds these thresholds, asymmetric librations will exist for $\mu$ small enough in the unaveraged restricted three-body problem