Flexible n-i-p thin film silicon solar cells on polyimide foils with textured ZnO:Ga back reflector

In thin film silicon solar cells on opaque substrates in n-i-p deposition sequence where the textured transparent conductive oxide (TCO) layer serves as a back reflector, one can independently optimize the morphology of the TCO layer without compromise on transparency and conductivity of this layer and further adjust the electro-optical properties of the back contact by using additional layers on top of the textured TCO. In the present work, we use this strategy to obtain textured back reflectors for solar cells in n-i-p deposition sequence on non-transparent flexible plastic foils. Gallium doped ZnO (ZnO:Ga) films were deposited on polyimide substrates by DC magnetron sputtering at a temperature of 200 °C. A wet-chemical etching step was performed by dipping the ZnO:Ga covered foil into a diluted HCl solution. The textured ZnO:Ga is then coated with a highly reflective Ag/ZnO double layer. On this back reflector, we develop thin film silicon solar cells with a microcrystalline silicon absorber layer. The current density for the cell with the textured ZnO:Ga layer is ~ 23 mA/cm2, 4 mA/cm2 higher than the one without such layer, and a maximum efficiency of 7.5% is obtained for a 1 cm2 cell.Fundação para a Ciência e a Tecnologia (FCT

Light scattering and trapping in different thin film photovoltaic device

Light trapping in different thin film technologies is investigated in the context of the European integrated project ATHLET since it allows for thinner devices and thus for reduction of costs for absorber material preparation as well as for advanced multi-junction solar cells. In silicon technology, rough interfaces are typically introduced by roughening of substrates, transparent conducting oxides (TCOs) and/or reflectors at the back side to scatter the light into the absorber material. Well known rough TCOs, plasma-textured poly-Si as well as rough Cu(In,Ga)Se2 (CIGS) absorbers are used as source for light scattering in microcrystalline silicon solar cells and compared regarding their surface roughness. The results prove that CIGS and poly silicon solar cells provide efficient light scattering by the surface features of the rough absorber

ZnO based Back Reflectors with a Wide Range of Surface Morphologies for Light Trapping in n-i-p Microcrystalline Silicon Solar Cells

AbstractSurface morphology of ZnO layers with as-deposited thickness between 550 to 1050nm was varied over wide range by changing etching time. The surface morphology of these ZnO layers was measured by atomic force microscopy (AFM) and statistically analyzed in terms of root mean square roughness and the diameter and depth of the craters. The texture-etched ZnO covered with a Ag and ZnO layers were applied into n-i-p μc-Si:H solar cells as back reflectors. The effects of the back reflector morphologies on solar cell performances were investigated. The link between the morphology, the scattering properties of ZnO layers, and the solar cell performance is discussed