Dendritic Core-Shell Macromolecules Soluble in Supercritical Carbon Dioxide

International audienceSupercritical carbon dioxide has found strong interest as a reaction medium recently.1,2 As an alternative to organic solvents, compressed carbon dioxide is toxicologically harmless, nonflammable, inexpensive, and environmentally benign.3 Its accessible critical temperature and pressure (Tc ) 31 °C, Pc ) 7.38 MPa, Fc ) 0.468 g cm-3)4 and the possibility of tuning the solvent-specific properties between the ones of liquid and gas are very attractive

Archaeometrical study of Khmer stoneware from the Angkorian period: Results from the Cerangkor Project

In the area around Angkor, Cambodia, several ceramics kilns dating from the ninth to 15th centuries ce have been discovered since 1995. The technical, typological and compositional characterization of their production has been one of the main goals of the Cerangkor Project. Samples of green‐glazed ‘Kulen‐type' stoneware and non‐ glazed stoneware produced in five kiln sites in the Angkor region were analysed chemically by wavelength‐dispersive X‐ray fluorescence spectrometry (WDS‐XRF) and also petrographically. The data indicate that some workshops used similar raw materials for the same types of ceramics, suggesting the exploitation of the same geological formations in the whole region. Several references groups were established for each type of stoneware offering an important database for future provenance studies of sherds from consumption sites

Particle decoration in super critical fluid to improve the hydrogen sorption cyclability of magnesium

Hydrogen is now one of the potential vectors of energy for the future..

Ba<inf>1−x</inf>Sr<inf>x</inf>TiO<inf>3</inf> (x =0.4) nanoparticles dispersion for 3D integration of decoupling capacitors on glass interposer

International audienc

BaSrTiO nanoparticles dispersion for 3D integration of decoupling capacitors on glass interposer

International audienc

Experiments and simulations of time-dependant phenomena in a hydrothermal oxidiation tubular reactor

The scaling up of a hydrothermal oxidation (HTO) facility depends on the development of simulation tools. In this way, a new approach to simulate the reactor thermal behavior during a nonstationary regime such as the start, stop, or emergency stop of the unit is developed. A numerical procedure of nonstationary temperature profile simulation in the reactor is described in order to predict the reactor thermal behavior. This new model is validated from experimental data obtained with a quasi-adiabatic reactor, which allows one to follow the temperature profile evolution along the reactor during the HTO process. Performances of the numerical procedure are tested with the simulation of three kinds of real nonstationary conditions: facility start, pump defect, and waste concentration dilution..