Surface Characterization of Heterogeneous Catalysts Using Low Energy Ion Scattering Spectroscopy Combined with Electrochemistry

Fundamental studies of heterogeneous catalysis were performed and presented in this dissertation to gain a better understanding of heterogeneous catalytic reactions at a molecular level. Surface science techniques were employed in achieving the goal. Low energy ion scattering spectroscopy (LEISS) is the main surface science technique which will be used in all the studies discussed throughout this dissertation. The main objectives of LEISS measurements are to: 1) obtain the information of surface composition of heterogeneous catalysts from the topmost layer; 2) observe the effects of reaction conditions on the surface composition of heterogeneous catalysts. The surface composition and morphology of Au-Pd clusters bimetallic model catalysts supported on SiO2 were characterized using LEISS, infrared reflection absorption spectroscopy (IRAS), and temperature programmed desorption (TPD). It is observed that relative to the bulk, the surface of the clusters is enriched in Au. Ethylene adsorption and dehydrogenation show a clear structure-reactivity correlation with respect to the structure/composition of these Au-Pd model catalysts. Fundamental studies of heterogeneous catalysis were performed and presented in this dissertation to gain a better understanding of heterogeneous catalytic reactions at a molecular level. Surface science techniques were employed in achieving the goal. Low energy ion scattering spectroscopy (LEISS) is the main surface science technique which will be used in all the studies discussed throughout this dissertation. The main objectives of LEISS measurements are to: 1) obtain the information of surface composition of heterogeneous catalysts from the topmost layer; 2) observe the effects of reaction conditions on the surface composition of heterogeneous catalysts. The surface composition and morphology of Au-Pd clusters bimetallic model catalysts supported on SiO2 were characterized using LEISS, infrared reflection absorption spectroscopy (IRAS), and temperature programmed desorption (TPD). It is observed that relative to the bulk, the surface of the clusters is enriched in Au. Ethylene adsorption and dehydrogenation show a clear structure-reactivity correlation with respect to the structure/composition of these Au-Pd model catalysts

An Electrochemical, Microtopographical and Ambient Pressure X-Ray Photoelectron Spectroscopic Investigation of Si/TiO_2/Ni/Electrolyte Interfaces

The electrical and spectroscopic properties of the TiO_2/Ni protection layer system, which enables stabilization of otherwise corroding photoanodes, have been investigated in contact with electrolyte solutions by scanning-probe microscopy, electrochemistry and in-situ ambient pressure X-ray photoelectron spectroscopy (AP-XPS). Specifically, the energy-band relations of the p+-Si/ALD-TiO_2/Ni interface have been determined for a selected range of Ni thicknesses. AP-XPS measurements using tender X-rays were performed in a three-electrode electrochemical arrangement under potentiostatic control to obtain information from the semiconductor near-surface region, the electrochemical double layer (ECDL) and the electrolyte beyond the ECDL. The degree of conductivity depended on the chemical state of the Ni on the TiO2surface. At low loadings of Ni, the Ni was present primarily as an oxide layer and the samples were not conductive, although the TiO_2 XPS core levels nonetheless displayed behavior indicative of a metal-electrolyte junction. In contrast, as the Ni thickness increased, the Ni phase was primarily metallic and the electrochemical behavior became highly conductive, with the AP-XPS data indicative of a metal-electrolyte junction. Electrochemical and microtopographical methods have been employed to better define the nature of the TiO_2/Ni electrodes and to contextualize the AP-XPS results

Direct observation of the energetics at a semiconductor/liquid junction by operando X-ray photoelectron spectroscopy

Photoelectrochemical (PEC) cells based on semiconductor/liquid interfaces provide a method of converting solar energy to electricity or fuels. Currently, the understanding of semiconductor/liquid interfaces is inferred from experiments and models. Operando ambient-pressure X-ray photoelectron spectroscopy (AP-XPS) has been used herein to directly characterize the semiconductor/liquid junction at room temperature under real-time electrochemical control. X-ray synchrotron radiation in conjunction with AP-XPS has enabled simultaneous monitoring of the solid surface, the solid/electrolyte interface, and the bulk electrolyte of a PEC cell as a function of the applied potential, U. The observed shifts in binding energy with respect to the applied potential have directly revealed ohmic and rectifying junction behavior on metallized and semiconducting samples, respectively. Additionally, the non-linear response of the core level binding energies to changes in the applied electrode potential has revealed the influence of defect-derived electronic states on the Galvani potential across the complete cell

Microemulsion-mediated syntheses of silicalite-1

Due to the character of the original source materials and the nature of batch digitization, quality control issues may be present in this document. Please report any quality issues you encounter to [email protected], referencing the URI of the item.Includes bibliographical references (leaves 83-88).Issued also on microfiche from Lange Micrographics.The cationic microemulsion-mediated synthesis of silicalite-1 has been studied. The focal point of this work is to determine if these microemulsions present a confined space in which zeolite particles of novel morphology can be formed. The phase behavior of the microemulsions has also been determined to help rationalize the results of the zeolite syntheses. The phase behavior studies of the microemulsions indicate that one-phase, optically transparent microemulsions can be formed at 368 K in the presence of linear and branched cationic surfactants, which can solubilize approximately ten weight percent zeolite synthesis mixture. The results from the phase behavior studies were used to guide the zeolite syntheses. The effects of synthesis parameters such as TPAOH content, microemulsion composition, surfactants and temperature on the morphology of silicalite-1 were analyzed. Using microemulsions with branched cationic surfactant at 95° C, silicalite-1 of novel morphology was synthesized. Disc like silicalite-1, around 400 nm in size, was synthesized from microemulsion-mediated syntheses, while spherical crystals of smaller size were synthesized in the absence of the microemulsion. However, when linear cationic surfactant is used, mesoporous silica is synthesized. At higher zeolite contents in the microemulsion, better crystallinity and shape of silicalite-1 were obtained, while at lower zeolite content (less than ten weight percent) amorphous materials were synthesized. By decreasing the TPAOH content, the shape of the crystals synthesized using microemulsion are more disc-like and slightly larger. Silicalite-1 of 400 nm in size was synthesized with zeolite mixture molar composition of 1 TEOS: 0.18 TPAOH: 20 H₂O, while smaller crystals, 200 nm, were observed at higher TPAOH content (above 0.30). Salt has deleterious effect on silicalite-1 formation at 95° C. Mesoporous silica is synthesized when NaCl is added into the synthesis mixture. Finally, our results indicate that the "nanoreactor concept" may not be valid, observed from the studies of mixtures before and after the solids sediment out of the synthesis mixture. Powder diffraction pattern of material extracted from microemulsion after the mixture phase separates indicates that silicalite-1 is synthesized and its FE-SEM image shows ordered shape. However, very poorly crystalline material is synthesized from one-phase synthesis mixtures

Varied Bulk Powder Properties of Micro-Sized API within Size Specifications as a Result of Particle Engineering Methods

Micronized particles are commonly used to improve the content uniformity (CU), dissolution performance, and bioavailability of active pharmaceutical ingredients (API). Different particle engineering routes have been developed to prepare micron-sized API in a specific size range to deliver desirable biopharmaceutical performance. However, such API particles still risk varying bulk powder properties critical to successful manufacturing of quality drug products due to different particle shapes, size distribution, and surface energetics, arising from the anisotropy of API crystals. In this work, we systematically investigated key bulk properties of 10 different batches of Odanacatib prepared through either jet milling or fast precipitation, all of which meet the particle size specification established to ensure equivalent biopharmaceutical performance. However, they exhibited significantly different powder properties, solid-state properties, dissolution, and tablet CU. Among the 10 batches, a directly precipitated sample exhibited overall best performance, considering tabletability, dissolution, and CU. This work highlights the measurable impact of processing route on API properties and the importance of selecting a suitable processing route for preparing fine particles with optimal properties and performance

Observing the Electrochemical Oxidation of Co Metal at the Solid/Liquid Interface Using Ambient Pressure X-ray Photoelectron Spectroscopy.

Recent advances of ambient pressure X-ray photoelectron spectroscopy (AP-XPS) have enabled the chemical composition and the electrical potential profile at a liquid/electrode interface under electrochemical reaction conditions to be directly probed. In this work, we apply this operando technique to study the surface chemical composition evolution on a Co metal electrode in 0.1 M KOH aqueous solution under various electrical biases. It is found that an ∼12.2 nm-thick layer of Co(OH)2 forms at a potential of about -0.4 VAg/AgCl, and upon increasing the anodic potential to about +0.4 VAg/AgCl, this layer is partially oxidized into cobalt oxyhydroxide (CoOOH). A CoOOH/Co(OH)2 mixture layer is formed on the top of the electrode surface. Finally, the oxidized surface layer can be reduced to Co0 at a cathodic potential of -1.35 VAg/Cl. These observations indicate that the ultrathin layer containing cobalt oxyhydroxide is the active phase for oxygen evolution reaction (OER) on a Co electrode in an alkaline electrolyte, consistent with previous studies