Carbon Dioxide Diffuse Emission from the Soil at Vesuvio and Campi Flegrei (Pozzuoli): Ten Years of Observations

Carbon dioxide flux from the soil is regularly monitored in selected areas of Vesuvio and Solfatara (Campi Flegrei, Pozzuoli) with the main aim of investigating if the surface phenomena could provide information about the processes occurring at depth. Surveyed areas include 15 fixed points around the rim of Vesuvio and 71 fixed points in the floor of Solfatara crater, where soil CO2 flux is measured since 1998, at least once a month. In addition, two automatic permanent stations, located at Vesuvio and Solfatara, continually measure the CO2 flux and some environmental parameters that can potentially influence the CO2 diffuse degassing. We analysed, with statistical procedures, the feature of the acquired signals, evaluating the spatial and temporal variations of the CO2 degassing process. Series acquired by continuous stations are characterized by an annual periodicity that is related to the typical periodicities of some meteorological parameters (e.g., air temperature, air humidity, etc.). Such a kind of signal permits to define the “reference” level of the CO2 degassing process that diffusely affects the flanks and the base of the volcanoes. Conversely, series of CO2 flux data arising from periodic measurements over the arrays of Vesuvio and Solfatara, are less dependent on external factors such as meteorological parameters, local soil properties (porosity, hydraulic conductivity) and topographic effects (high or low ground). Therefore we argue that the longterm trend of this signal contains the “best” possible representation of the endogenous signal related to the upflow of deep hydrothermal fluids. At Vesuvio and Solfatara, the variations of these series have shown some correspondence with other physical changes of the volcanic systems

Temperature and pressure gas geoindicators at the Solfatara fumaroles (Campi Flegrei)

Long time series of fluid pressure and temperature within a hydrothermal system feeding the Solfatara fumaroles are investigated here, on the basis of the chemical equilibria within the CO2-H2O-H2-CO gas system. The Pisciarelli fumarole external to Solfatara crater shows an annual cycle of CO contents that indicates the occurrence of shallow secondary processes that mask the deep signals. In contrast, the Bocca Grande and Bocca Nova fumaroles located inside Solfatara crater do not show evidence of secondary processes, and their compositional variations are linked to the temperature–pressure changes within the hydrothermal system. The agreement between geochemical signals and the ground movements of the area (bradyseismic phenomena) suggests a direct relationship between the pressurization process and the ground uplift. Since 2007, the gas geoindicators have indicated pressurization of the system, which is most probably caused by the arrival of deep gases with high CO2 contents in the shallow parts of the hydrothermal system. This pressurization process causes critical conditions in the hydrothermal system, as highlighted by the increase in the fumarole temperature, the opening of new vents, and the localized seismic activity. If the pressurization process continues with time, it is not possible to rule out the occurrence of phreatic explosions

Geochemical monitoring integrated in a real time hydrological network

Hydrological data relative to springs and water wells collected by the Hydrografic National Service in Naples indicate that some anomalies can be correlated with the seismic activity in Southern Apennines. In this paper we report some hydrological anomalies for the November 23, 1980 earthquake and suggest that an improvement of the hydrometeorological network of the Hydrographic National Service can reveal geochemical and hydrological anomalies before the earthquakes

Long time-series of chemical and isotopic compositions of Vesuvius fumaroles: evidence for deep and shallow processes

Long time-series of chemical and isotopic compositions of Vesuvius fumaroles were acquired in the framework of the volcanic surveillance in the 1998-2010 period. These allow the identification of processes that occur at shallow levels in the hydrothermal system, and variations that are induced by deep changes in volcanic activity. Partial condensation processes of fumarolic water under near-discharge conditions can explain the annual 18O and deuterium variabilities that are observed at Vesuvius fumaroles. Significant variations in the chemical compositions of fumaroles occurred over the 1999-2002 period, which accompanied the seismic crisis of autumn 1999, when Vesuvius was affected by the most energetic earthquakes of its last quiescence period. A continuous increase in the relative concentrations of CO2 and He and a general decrease in the CH4 concentrations are interpreted as the consequence of an increment in the relative amount of magmatic fluids in the hydrothermal system. Gas equilibria support this hypothesis, showing a PCO2 peak that culminated in 2002, increasing from values of ~40 bar in 1998 to ~55-60 bar in 2001- 2002. We propose that the seismic crisis of 1999 marked the arrival of the magmatic fluids into the hydrothermal system, which caused the observed geochemical variations that started in 1999 and culminated in 2002

Long Time Series Of Fumarolic Compositions At Volcanoes: The Key To Understand The Activity Of Quiescent Volcanoes

Long time series of fumarolic chemical and isotopic compositions at Campi Flegrei, Vulcano, Panarea, Nisyros and Mammoth volcanoes highlight the occurrence of mixing processes among magmatic and hydrothermal fluids. At Campi Flegrei temperatures of about 360°C of the hydrothermal system are inferred by chemical and isotopic geoindicators. These high temperatures are representative of a deep zone where magmatic gases mix with hydrothermal liquids forming the gas plume feeding the fumaroles. Similar mixing processes between magmatic fluids and a hydrothermal component of marine origin have been recognized at Vulcano high temperature fumaroles. In both the system a typical ‘andesitic’ water type composition and high CO2 contents characterizes the magmatic component. Our hypothesis is that pulsing injections of these CO2- rich magmatic fluids at the bottom of the hydrothermal systems trigger the bradyseismic crises, periodically affecting Campi Flegrei, and the periodical volcanic unrest periods of Vulcano. At Campi Flegrei a strong increase of the fraction of the magmatic component marked the bradyseismic crisis (seismicity and ground uplift) of 1982-84 and four minor episodes occurred in 1989, 1994 and 2000 and 2006. Increases of the magmatic component in the fumaroles of Vulcano were recorded in 1979-1981, 1985, 1988, 1996, 2004 and 2005 concurrently with anomalous seismic activity. Physicalnumerical simulations of the injection of hot, CO2 rich fluids at the base of a hydrothermal system, asses the physical feasibility the process. Ground deformations, gravitational anomalies and seismic crisis can be well explained by the complex fluid dynamic processes caused by magma degassing episodes. Sporadic data on the fumaroles of other volcanoes, for example Panarea, Nisyros (Greece), Mammoth (California), suggest that magma degassing episodes frequently occur in dormant volcanoes causing volcanic unrest processes not necessarily linked to magma movement but rather to pulsating degassing processes from deep pressurized, possibly stationary, magma bodies

One year of geochemical monitoring of groundwater in the Abruzzi region after the 2009 earthquakes.

The presence of a deep and inorganic source of CO2 has been recently recognized in Italy on the basis of the deeply derived carbon dissolved in the groundwater. In particular, the regional map of CO2 Earth degassing shows that two large degassing structures (Tuscan Roman degassing structure, TRDS, and Campanian degassing structure, CDS) affect the Tyrrhenian side of the Italian peninsula. The comparison between the map of CO2 Earth degassing and of the location of the Italian earthquakes highlights that the anomalous CO2 flux suddenly disappears in the Apennine in correspondence of a narrow band where most of the seismicity concentrates. A previous conceptual model proposed that in this area, at the eastern borders of TRDS and CDS, the CO2 from the mantle wedge intrudes the crust and accumulate in structural traps generating over-pressurized reservoirs. These CO2 over-pressurized levels can play a major role in triggering the Apennine earthquakes. The 2009 Abruzzo earthquakes, like previous seismic crises in the Northern Apennine, occurred at the border of the TRDS, suggesting also in this case a possible role played by deeply derived fluids in the earthquake generation. Detailed hydro-geochemical campaigns, with a monthly frequency, started immediately after the main shock of the 6th of April 2009. The new campaigns include the main springs of the area which were previously studied in detail, during a campaign performed ten years ago, constituting a pre-crisis reference case. Almost one year of geochemical data of the main dissolved ions, of dissolved gases (CO2, CH4, N2, Ar, He) and of the stable isotopes of the water (H, O), CO2 (13C) and He (3He/4He), highlight both that the epicentral area of L’Aquila earthquakes is affected by an important process of CO2 Earth degassing and that that the gases dissolved in the groundwater reflects the input in to the aquifers of a deep gas phase, CO2- rich, with an high He content and with low 3He/4He ratios, similar to the gases emitted by natural manifestations located in the northern Apennines which are fed by deep pressurized reservoirs. Furthermore a systematic increase in the content of the deeply derived CO2 dissolved in the aquifers occurred respect to the July 1997 samples. This increase, followed by a gentle decline of the anomaly, can be compatible with the occurrence of an episode of deep CO2 degassing concurrently with the earthquakes. The origin of this regional variation is under investigation and, at the present moment, an unambiguous interpretation of the data is not possible because the lack of a systematic monitoring of the springs before the seismic events and because eventual seasonal effects on observed variation in CO2 flux are still under investigatio

A shallow-layer model for heavy gas dispersion from natural sources: Application and hazard assessment at Caldara di Manziana, Italy

Several nonvolcanic sources in central Italy emit a large amount of carbon dioxide (CO2). Under stable atmospheric conditions and/or in the presence of topographic depressions, the concentration of CO2, which has a molecular mass greater than that of air, can reach high values that are lethal to humans or animals. Several episodes of this phenomenon were recorded in central Italy and elsewhere. In order to validate a model for the dispersion of a heavy gas and to assess the consequent hazard, we applied and tested the code TWODEE-2, an improved version of the established TWODEE model, which is based on a shallow-layer approach that uses depth-averaged variables to describe the flow behavior of dense gas over complex topography. We present results for a vented CO2 release at Caldara di Manziana in central Italy. We find that the model gives reliable results when the input quantity can be properly defined. Moreover, we show that the model can be a useful tool for gas hazard assessment by evaluating where and when lethal concentrations for humans and animals are reached

A GIS-Based Hydrogeological Approach to the Assessment of the Groundwater Circulation in the Ischia Volcanic Island (Italy)

Assessing the variations in space and time of groundwater circulation in volcanic islands is of paramount importance to the description of the hydro-geo-thermal system and implementation of hydrogeological, geochemical, and volcanic monitoring systems. In fact, the reliable reconstruction of the groundwater potentiometric surface in such composite volcanic aquifer systems can enable the identification of the most advantageous strategies for both the sustainable use of groundwater resources and the management of volcanic risk. Geographical Information System (GIS) platforms can support the integration and analysis of many spatial and temporal variables derived from monitoring of active volcanoes and the elaboration of spatially continuous data. However, open issues still affect the reliability and general applicability of common spatial interpolation methods in the case of groundwater potentiometric surfaces. This is related to the assessment of the main stratigraphic and volcano-tectonic features affecting the hydraulic head changes. With regard to the dynamically very active Ischia Island (Italy), this study illustrates a GIS-based hydrogeological approach to identify the most accurate interpolation method for mapping the potentiometric surface in complex hydrogeological terrains. The proposed approach has been applied to the existing dataset (1977–2003) stored by Istituto Nazionale di Geofisica e Vulcanologia. Based on a careful geological and hydrogeological survey, a total of 267 wells, from 5 to 250 m in depth, were processed. The data pre-processing involved four meteorological time-series data (1922–1997) and six long records of piezometric water levels (1930–1994). As a result, knowledge of the delineation of rather homogeneous stratigraphic and volcano-tectonic structures at the basin-scale has improved. Thus, new, more reliable potentiometric surfaces of the four main geothermal areas closest to the coast were produced during both dry and wet seasons. The reliability of the processed potentiometric surface was then validated by comparing the spatially continuous data with complementary field data. These findings point toward an optimal interpolation approach for representing the seasonal and areal distribution of main hydrogeological parameters in complex aquifer systems. Finally, insights into variations of hydrological behavior at an active volcanic area will foster an understanding of possible involvement of fresh and thermal waters in triggering phreatic explosions