1 research outputs found
First Report on the Separation of Trivalent Lanthanides from Trivalent Actinides Using an Aqueous Soluble Multiple N‑Donor Ligand, 2,6-bis(1<i>H</i>‑tetrazol-5-yl)pyridine: Extraction, Spectroscopic, Structural, and Computational Studies
A terdentate
multiple N donor ligand, 2,6-bisÂ(1<i>H</i>-tetrazol-5-yl)Âpyridine
(H<sub>2</sub>BTzP), was synthesized, and its complexation with trivalent
americium, neodymium, and europium was studied using single-crystal
X-ray diffraction, attenuated total reflectance-fourrier transform
infrared spectroscopy, time-resolved fluorescence spectroscopy, UV–vis
absorption spectrophotometry. Higher complexation strength of BTzP
toward trivalent actinide over lanthanides as observed from UV–vis
spectrophotometric study resulted in an effective separation of Am<sup>3+</sup> and Eu<sup>3+</sup> in liquid–liquid extraction studies
employing <i>N,N,<i>N</i>′,N′</i>-tetra-<i>n</i>-octyl diglycolamide in the presence of
BTzP as the aqueous complexant. The selectivity of BTzP toward Am<sup>3+</sup> over Eu<sup>3+</sup> was further investigated by DFT computations,
which indicated higher metal–ligand overlap in the Am<sup>3+</sup> complex as indicated from the metal–nitrogen bond order and
frontier molecular orbital analysis of the BTzP complexes of Am<sup>3+</sup> and Eu<sup>3+</sup>