17 research outputs found

    Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis

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    Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(UI)2(L)], [(NpI)2(L)], and [{U(BH4)}2(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.JRC.E.6-Actinides researc
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