A Gibeon meteorite yields a high-performance water oxidation electrocatalyst

Examining the electrocatalytic performance of naturally-occurring metallic minerals is of interest for energy conversion applications given their unique atomic composition and formation history. Herein, we report the electrocatalytic function of an iron-based Gibeon meteorite for the oxygen evolution reaction (OER). After ageing under operational conditions in an alkaline electrolyte, an activity matching or possibly slightly superior to the best performing OER catalysts emerges, with stable overpotentials as low as 270 mV (for 10 mA cm(-2)) and Tafel slopes of 37 mV decade(-1). The Faradaic efficiency for the OER was unity and no deterioration in performance was detected during 1000 hours of OER operation at 500 mA cm(-2). Mechanistic studies suggest an operando surface modification involving the formation of a 3D oxy(hydroxide) layer with a metal atom composition of Co0.11Fe0.33Ni0.55, as indicated by Raman and XPS studies and trace Ir as indicated via elemental analysis. The growth of the catalyst layer was self-limiting to <200 nm after ca. 300 hours of operation as indicated through XPS depth profiling and cyclic voltammetry. The unique composition and structure of the Gibeon meteorite suggest that further investigation of Ir-Co-Ni-Fe systems or other alloys inspired by natural materials for water oxidation are of interest

Development of heterogeneous catalytic systems for the transformation of carbon dioxide to methanol under mild conditions.

Rising level of carbon dioxide (CO2) is a significant contributor to global warming and poses a major concern in modern society and environment. Anthropogenic activities such as fossil fuel combustion, cement production and deforestation are the primary causes of CO2 emissions. Creating sustainable pathways by converting abundantly available CO2 into fuel could help in mitigating the ever-growing global energy demand. Owing to the high intrinsic thermodynamic stability of CO2 molecule, the chemical reduction mechanism requires an appropriate catalyst system to reduce the high activation energy barrier. Additionally, the prospect of utilising CO2 as C1 synthon to convert the amines to afford value-added formamides is even more appealing. In the present dissertation, the development of efficient industrial friendly heterogeneous catalytic routes for CO2 fixation on amines by chemical reduction method to formamides, as well as their subsequent conversion to fuel, methanol under mild conditions are investigated. The first chapter describes an overview about the current trends in global climate change, about the challenges in CO2 capture and storage, the employment of CO2 as a source of carbon to synthesise industrially essential formamide products by catalytic reduction. Subsequently, the reduction pathway of formamides to afford methanol is also elucidated. Additionally, the prospect of using formic acid (a known CO2 and H2 carrier) to formylate amines and the consequent reduction to methanol is also given. The combination of these reactions presents a viable CO2 reduction system using amines. In the second chapter, N-formylation and N-methylation of amines using CO2 as the carbon source catalysed by palladium nanoparticles (Pd NPs) under mild conditions are discussed. The concluding results point out the high efficiency and high selectivity of Pd NPs in catalysing the amines to fix CO2 to afford formamides at room temperature. The Pd NPs exhibited excellent catalytic activity and selectivity on par with the reported catalysts. The overall selectivity and conversion of the products could be altered by adjusting the CO2 pressure, catalyst loading, temperature and solvent. The catalyst could be recycled for multiple reactions without significant loss of activity. The third chapter describes a âGeo-inspiredâ catalyst system with the use of an iron-rich natural mineral-Gibeon meteorite, as the catalyst for N-formylation and N-methylation of amines using CO2 as the carbon source at room temperature. Similar to the second chapter, the Gibeon meteorite exhibited excellent catalytic activity and selectivity on par with the reported catalysts. The overall selectivity and conversion could be altered by adjusting the CO2 pressure, catalyst loading, temperature and solvent. Comparative studies with the similar iron-containing alloys were also carried out. A plausible mechanism is proposed with the Gibeon meteoriteâs surface bound hydroxide ions. Moreover, the catalyst could be easily recovered and reused for multiple reactions as well without significant loss of activity. The fourth chapter encompasses the investigation of a metal-free catalytic system using polymerisable ionic liquid- (4-Vinylbenzyl)trimethylammonium chloride catalysed N-formylation and N-methylation of amines using CO2 as the carbon source under mild conditions. Similar to second and third chapters, the monomer and the polymer exhibited excellent catalytic activity (comparabl

Soft Approaches to CO2 Activation

The utilization of CO2 as a C1 synthon is becoming increasingly important as a feedstock derived from carbon capture and storage technologies. Herein, we describe some of our recent research on carbon dioxide valorization, notably, using organocatalysts to convert CO2 into carboxylic acid, ester, formyl and methyl groups on various organic molecules. We describe these studies within the broader context of CO2 capture and valorization and suggest approaches for future research

UV-Imprint Resists Generated from Polymerizable Ionic Liquids and Titania Nanoparticles

Ionic liquids incorporating a polymerizable anion were prepared in a facile manner and used to fabricate stable titania nanoparticle films. The nanotitania was directly patterned by UV imprinting using micrometer size test structures in a polydimethylsiloxane mold. The resulting resist microstructures are resistant to cracking with only slight shrinkage observed for the system made using a hydrophobic ionic liquid. Because ionic liquids with a plethora of different physical and chemical properties can be made (designed) in a facile manner their application in this facile process instead of organic solvents could lead to many new types of functional materials

Synthesis of Cross-linked Ionic Poly(styrenes) and their Application as Catalysts for the Synthesis of Carbonates from CO2 and Epoxides

A series of dicationic styrene-functionalized imidazolium-based salts, in which the two imidazolium rings are bridged by a functionalized spacer, are prepared. The salts are polymerized to afford cross-linked imidazolium-based ionic polystyrene materials, which, owing to the presence of the functionalized spaces, should be highly active organocatalysts for the cycloaddition of CO2 to epoxides to afford cyclic carbonates (CCE reaction). The catalytic activities of the polymers are evaluated in the CCE reaction. The most active catalyst incorporates a diol functionality and is active at 80 degrees C and a pressure of 4bar at a loading of 5mol%, which is comparable to the most active organocatalysts. Moreover, high yields can be obtained under atmospheric pressure upon increasing the temperature to 120 degrees C. Under harsher conditions, the catalyst is highly active at a loading one order of magnitude lower, highlighting the importance of benchmark conditions for the CCE reaction. Moreover, the polymer catalysts are advantageous because they can be used at low catalyst loadings, the carbonate product is easily isolated in pure form, and loss of activity of the recovered polymer catalyst is not observed during reuse