Lead-free piezoelectrics: V3+ to V5+ ion conversion promoting the performances of V-doped Zinc Oxide

Vanadium doped ZnO (VZO) thin films were grown by RF magnetron sputtering, starting from a ZnO:V ceramic target. The crystal structure, chemical composition, electric and piezoelectric properties of the films were investigated either on the as-grown thin films or after a post-deposition rapid thermal annealing (RTA) treatment performed at 600 °C for different lengths of time (1 and 5 min) in an oxygen atmosphere. Substitutional doping of Zn2+ with V3+ and V5+ ions strongly deteriorated the hexagonal wurtzite ZnO structure of the as-grown thin films due to lattice distortion. The resulting slight amorphization led to a poor piezoelectric response and higher resistivity. After the RTA treatment, strong c-axis oriented VZO thin films were obtained, together with a partial conversion of the starting V3+ ions into V5+. The improvement of the crystal structure and the stronger polarity of both V3+ – O and V5+ – O chemical bonds, together with the corresponding easier rotation under the application of an external electric field, positively affected the piezoelectric response and increased conductivity. This was confirmed by closed-loop butterfly piezoelectric curves, by a maximum d33 piezoelectric coefficient of 85 pm·V−1, and also by ferroelectric switching domains with a well-defined polarization hysteresis curve, featuring a residual polarization of 12.5 μC∙cm−2

Accelerated Electrons in Cassiopeia A: An Explanation for the Hard X-ray Tail

We propose a model for the hard X-ray (> 10 keV) emission observed from the supernova remnant Cas A. Lower hybrid waves are generated in strong (mG) magnetic fields, generally believed to reside in this remnant, by shocks reflected from density inhomogeneities. These then accelerate electrons to energies of several tens of keV. Around 4% of the x-ray emitting plasma electrons need to be in this accelerated distribution, which extends up to electron velocities of order the electron Alfven speed, and is directled along magnetic field lines. Bremsstrahlung from these electrons produces the observed hard x-ray emission. Such waves and accelerated electrons have been observed in situ at Comet Halley, and we discuss the viability of the extrapolation from this case to the parameters relevant to Cas A.Comment: 20 pages, 3 figures, aasTeX502, accepted in Ap

Near-Infrared Synchrotron Emission from Cas A

High energy observations of Cas A suggested the presence of synchrotron radiation, implying acceleration of cosmic rays by young supernova remnants. We detect synchrotron emission from Cas A in the near-infrared using Two Micron All Sky Survey (2MASS) and Palomar 200 inch PFIRCAM observations. The remnant is detected in J, H, and Ks bands, with Ks band brightest and J faint. In the J and H bands, bright [Fe II] lines (1.24um and 1.64um) are detected spectroscopically. The Palomar observations include Ks continuum, narrow-band 1.64um (centered on [Fe II]) and 2.12um (centered on H2(1-0)) images. While the narrow-band 1.64um image shows filamentary and knotty structures, similar to the optical image, the Ks image shows a relatively smooth, diffuse shell, remarkably similar to the radio image. The broad-band near-infrared fluxes of Cas A are generally consistent with, but a few tens of percent higher than, an extrapolation of the radio fluxes. The hardening to higher frequencies is possibly due to nonlinear shock acceleration and/or spectral index variation across the remnant. We show evidence of spectral index variation. The presence of near-infrared synchrotron radiation requires the roll-off frequency to be higher than 1.5e14 Hz, implying that electrons are accelerated to energies of at least 0.2 TeV. The morphological similarity in diffuse emission between the radio and Ks band images implies that synchrotron losses are not dominant. Our observations show unambiguous evidence that the near-infrared Ks band emission of Cas A is from synchrotron emission by accelerated cosmic-ray electrons.Comment: accepted by Ap

Nonthermal Emission from a Supernova Remnant in a Molecular Cloud

In evolved supernova remnants (SNRs) interacting with molecular clouds, such as IC 443, W44, and 3C391, a highly inhomogeneous structure consisting of a forward shock of moderate Mach number, a cooling layer, a dense radiative shell and an interior region filled with hot tenuous plasma is expected. We present a kinetic model of nonthermal electron injection, acceleration and propagation in that environment and find that these SNRs are efficient electron accelerators and sources of hard X- and gamma-ray emission. The energy spectrum of the nonthermal electrons is shaped by the joint action of first and second order Fermi acceleration in a turbulent plasma with substantial Coulomb losses. Bremsstrahlung, synchrotron, and inverse Compton radiation of the nonthermal electrons produce multiwavelength photon spectra in quantitative agreement with the radio and the hard emission observed by ASCA and EGRET from IC 443. We distinguish interclump shock wave emission from molecular clump shock wave emission accounting for a complex structure of molecular cloud. Spatially resolved X- and gamma- ray spectra from the supernova remnants IC 443, W44, and 3C391 as might be observed with BeppoSAX, Chandra XRO, XMM, INTEGRAL and GLAST would distinguish the contribution of the energetic lepton component to the gamma-rays observed by EGRET.Comment: 14 pages, 4 figure, Astrophysical Journal, v.538, 2000 (in press

A study of Tycho's SNR at TeV energies with the HEGRA CT-System

Tycho's supernova remnant (SNR) was observed during 1997 and 1998 with the HEGRA Cherenkov Telescope System in a search for gamma-ray emission at energies above ~1 TeV. An analysis of these data, ~65 hours in total, resulted in no evidence for TeV gamma-ray emission. The 3sigma upper limit to the gamma-ray flux (>1 TeV) from Tycho is estimated at 5.78x10^{-13} photons cm^{-2} s^{-1}, or 33 milli-Crab. We interpret our upper limit within the framework of the following scenarios: (1) that the observed hard X-ray tail is due to synchrotron emission. A lower limit on the magnetic field within Tycho may be estimated B>=22 microG, assuming that the RXTE-detected X-rays were due to synchrotron emission. However, using results from a detailed model of the ASCA emission, a more conservative lower limit B>=6 microG is derived. (2) the hadronic model of Drury, Aharonian & Voelk, and (3) the more recent time-dependent kinetic theory of Berezhko & Voelk. Our upper limit lies within the range of predicted values of both hadronic models, according to uncertainties in physical parameters of Tycho, and shock acceleration details. In the latter case, the model was scaled to suit the parameters of Tycho and re-normalised to account for a simplification of the original model. We find that we cannot rule out Tycho as a potential contributor at an average level to the Galactic cosmic-ray flux.Comment: 9 pages, 6 figures. Accepted for publication in Astronomy and Astrophysic

Evidence of X-ray Synchrotron Emission from Electrons Accelerated to 40 TeV in the Supernova Remnant Cassiopeia A

We present the 2-60 keV spectrum of the supernova remnant Cassiopeia A measured using the Proportional Counter Array and the High Energy X-ray Timing Experiment on the Rossi X-ray Timing Explorer satellite. In addition to the previously reported strong emission-line features produced by thermal plasmas, the broad-band spectrum has a high-energy "tail" that extends to energies at least as high as 120 keV. This tail may be described by a broken power law that has photon indices of 1.8 +0.5/-0.6 and 3.04 +0.15/-0.13 and a break energy of 15.9 +0.3/-0.4 keV. We argue that the high-energy component, which dominates the spectrum above about 10 keV, is produced by synchrotron radiation from electrons that have energies up to at least 40 TeV. This conclusion supports the hypothesis that Galactic cosmic rays are accelerated predominantly in supernova remnants.Comment: 10 pages of text, 3 figures, accepted for Astrophys. J. Letter

A Possible Site of Cosmic Ray Acceleration in the Supernova Remnant IC 443

We present evidence for shock acceleration of cosmic rays to high energies (about 10 TeV) in the supernova remnant IC 443. X-ray imaging spectroscopy with ASCA reveals two regions of particularly hard emission: an unresolved source embedded in an extended emission region, and a ridge of emission coincident with the southeastern rim. Both features are located on part of the radio shell where the shock wave is interacting with molecular gas, and together they account for a majority of the emission at 7 keV. Though we would not have noticed it a priori, the unresolved feature is coincident with one resolved by the ROSAT HRI. Because this feature overlaps a unique region of flat radio spectral index (alpha < 0.24), has about equal light-crossing and synchrotron loss times, and a power law spectrum with a spectral index of 2, we conclude that the hard X-ray feature is synchrotron radiation from a site of enhanced particle acceleration. Evidence against a plerion includes a lack of observed periodicity (the pulsed fraction upper limit is 33%), the spectral similarity with the more extended hard region, the location of the source outside the 95% error circle of the nearby EGRET source, the fact that it is nestled in a bend in the molecular cloud ring with which IC 443 is interacting, and the requirement of an extremely high transverse velocity (>5,000 km/s). We conclude that the anomalous feature is most likely tracing enhanced particle acceleration by shocks that are formed as the supernova blast wave impacts the ring of molecular clouds.Comment: 10 pages with embedded figures; accepted by the Ap.J; author's web pages at http://lheawww.gsfc.nasa.gov/users/jonathan/ , http://lheawww.gsfc.nasa.gov/users/rob/Vita/petre.html , http://lheawww.gsfc.nasa.gov/users/evg/evg.htm

Separating Thermal and Nonthermal X-Rays in Supernova Remnants I: Total Fits to SN 1006 AD

The remnant of SN 1006 has an X-ray spectrum dominated by nonthermal emission, and pre-ASCA observations were well described by a synchrotron calculation with electron energies limited by escape. We describe the results of a much more stringent test: fitting spatially integrated ASCA GIS (0.6-8 keV) and RXTE PCA (3-10 keV) data with a combination of the synchrotron model SRESC newly ported to XSPEC and a new thermal shock model VPSHOCK. The new model can describe the continuum emission above 2 keV well, in both spatial distribution and spectrum. We find that the emission is dominantly nonthermal, with a small but noticeable thermal component: Mg and Si are clearly visible in the integrated spectrum. The synchrotron component rolls off smoothly from the extrapolated radio spectrum, with a characteristic rolloff frequency of 3.1E17 Hz, at which the spectrum has dropped about a factor of 6 below a powerlaw extrapolation from the radio spectrum. Comparison of TeV observations with new TeV model images and spectra based on the X-ray model fits gives a mean post-shock magnetic field strength of about 9 microGauss, implying (for a compression ratio of 4) an upstream magnetic field of 3 microGauss, and fixing the current energy content in relativistic electrons at about 7E48 ergs, resulting in a current electron-acceleration efficiency of about 5%. This total energy is about 100 times the energy in the magnetic field. Our results indicate that joint thermal and nonthermal fitting, using sophisticated models, will be required for analysis of most supernova-remnant X-ray data in the future.Comment: 26 pages + 12 figures, accepted by Ap

The Relation Between the Surface Brightness and the Diameter for Galactic Supernova Remnants

In this work, we have constructed a relation between the surface brightness ($\Sigma$) and diameter (D) of Galactic C- and S-type supernova remnants (SNRs). In order to calibrate the $\Sigma$-D dependence, we have carefully examined some intrinsic (e.g. explosion energy) and extrinsic (e.g. density of the ambient medium) properties of the remnants and, taking into account also the distance values given in the literature, we have adopted distances for some of the SNRs which have relatively more reliable distance values. These calibrator SNRs are all C- and S-type SNRs, i.e. F-type SNRs (and S-type SNR Cas A which has an exceptionally high surface brightness) are excluded. The Sigma-D relation has 2 slopes with a turning point at D=36.5 pc: $\Sigma$(at 1 GHz)=8.4$^{+19.5}_{-6.3}$$\times10^{-12}$ D$^{{-5.99}^{+0.38}_{-0.33}}$ Wm$^{-2}$Hz$^{-1}$ster$^{-1}$ (for $\Sigma$$\le3.7\times10^{-21}$ Wm$^{-2}$Hz$^{-1}$ster$^{-1}$ and D$\ge$36.5 pc) and $\Sigma$(at 1 GHz)=2.7$^{+2.1}_{-1.4}$$\times$ 10$^{-17}$ D$^{{-2.47}^{+0.20}_{-0.16}}$ Wm$^{-2}$Hz$^{-1}$ster$^{-1}$ (for $\Sigma$$>3.7\times10^{-21}$ Wm$^{-2}$Hz$^{-1}$ster$^{-1}$ and D$<$36.5 pc). We discussed the theoretical basis for the $\Sigma$-D dependence and particularly the reasons for the change in slope of the relation were stated. Added to this, we have shown the dependence between the radio luminosity and the diameter which seems to have a slope close to zero up to about D=36.5 pc. We have also adopted distance and diameter values for all of the observed Galactic SNRs by examining all the available distance values presented in the literature together with the distances found from our $\Sigma$-D relation.Comment: 45 pages, 2 figures, accepted for publication in Astronomical and Astrophysical Transaction