547 research outputs found
Charge density studies of energetic material: RDX
Experimental charge density study has been carried out for Cyclotrimethylene-trinitramine (space group Pbca), an explosive material from a low temperature X-ray diffraction experiment. The electron density was modeled using the Hansen-Coppens multipole model and refined to R=0.032 for 6226 unique observed reflections. The electron density, laplacian and electrostatic potential distributions are reported and discussed, especially, the properties of the bond (3,-1) critical points, which are thought to play a key role in the decomposition of the molecule. From the bond topological analysis of all the bonds, it is observed that the N–N bond is the weakest. The dominating nature of the oxygen atoms was clearly well understood from isosurface electrostatic potential of isolated and symmetrically sitting molecules in the crystal
Combustion Behaviour of Advanced Solid Propellants.
The study reports the effect of incorporation of Al and ammonium perchlorate (AP) individually and in combination with each other on combustion pattern and specific impulse (Isp) of minimum signature propellants. Incorporation of Al obviates the combustion instability problems; however, it has marginal effect on burning rates. The composition containing AP and zirconium silicate combination gives superior performance; however, its Isp is considerably lower than the composition incorporating 9 per cent AP. A combination of 6 per cent Al gave 20 per cent enhancement in burning rate and 12 s increase in Isp as compared to purely nitramine-based composition, cal-val results also reveal increase in energy output on incorporating AP and Al. Hot stage microscopic and propellant combustion studies indicate occurrence of intense decomposition reaction in case of AP-based compositions
On Radiative Weak Annihilation Decays
We discuss a little-studied class of weak decay modes sensitive to only one
quark topology at leading order in G_F: M --> m gamma, where M,m are mesons
with completely distinct flavor quantum numbers. Specifically, they proceed via
the annihilation of the valence quarks through a W and the emission of a single
hard photon, and thus provide a clear separation between CKM and strong
interaction physics. We survey relevant calculations performed to date, discuss
experimental discovery potential, and indicate interesting future directions.Comment: 10 pages LaTeX, includes macros file and 9 .eps figures. Invited talk
at RADCOR 2000 (5th Int. Symp. on Radiative Corrections), Carmel, CA, Sept.
200
Risk-Averse Matchings over Uncertain Graph Databases
A large number of applications such as querying sensor networks, and
analyzing protein-protein interaction (PPI) networks, rely on mining uncertain
graph and hypergraph databases. In this work we study the following problem:
given an uncertain, weighted (hyper)graph, how can we efficiently find a
(hyper)matching with high expected reward, and low risk?
This problem naturally arises in the context of several important
applications, such as online dating, kidney exchanges, and team formation. We
introduce a novel formulation for finding matchings with maximum expected
reward and bounded risk under a general model of uncertain weighted
(hyper)graphs that we introduce in this work. Our model generalizes
probabilistic models used in prior work, and captures both continuous and
discrete probability distributions, thus allowing to handle privacy related
applications that inject appropriately distributed noise to (hyper)edge
weights. Given that our optimization problem is NP-hard, we turn our attention
to designing efficient approximation algorithms. For the case of uncertain
weighted graphs, we provide a -approximation algorithm, and a
-approximation algorithm with near optimal run time. For the case
of uncertain weighted hypergraphs, we provide a
-approximation algorithm, where is the rank of the
hypergraph (i.e., any hyperedge includes at most nodes), that runs in
almost (modulo log factors) linear time.
We complement our theoretical results by testing our approximation algorithms
on a wide variety of synthetic experiments, where we observe in a controlled
setting interesting findings on the trade-off between reward, and risk. We also
provide an application of our formulation for providing recommendations of
teams that are likely to collaborate, and have high impact.Comment: 25 page
Polyurethane Based Inhibition for High Flame Temperature Nitramine Based Composite Modified Double Base propellant
The findings for polypropylene glycol (PPG) and hydroxyl-terminated polybutadiene (HTPB)-based inhibition systems are reported. These findings established that the inhibition system comprising HTPB-IPDI-IDP binder and Sb/sub 2/O/sub 3/-C black filler is most suitable for advanced nitramine-based composite modified double-base propellants in terms of mechanical properties and processibility. The promising composition was characterised for glass-transition behaviour and propellant-inhibition bond strength. Propellant grains inhibited with selected formulations were subjected to static evaluation at extreme temperatures and limited aging studies to obtain data of practical value
Detonating Cord for Flux Compression Generation using Electrical Detonator No. 33
The paper highlights the use of electrical detonators for magnetic flux compression generator applications which requires synchronisation of two events with precise time delay of tens of ms and jitter within a few ms. These requirements are generally achieved by exploding bridge wire type detonators which are difficult to develop and are not commercially available. A technique has been developed using commercially available electrical detonator no. 33 to synchronise between peak of seed current in stator coil and detonation of explosive charge in armature. In present experiments, electrical signal generated by self-shorting pin due to bursting of electrical detonator has been used to trigger the capacitor discharge and the detonating cord of known length has been used to incorporate predetermined delay to synchronise the events. It has been demonstrated that using electrical detonator and known length of detonating cord, the two events can be synchronised with predetermined delay between 31 and 251 ms with variation of ± 0.5ms. The technique developed is suitable for defence applications like generation of high power microwaves using explosive driven magnetic flux compression generators.Defence Science Journal, 2011, 61(1), pp.19-24, DOI:http://dx.doi.org/10.14429/dsj.61.3
Long distance effects in weak radiative decays of D-mesons
We present a detailed analysis of the transitions, using a
model which combines heavy quark effective theory and the chiral Lagrangian
approach and includes symmetry breaking. We notice that in addition to the
previously considered s - channel annihilation and t - channel W - exchange,
there is a long distance penguin - like contribution in the t
- channel of Cabibbo - suppressed modes. Its magnitude is determined by the
size of symmetry breaking which we calculate with a vector dominance approach.
Although smaller in magnitude, the penguin - like contribution would lead to
sizeable effects in case of cancellations among the other contributions to the
amplitude. Thus, it may invalidate suggested tests for beyond the standard
model effects in these decays. We also indicate the range of expectations for
the branching ratios of various modes.Comment: 28 pages, Latex, 2 Figure
Bonding of Silicon Carbide Based Ceramics using Particulate Reinforced Ag-Cu-Ti Alloys
No abstract availabl
Hyperon weak radiative decays in chiral perturbation theory
We investigate the leading-order amplitudes for weak radiative decays of
hyperons in chiral perturbation theory. We consistently include contributions
from the next-to-leading order weak-interaction Lagrangian. It is shown that
due to these terms Hara's theorem is violated. The data for the decays of
charged hyperons can be easily accounted for. However, at this order in the
chiral expansion, the four amplitudes for the decays of neutral hyperons
satisfy relations which are in disagreement with the data. The asymmetry
parameters for all the decays can not be accounted for without higher-order
terms. We shortly comment on the effect of the 27-plet part of the weak
interaction.Comment: 8 pages of REVTeX and using macro-package "feynman.tex" (available at
http://xxx.lanl.gov/ftp/hep-ph/papers/macros) for the 2 figure
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