Ion molecule reactions in vinyl fluoride by photoionization. Effects of vibrational excitation on major reaction pathways

Photoionization methods have been used to study the reactions of the molecular ion in vinyl fluoride to yield the ionic products C_3H_3F_2^+, C_3H_4F^+, and C_3H_5^+. Quantitative measurements are reported of the effect of the vibrational state of the reactant ion on the product distribution and overall reaction cross section. Reaction cross sections for all three channels decrease with reactant internal energy. The effect on the reaction pathway producing C_3H_3F_2^+ is especially pronounced, with 0.18 eV of vibrational excitation being sufficient to reduce the reaction probability by 75%. Deactivation of vibrationally excited reactant ions competes with the reaction and is shown to be an efficient process

A Search For Star Formation in the Smith Cloud

Motivated by the idea that a subset of HVCs trace dark matter substructure in the Local Group, we search for signs of star formation in the Smith Cloud, a nearby ~2x10^6 Msun HVC currently falling into the Milky Way. Using GALEX NUV and WISE/2MASS NIR photometry, we apply a series of color and apparent magnitude cuts to isolate candidate O and B stars that are plausibly associated with the Smith Cloud. We find an excess of stars along the line of sight to the cloud, but not at a statistically significant level relative to a control region. The number of stars found in projection on the cloud after removing an estimate of the contamination by the Milky Way implies an average star formation rate surface density of 10^(-4.8 +/- 0.3) Msun yr^(-1) kpc^(-2), assuming the cloud has been forming stars at a constant rate since its first passage through the Milky Way ~70 Myr ago. This value is consistent with the star formation rate expected based on the average gas density of the cloud. We also discuss how the newly discovered star forming galaxy Leo P has very similar properties to the Smith Cloud, but its young stellar population would not have been detected at a statistically significant level using our method. Thus, we cannot yet rule out the idea that the Smith Cloud is really a dwarf galaxy.Comment: 9 pages, 7 figures, accepted for publication in MNRA

Mechanisms of nonstoichiometry in HfN_1-<i>x</i>

Density functional theory is used to calculate defect structures that can accommodate nonstoichiometry in hafnium nitride: HfN1-x, 0 ≤ X ≤ 0.25. It is predicted that a mechanism assuming simple distributions of nitrogen vacancies can accurately describe the variation in the experimentally observed lattice parameter with respect to the nitrogen nonstoichiometry. Although the lattice parameter changes are remarkably small across the whole nonstoichiometry range, the variations in the bulk modulus are much greater

Evidence for bimodal orbital separations of white dwarf-red dwarf binary stars

We present the results of a radial velocity survey of 20 white dwarf plus M dwarf binaries selected as a follow up to a \textit{Hubble Space Telescope} study that aimed to spatially resolve suspected binaries. Our candidates are taken from the list of targets that were spatially unresolved with \textit{Hubble}. We have determined the orbital periods for 16 of these compact binary candidates. The period distribution ranges from 0.14 to 9.16\,d and peaks near 0.6\,d. The original sample therefore contains two sets of binaries, wide orbits ($\approx100-1000$\,au) and close orbits ($\lesssim1-10$\,au), with no systems found in the $\approx10-100$\,au range. This observational evidence confirms the bimodal distribution predicted by population models and is also similar to results obtained in previous studies. We find no binary periods in the months to years range, supporting the post common envelope evolution scenario. One of our targets, WD\,1504+546, was discovered to be an eclipsing binary with a period of 0.93\,d

Phenology satellite experiment

The detection of a phenological event (the brown wave-vegetation senescence) for specific forest and crop types using ERTS-1 imagery is described. Data handling techniques included computer analysis and photo interpretation procedures. Computer analysis of ERTS-1 multispectral scanner digital tapes in all bands was used to give the relative changes of spectral reflectance with time of forests and specified crops. These data were obtained for a number of the study's twenty-four sites located within four north-south corridors across the United States. Analysis of ground observation photography and ERTS-1 imagery for sites in the Appalachian Corridor and Mississippi Valley Corridor indicates that the recession of vegetation development can be detected very well. Tentative conclusions are that specific phenological events such as crop maturity or leaf fall can be mapped for specific sites and possibly for entire regions