Thermal Decomposition of Co-Doped Calcium Tartrate and Use of the Products for Catalytic Chemical Vapor Deposition Synthesis of Carbon Nanotubes.

Thermal decomposition of Co-doped calcium tartrate in an inert atmosphere or air was studied using thermogravimetric analysis and X-ray absorption fine structure (XAFS) spectroscopy. It was shown that the powder substance containing 4 at.% of cobalt completely decomposes within 650-730 °C, depending on the environment, and the formation of Co clusters does not proceed before 470 °C. The products of decomposition were characterized by transmission electron microscopy, XAFS, and X-ray photoelectron spectroscopy. Surfaceoxidized Co metal nanoparticles as large as ∼5.6 ( 1.2 nm were found to form in an inert atmosphere, while the annealing in air led to a wide distribution of diameters of the nanoparticles, with the largest nanoparticles (30-50 nm) mainly present as a Co3O4 phase. It was found that the former nanoparticles catalyze the growth of CNTs from alcohol while a reducing atmosphere is required for activation of the latter nanoparticles. We propose the scheme of formation of CaO-supported catalyst from Co-doped tartrate, depending on the thermal decomposition conditions

Changes in daily temperature and precipitation extremes in central and south Asia

Changes in indices of climate extremes are studied on the basis of daily series of temperature and precipitation observations from 116 meteorological stations in central and south Asia. Averaged over all stations, the indices of temperature extremes indicate warming of both the cold tail and the warm tail of the distributions of daily minimum and maximum temperature between 1961 and 2000. For precipitation, most regional indices of wet extremes show little change in this period as a result of low spatial trend coherence with mixed positive and negative station trends. Relative to the changes in the total amounts, there is a slight indication of disproportionate changes in the precipitation extremes. Stations with near-complete data for the longer period of 1901-2000 suggest that the recent trends in extremes of minimum temperature are consistent with long-term trends, whereas the recent trends in extremes of maximum temperature are part of multidecadal climate variability