5 research outputs found
Studies on titanium (IV) ¾ -diketonates and investigation of the tetracarbonylcobaltate anion for m-m bond formation
Ce-Based Catalysts for the Selective Catalytic Reduction of NO<sub><i>x</i></sub> in the Presence of Excess Oxygen and Simulated Diesel Engine Exhaust Conditions
A family of various cerium oxide-based
catalysts were synthesized
by adopting flame aerosol (FSP), coprecipitation, wet impregnation,
and hydrothermal synthesis techniques. The resulting catalysts were
explored for the selective catalytic reduction (SCR) of NO<sub><i>x</i></sub> using NH<sub>3</sub> as reductant. In our studies,
both the preparation method and the Ce/W ratios were found to be critical
variables for successful catalyst promotion. For the industrial realization,
we have scaled up the SCR activity tests. The microreactor catalytic
formulations at simulated diesel engine exhaust conditions revealed
that the Ce–W (1:1 atomic ratio) and Ce–W/TiO<sub>2</sub> catalysts showed high deNO<sub><i>x</i></sub> activity,
while the other catalysts’ activity was found to be rather
low. Of interest is the finding that the Ce–W/TiO<sub>2</sub>/cordierite and Ce–W (1:1 atomic ratio)/cordierite formulations
show impressive deNO<sub><i>x</i></sub> performance and
high N<sub>2</sub> selectivity with respect to a commercial vanadia
based reference currently used for mobile applications. To gain fundamental
insights which may acquaint further improvements to the promoted Ce-based
catalysts, X-ray photoelectron spectroscopy and other characterizations
were executed to study the relationship between catalyst surface and
NO<sub><i>x</i></sub> reduction activity. Our XRD results
indicate smaller lattice parameters of prepared catalysts compared
to that of CeO<sub>2</sub> (0.540 nm). The crystal lattice contraction
is attributed to the lesser ionic radius of relevant foreign metal
ions (W<sup>6+</sup> = 0.067 nm and Ti<sup>4+</sup> = 0.074 nm) in
relation to Ce<sup>4+</sup> (0.092 nm) in the host lattice. This lattice
shrinkage elucidates the formation of solid solutions. These results
illustrate that the synthesis technique and various promoters could
indeed influence the lattice structures and electronic state of the
active components. The XPS results illustrate the higher atomic ratios
of Ce<sup>3+</sup>/(Ce<sup>3+</sup> + Ce<sup>4+</sup>) 0.30 and 0.29
in Ce–W/TiO<sub>2</sub> and Ce–W (1:1) coprecipitation
catalysts, respectively, compared to other samples. The higher surface
Ce<sup>3+</sup>/Ce<sup>4+</sup> ratio in Ce–W (1:1) coprecipitation
and Ce–W/TiO<sub>2</sub> samples indicate the enrichment in
surface oxygen vacancies, which results in activation of reactive
molecules and enhanced adsorption of oxygen species in SCR reaction.
Interestingly, the surface atomic ratio of Ce<sup>3+</sup>/Ce<sup>4+</sup> and Ce<sup>3+</sup>/Ce<sup><i>n</i>+</sup> are
interrelated to the SCR activity of the individual catalysts