Photon Emission from Ultrarelativistic Plasmas

The emission rate of photons from a hot, weakly coupled ultrarelativistic plasma is analyzed. Leading-log results, reflecting the sensitivity of the emission rate to scattering events with momentum transfers from $gT$ to $T$, have previously been obtained. But a complete leading-order treatment requires including collinearly enhanced, inelastic processes such as bremsstrahlung. These inelastic processes receive O(1) modifications from multiple scattering during the photon emission process, which limits the coherence length of the emitted radiation (the Landau-Pomeranchuk-Migdal effect). We perform a diagrammatic analysis to identify, and sum, all leading-order contributions. We find that the leading-order photon emission rate is not sensitive to non-perturbative $g^2 T$ scale dynamics. We derive an integral equation for the photon emission rate which is very similar to the result of Migdal in his original discussion of the LPM effect. The accurate solution of this integral equation for specific theories of interest will be reported in a companion paper.Comment: 50 pages, 20 figures. Added references and minor rewordings: published versio

Pressure of Hot QCD at Large N_f

We compute the pressure and entropy of hot QCD in the limit of large number of fermions, N_f >> N_c ~ 1, to next to leading order in N_f. At this order the calculation can be done exactly, up to ambiguities due to the presence of a Landau pole in the theory; the ambiguities are O(T^8/\Lambda^4_{Landau}) and remain negligible long after the perturbative series (in g^2 N_f) has broken down. Our results can be used to test several proposed resummation schemes for the pressure of full QCD.Comment: 16 pages including 4 figures. Short enough for you to read. Numerical results corrected after an error was found by Andreas Ipp and Anton Rebha

Effective Kinetic Theory for High Temperature Gauge Theories

Quasiparticle dynamics in relativistic plasmas associated with hot, weakly-coupled gauge theories (such as QCD at asymptotically high temperature $T$) can be described by an effective kinetic theory, valid on sufficiently large time and distance scales. The appropriate Boltzmann equations depend on effective scattering rates for various types of collisions that can occur in the plasma. The resulting effective kinetic theory may be used to evaluate observables which are dominantly sensitive to the dynamics of typical ultrarelativistic excitations. This includes transport coefficients (viscosities and diffusion constants) and energy loss rates. We show how to formulate effective Boltzmann equations which will be adequate to compute such observables to leading order in the running coupling $g(T)$ of high-temperature gauge theories [and all orders in $1/\log g(T)^{-1}$]. As previously proposed in the literature, a leading-order treatment requires including both $22$ particle scattering processes as well as effective ``$12$'' collinear splitting processes in the Boltzmann equations. The latter account for nearly collinear bremsstrahlung and pair production/annihilation processes which take place in the presence of fluctuations in the background gauge field. Our effective kinetic theory is applicable not only to near-equilibrium systems (relevant for the calculation of transport coefficients), but also to highly non-equilibrium situations, provided some simple conditions on distribution functions are satisfied.Comment: 40 pages, new subsection on soft gauge field instabilities adde

Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes.

The one-electron reduction of a cationic (allenylidene)[cyclic(alkyl) (amino)carbene]gold(i) complex leads to the corresponding neutral, paramagnetic, formally gold(0) complex. DFT calculations reveal that the spin density of this highly robust coinage metal complex is mainly located on the allenylidene fragment, with only 1.8 and 3.1% on the gold center and the CAAC ligand, respectively. In addition, the first homoleptic bis(allenylidene)gold(i) complex has been prepared and fully characterized

Inhibition of a viral enzyme by a small-molecule dimer disruptor.

We identified small-molecule dimer disruptors that inhibit an essential dimeric protease of human Kaposi's sarcoma-associated herpesvirus (KSHV) by screening an alpha-helical mimetic library. Next, we synthesized a second generation of low-micromolar inhibitors with improved potency and solubility. Complementary methods including size exclusion chromatography and 1H-13C HSQC titration using selectively labeled 13C-Met samples revealed that monomeric protease is enriched in the presence of inhibitor. 1H-15N HSQC titration studies mapped the inhibitor binding site to the dimer interface, and mutagenesis studies targeting this region were consistent with a mechanism where inhibitor binding prevents dimerization through the conformational selection of a dynamic intermediate. These results validate the interface of herpesvirus proteases and other similar oligomeric interactions as suitable targets for the development of small-molecule inhibitors