Rare earth magnetism and ferroelectricity in RMnO3

Magnetic rare earths R have been proven to have a significant effect on the multiferroic properties of the orthorhombic manganites RMnO3. A re-examination of previous results from synchrotron based x-ray scattering experiments suggests that symmetric exchange striction between neighboring R and Mn ions may account for the enhancement of the ferroelectric polarization in DyMnO3 as well as the magnetic-field induced ferroelectricity in GdMnO3. In general, adding a second magnetic species to a multiferroic material may be a route to enhance its ferroelectric properties.Comment: Contribution to ICM 2009; accepted for publication in Journal of Physics: Conference Serie

Commensurate Dy magnetic ordering associated with incommensurate lattice distortion in orthorhombic DyMnO3

Synchrotron x-ray diffraction and resonant magnetic scattering experiments on single crystal DyMnO3 have been carried out between 4 and 40 K. Below TN(Dy) = 5K, the Dy magnetic moments order in a commensurate structure with propagation vector 0.5 b*. Simultaneous with the Dy magnetic ordering, an incommensurate lattice modulation with propagation vector 0.905 b* evolves while the original Mn induced modulation is suppressed and shifts from 0.78 b* to 0.81 b*. This points to a strong interference of Mn and Dy induced structural distortions in DyMnO3 besides a magnetic coupling between the Mn and Dy magnetic moments.Comment: submitted to Phys. Rev. B Rapid Communication

Enhanced ferroelectric polarization by induced Dy spin-order in multiferroic DyMnO3

Neutron powder diffraction and single crystal x-ray resonant magnetic scattering measurements suggest that Dy plays an active role in enhancing the ferroelectric polarization in multiferroic DyMnO3 above TNDy = 6.5 K. We observe the evolution of an incommensurate ordering of Dy moments with the same periodicity as the Mn spiral ordering. It closely tracks the evolution of the ferroelectric polarization which reaches a maximum value of 0.2 muC/m^2. Below TNDy, where Dy spins order commensurately, the polarization decreases to values similar for those of TbMnO3

Transition from a phase-segregated state to single-phase incommensurate sodium ordering in Na_xCoO_2 with x \approx 0.53

Synchrotron X-ray diffraction investigations of two single crystals of Na_xCoO_2 from different batches with composition x = 0.525-0.530 reveal homogeneous incommensurate sodium ordering with propagation vector (0.53 0.53 0) at room-temperature. The incommensurate (qq0) superstructure exists between 220 K and 430 K. The value of q varies between q = 0.514 and 0.529, showing a broad plateau at the latter value between 260 K and 360 K. On cooling, unusual reversible phase segregation into two volume fractions is observed. Below 220 K, one volume fraction shows the well-known commensurate orthorhombic x = 0.50 superstructure, while a second volume fraction with x = 0.55 exhibits another commensurate superstructure, presumably with a 6a x 6a x c hexagonal supercell. We argue that the commensurate-to-incommensurate transition is an intrinsic feature of samples with Na concentrations x = 0.5 + d with d ~ 0.03.Comment: Corrected/improved versio

Coupling of frustrated Ising spins to magnetic cycloid in multiferroic TbMnO3

We report on diffraction measurements on multiferroic TbMnO3 which demonstrate that the Tb- and Mn-magnetic orders are coupled below the ferroelectric transition TFE = 28 K. For T < TFE the magnetic propagation vectors (tau) for Tb and Mn are locked so that tauTb = tauMn, while below TNTb = 7 K we find that tauTb and tauMn lock-in to rational values of 3/7 b* and 2/7 b*, respectively, and obey the relation 3tauTb - tauMn = 1. We explain this novel matching of wave vectors within the frustrated ANNNI model coupled to a periodic external field produced by the Mn-spin order. The tauTb = tauMn behavior is recovered when Tb magnetization is small, while the tauTb = 3/7 regime is stabilized at low temperatures by a peculiar arrangement of domain walls in the ordered state of Ising-like Tb spins.Comment: 5 pages, 3 figure

Albanian grapevine cultivars: preliminary results of molecular, phenolic and ampelometric profiles and relatedness

'Shesh i Zi', 'Shesh i Bardhë', 'Kallmet' and 'Vlosh' are commercialised grapevine wine varieties which best represent the high variability of the Albanian autochthonous germplasm because of their different origin within the country and their great wine potential. We characterised these cultivars at molecular, phenolic and ampelometric level as well as assessing their relatedness. The leaves were scanned and images were analyzed using SuperAmpelo, which allows to measure leaves, clusters, berries, and seeds, and to record the main descriptive ampelographic characters, including carpometric indices. The content of total anthocyanins, total flavonoids, non-anthocyanic flavonoids, proanthocyanidins and total polyphenols were determined in the extracts of the grape skins and seeds of 10 berries from each of 10 representative clusters as well as in samples of one year old wines. For the molecular characterization, 10 SSR loci were used. The similarity of cultivars was studied by applying the Ward's method for hierarchical clustering along with other Albanian genotypes. This work has completed and made more accurate the existing ampelographic descriptions found in literature with the aim to valorize these autochthonous cultivars, which could represent a valuable instrument for improving the local economies

Ga substitution as an effective variation of Mn-Tb coupling in multiferroic TbMnO3

Ga for Mn substitution in multiferroic TbMnO$_{3}$ has been performed in order to study the influence of Mn-magnetic ordering on the Tb-magnetic sublattice. Complete characterization of TbMn$_{1-x}$Ga$_x$O$_{3}$ ($x$ = 0, 0.04, 0.1) samples, including magnetization, impedance spectroscopy, and x-ray resonant scattering and neutron diffraction on powder and single crystals has been carried out. We found that keeping the same crystal structure for all compositions, Ga for Mn substitution leads to the linear decrease of $T_{\rm N}^{\rm Mn}$ and $\tau^{\rm Mn}$, reflecting the reduction of the exchange interactions strength $J_{\rm Mn-Mn}$ and the change of the Mn-O-Mn bond angles. At the same time, a strong suppression of both the induced and the separate Tb-magnetic ordering has been observed. This behavior unambiguously prove that the exchange fields $J_{\rm Mn-Tb}$ have a strong influence on the Tb-magnetic ordering in the full temperature range below $T_{\rm N}^{\rm Mn}$ and actually stabilize the Tb-magnetic ground state.Comment: 9 pages, 8 figure

Characterization of the optical properties of the buried contact of the JWST MIRI Si:As infrared blocked impurity band detectors

The Mid-Infrared Instrument MIRI on-board the James Webb Space Telescope uses three Si:As impurity band conduction detector arrays. MIRI medium resolution spectroscopic measurements (R$\sim$3500-1500) in the 5~$\mu m$ to 28~$\mu m$ wavelength range show a 10-30\% modulation of the spectral baseline; coherent reflections of infrared light within the Si:As detector arrays result in fringing. We quantify the shape and impact of fringes on spectra of optical sources observed with MIRI during ground testing and develop an optical model to simulate the observed modulation. We use our optical model in conjunction with the MIRI spectroscopic data to show that the properties of the buried contact inside the MIRI Si:As detector have a significant effect on the fringing behavior.Comment: 11 pages, 7 figures, SPIE Astronomical Telescopes + Instrumentation 2020, submitted to SPI