Emissions of Volatile Organic Compounds Inferred From Airborne Flux Measurements over a Megacity

Toluene and benzene are used for assessing the ability to measure disjunct eddy covariance (DEC) fluxes of Volatile Organic Compounds (VOC) using Proton Transfer Reaction Mass Spectrometry (PTR-MS) on aircraft. Statistically significant correlation between vertical wind speed and mixing ratios suggests that airborne VOC eddy covariance (EC) flux measurements using PTR-MS are feasible. City-median midday toluene and benzene fluxes are calculated to be on the order of 14.1±4.0 mg/m<sup>2</sup>/h and 4.7±2.3 mg/m<sup>2</sup>/h, respectively. For comparison the adjusted CAM2004 emission inventory estimates toluene fluxes of 10 mg/m<sup>2</sup>/h along the footprint of the flight-track. Wavelet analysis of instantaneous toluene and benzene measurements during city overpasses is tested as a tool to assess surface emission heterogeneity. High toluene to benzene flux ratios above an industrial district (e.g. 10–15 g/g) including the International airport (e.g. 3–5 g/g) and a mean flux (concentration) ratio of 3.2±0.5 g/g (3.9±0.3 g/g) across Mexico City indicate that evaporative fuel and industrial emissions play an important role for the prevalence of aromatic compounds. Based on a tracer model, which was constrained by BTEX (BTEX– Benzene/Toluene/Ethylbenzene/m, p, o-Xylenes) compound concentration ratios, the fuel marker methyl-tertiary-butyl-ether (MTBE) and the biomass burning marker acetonitrile (CH<sub>3</sub>CN), we show that a combination of industrial, evaporative fuel, and exhaust emissions account for >87% of all BTEX sources. Our observations suggest that biomass burning emissions play a minor role for the abundance of BTEX compounds in the MCMA (2–13%)

Upper tropospheric ozone production from lightning NO_x-impacted convection: Smoke ingestion case study from the DC3 campaign

As part of the Deep Convective Cloud and Chemistry (DC3) experiment, the National Science Foundation/National Center for Atmospheric Research (NCAR) Gulfstream-V (GV) and NASA DC-8 research aircraft probed the chemical composition of the inflow and outflow of two convective storms (north storm, NS, south storm, SS) originating in the Colorado region on 22 June 2012, a time when the High Park wildfire was active in the area. A wide range of trace species were measured on board both aircraft including biomass burning (BB) tracers hydrogen cyanide (HCN) and acetonitrile (ACN). Acrolein, a much shorter lived tracer for BB, was also quantified on the GV. The data demonstrated that the NS had ingested fresh smoke from the High Park fire and as a consequence had a higher VOC OH reactivity than the SS. The SS lofted aged fire tracers along with other boundary layer ozone precursors and was more impacted by lightning NO_x (LNO_x) than the NS. The NCAR master mechanism box model was initialized with measurements made in the outflow of the two storms. The NS and SS were predicted to produce 11 and 14 ppbv of O_3, respectively, downwind of the storm over 2 days. Sensitivity tests revealed that the ozone production potential of the SS was highly dependent on LNO_x. Normalized excess mixing ratios, ΔX/ΔCO, for HCN and ACN were determined in both the fire plume and the storm outflow and found to be 7.0 ± 0.5 and 2.3 ± 0.5 pptv ppbv^(−1), respectively, and 1.4 ± 0.3 pptv ppbv^(−1) for acrolein in the outflow only

Global and regional effects of the photochemistry of CH_3O_2NO_2: evidence from ARCTAS

Using measurements from the NASA Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) experiment, we show that methyl peroxy nitrate (CH_3O_2NO_2) is present in concentrations of ~5–15 pptv in the springtime arctic upper troposphere. We investigate the regional and global effects of CH_3O_2NO_2 by including its chemistry in the GEOS-Chem 3-D global chemical transport model. We find that at temperatures below 240 K inclusion of CH_3O_2NO_2 chemistry results in decreases of up to ~20 % in NO_x, ~20 % in N_2O_5, ~5 % in HNO3, ~2 % in ozone, and increases in methyl hydrogen peroxide of up to ~14 %. Larger changes are observed in biomass burning plumes lofted to high altitude. Additionally, by sequestering NO_x at low temperatures, CH_3O_2NO_2 decreases the cycling of HO_2 to OH, resulting in a larger upper tropospheric HO_2 to OH ratio. These results may impact some estimates of lightning NO_x sources as well as help explain differences between models and measurements of upper tropospheric composition

Effect of topology on the transport properties of two interacting dots

The transport properties of a system of two interacting dots, one of them directly connected to the leads constituting a side-coupled configuration (SCD), are studied in the weak and strong tunnel-coupling limits. The conductance behavior of the SCD structure has new and richer physics than the better studied system of two dots aligned with the leads (ACD). In the weak coupling regime and in the case of one electron per dot, the ACD configuration gives rise to two mostly independent Kondo states. In the SCD topology, the inserted dot is in a Kondo state while the side-connected one presents Coulomb blockade properties. Moreover, the dot spins change their behavior, from an antiferromagnetic coupling to a ferromagnetic correlation, as a consequence of the interaction with the conduction electrons. The system is governed by the Kondo effect related to the dot that is embedded into the leads. The role of the side-connected dot is to introduce, when at resonance, a new path for the electrons to go through giving rise to the interferences responsible for the suppression of the conductance. These results depend on the values of the intra-dot Coulomb interactions. In the case where the many-body interaction is restricted to the side-connected dot, its Kondo correlation is responsible for the scattering of the conduction electrons giving rise to the conductance suppression

Is there a renormalization of the 1D conductance in Luttinger Liquid model?

Properties of 1D transport strongly depend on the proper choice of boundary conditions. It has been frequently stated that the Luttinger Liquid (LL) conductance is renormalized by the interaction as $g \frac{e^2} {h}$. To contest this result I develop a model of 1D LL wire with the interaction switching off at the infinities. Its solution shows that there is no renormalization of the universal conductance while the electrons have a free behavior in the source and drain reservoirs.Comment: 5 pages, RevTex 2.0, attempted repair of tex error

Spectral Function in Mott Insulating Surfaces

We show theoretically the fingerprints of short-range spiral magnetic correlations in the photoemission spectra of the Mott insulating ground states realized in the triangular silicon surfaces K/Si(111)-B and SiC(0001). The calculated spectra present low energy features of magnetic origin with a reduced dispersion ~10-40 meV compared with the center-of-mass spectra bandwidth ~0.2-0:3 eV. Remarkably, we find that the quasiparticle signal survives only around the magnetic Goldstone modes. Our findings would position these silicon surfaces as new candidates to investigate non-conventional quasiparticle excitations.Comment: 5 pages, 4 figures. To be published in Journal of Physics: Condensed Matte

Biomass burning and urban air pollution over the Central Mexican Plateau

Observations during the 2006 dry season of highly elevated concentrations of cyanides in the atmosphere above Mexico City (MC) and the surrounding plains demonstrate that biomass burning (BB) significantly impacted air quality in the region. We find that during the period of our measurements, fires contribute more than half of the organic aerosol mass and submicron aerosol scattering, and one third of the enhancement in benzene, reactive nitrogen, and carbon monoxide in the outflow from the plateau. The combination of biomass burning and anthropogenic emissions will affect ozone chemistry in the MC outflow

Massive Spin Collective Mode in Quantum Hall Ferromagnet

It is shown that the collective spin rotation of a single Skyrmion in quantum Hall ferromagnet can be regarded as precession of the entire spin texture in the external magnetic field, with an effective moment of inertia which becomes infinite in the zero g-factor limit. This low-lying spin excitation may dramatically enhance the nuclear spin relaxation rate via the hyperfine interaction in the quantum well slightly away from filling factor equal one.Comment: 4 page

Transport in an inhomogeneous interacting one--dimensional system

Transport through a one--dimensional wire of interacting electrons connected to semi--infinite leads is investigated using a bosonization approach. An incident electron is transmitted as a sequence of partial charges. The dc conductance is found to be entirely determined by the properties of the leads. The dynamic nonlocal conductivity is rigorously expressed in terms of the transmission. For abrupt variations of the interaction parameters at the junctions the central wire acts as a Fabry--Perot resonator. When one of the connected wires has a tendency towards superconducting order, partial Andreev reflection of an incident electron occurs.Comment: 11 pages, RevTeX 3.0, 1 postscript figure, everything in a uuencoded fil

Atmospheric Acetaldehyde: Importance of Air-Sea Exchange and a Missing Source in the Remote Troposphere.

We report airborne measurements of acetaldehyde (CH3CHO) during the first and second deployments of the National Aeronautics and Space Administration (NASA) Atmospheric Tomography Mission (ATom). The budget of CH3CHO is examined using the Community Atmospheric Model with chemistry (CAM-chem), with a newly-developed online air-sea exchange module. The upper limit of the global ocean net emission of CH3CHO is estimated to be 34 Tg a-1 (42 Tg a-1 if considering bubble-mediated transfer), and the ocean impacts on tropospheric CH3CHO are mostly confined to the marine boundary layer. Our analysis suggests that there is an unaccounted CH3CHO source in the remote troposphere and that organic aerosols can only provide a fraction of this missing source. We propose that peroxyacetic acid (PAA) is an ideal indicator of the rapid CH3CHO production in the remote troposphere. The higher-than-expected CH3CHO measurements represent a missing sink of hydroxyl radicals (and halogen radical) in current chemistry-climate models