3 research outputs found
In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia)
Layers rich in chromian spinel (Cr-spinel) occur in numerous differentiated and layered intrusions. These layers are often characterized by elevated and even economic concentrations of platinum-group-elements (PGEs), but only scarce sulfide mineralization. One particular type of such lithology occurs in the roof parts of the Norilsk-type differentiated intrusions (Russia) and is referred to as the "sulfide-poor PGE ores". We investigated rocks containing variable enrichments in Cr-spinel, sulfides, and platinum-group minerals (PGMs) from two sections of the upper zone of the Norilsk-1 intrusion, with a focus on Cr-spinel. The rocks are dominated by two lithological types: (1) leucogabbro/troctolitic and (2) olivine-gabbro. Fine-grained (5-100 mu m) disperse disseminations with varying modal abundances of Cr-spinel are characteristic for the rocks studied. Those abundances range from scarce mineralization through to very dense (up to 30 vol. % Cr-spinel) cloud-like accumulations. However, compact-grained accumulations and cumulate-like textures, which are typical for chromitites of layered intrusions, are not characteristic for the studied rocks. Instead, the disseminations exhibit chain- and trail-like alignments of Cr-spinel grains, which cross the boundaries between enclosing silicates, and sub-circular arrangements. The study revealed millimeter-scaled patchy distribution of Cr-spinel compositions within a given dissemination with Cr-spinel chemistry being strongly correlated with a kind of the enclosing silicate. (1) In unaltered rocks, plagioclase hosts more magnesian Cr-spinel (Mg# 30-60), while Cr-spinel in mafic minerals is less magnesian (Mg# 18-35). (2) In altered rocks, more magnesian Cr-spinel is hosted by less altered silicates, while strongly altered silicates mainly host less magnesian Cr-spinel. Systematics of trivalent cations exhibits divergent trends, even on a scale of a thin section, and depends on a kind of hosting lithology. Leucogabbro/troctolite lithologies contain Cr-spinel with anomalously low Fe(3+)and extremely high Ti contents, whereas Cr-spinel from olivine-gabbro lithologies have moderate Fe(3+)and moderately-high Ti contents. It is envisaged that crystallization of Cr-spinel and their host rocks occurred from viscous mingled magmas, which had different compositions and redox state. Subsequent processes involved (1) high-temperature re-equilibration of Cr-spinel with enclosing silicates and (2) post-magmatic alteration and partial recrystallization of Cr-spinel. During these processes, Cr-spinel was losing Mg and Al and gaining Fe and Ti. These chemical trends are generally coincident with those established for other intrusions worldwide, but the upper zone of the Norilsk-1 intrusion seems to possess an exceptional variety of Cr-spinel compositions, not recorded elsewhere.Peer reviewe
Early Triassic Monzonite–Granite Series in Eastern Kazakhstan as a Reflection of Siberian Large Igneous Province Activity
We provide the results of studying the internal structure and composition of the rocks of the Semeitau and Delbegetei massifs located in Eastern Kazakhstan. It was previously believed that these massifs have different ages and were formed in different geodynamic settings. The U-Pb zircon age from the monzonites and quartz monzonites was determined to be 249 ± 2 Ma, which showed the same Early Triassic age of the massifs. Both massifs are composed of rocks of the same monzonite–granite series of rocks with a significant proportion of high-silica rocks (leucocratic granites). Intermediate rocks are formed due to the differentiation of subalkaline mafic magmas, and the felsic rocks (rhyolites and granites) are the result of partial melting of crustal substrates. The massif formation model assumes the intrusion of mafic magmas into the crust, their differentiation and mixing with crustal melts, and then the intrusion of various rocks into the upper crustal levels. Analysis of the geological position, age and composition of the rocks allows us to conclude that the Semeitau and Delbegetei massifs were formed in an intraplate geodynamic setting. The activity of the mantle plume is the most probable reason for their formation. The Semeitau and Delbegetei massifs can be included in the southern part of the range of the Early Triassic Siberian Large Igneous Province
Early Triassic Monzonite–Granite Series in Eastern Kazakhstan as a Reflection of Siberian Large Igneous Province Activity
We provide the results of studying the internal structure and composition of the rocks of the Semeitau and Delbegetei massifs located in Eastern Kazakhstan. It was previously believed that these massifs have different ages and were formed in different geodynamic settings. The U-Pb zircon age from the monzonites and quartz monzonites was determined to be 249 ± 2 Ma, which showed the same Early Triassic age of the massifs. Both massifs are composed of rocks of the same monzonite–granite series of rocks with a significant proportion of high-silica rocks (leucocratic granites). Intermediate rocks are formed due to the differentiation of subalkaline mafic magmas, and the felsic rocks (rhyolites and granites) are the result of partial melting of crustal substrates. The massif formation model assumes the intrusion of mafic magmas into the crust, their differentiation and mixing with crustal melts, and then the intrusion of various rocks into the upper crustal levels. Analysis of the geological position, age and composition of the rocks allows us to conclude that the Semeitau and Delbegetei massifs were formed in an intraplate geodynamic setting. The activity of the mantle plume is the most probable reason for their formation. The Semeitau and Delbegetei massifs can be included in the southern part of the range of the Early Triassic Siberian Large Igneous Province