7 research outputs found
Driving force and mechanism for spontaneous metal whisker formation
Physical Review Letters, 93(20): pp. 206104-1—206104-4. Retrieved September 19, 2006 from http://www.mse.drexel.edu/max/pdf%20references/drexel_pdfs/papers/WhiskesPRL_2004.pdf. DOI: http://dx.doi.org/10.1103/PhysRevLett.93.206104The room temperature spontaneous growth of low melting point metal whiskers, such as Sn, poses a
serious reliability problem in the semiconducting industry; a problem that has become acute with the
introduction of Pb-free technology. To date, this 50+ year old problem has resisted interpretation.
Herein we show that the driving force is essentially a reaction between oxygen and the sprouting metal.
The resulting volume expansion creates a compressive stress that pushes the whiskers up. The model
proposed explains our observations on In and Sn whiskers and many past observations. The solution is
in principle simple: diffusion of oxygen into the metal must be prevented or slowed down. This was
demonstrated by coating the active surfaces with a polymer coating
On the spontaneous growth of soft metallic whiskers
Electrical Contacts, Proceedings of the Annual Holm Conference on Electrical Contacts, September 2005: pp. 121-126.The room temperature spontaneous growth of low
melting point metal whiskers, such as Sn, poses a serious
reliability problem in the semiconducting industry; a problem
that has become acute with the introduction of Pb-free solder
technology. Recently it was shown that the driving force is most
probably a reaction between oxygen and the sprouting metal. [1]
The resulting volume expansion creates a compressive stress that
pushes the whiskers up. The model proposed explains
observations on In and Sn whiskers as well as many past
observations. Herein further evidence is presented for, and
discussion of, the proposed model. Stresses, calculated using
finite element modeling, are reasonable and in line with
measured values. Based on this work, a potential solution to the
whisker problem is in principle simple: either slow or prevent the
diffusion of oxygen into the soft metal or, more practically and
effectively, work with larger grained solder, which should reduce
the magnitude of the compressive stresses
Elasto-viscoplasticity of isotropic porous metals
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 1992.Includes bibliographical references (leaves 287-297).by Antonios I. Zavaliangos.Ph.D