1 research outputs found
[(F<sub>6</sub>acac)Pd(μ-HNC<sub>6</sub>F<sub>5</sub>)]<sub>2</sub>, a Large Family of Polymorphs and Solvates with Short F···F Contacts
Highly fluorinated
[(F6acac)Pd(μ-HNC6F5)]2 was prepared by the reaction of palladium
bis(hexafluoroacetylacetonate), Pd(F6acac)2, with pentafluoroaniline. This compound generates
a large family of crystalline polymorphs and solvates. In this paper,
we present a study on the synthesis, solution phase dynamics, and
crystal structures of highly fluorinated [(F6acac)Pd(μ-HNC6F5)]2. Pd3(μ-F6acac)2(μ-HNC6F5)4 is produced as a minor byproduct. We also describe the synthesis
and structural characterization of trinuclear Pd3(μ-F6acac)3[μ-(CF3)2CN]3 prepared by the reaction of Pd(F6acac)2 with hexafluoroacetone imine