Exploiting classical nucleation theory for reverse self-assembly

In this paper we introduce a new method to design interparticle interactions to target arbitrary crystal structures via the process of self-assembly. We show that it is possible to exploit the curvature of the crystal nucleation free-energy barrier to sample and select optimal interparticle interactions for self-assembly into a desired structure. We apply this method to find interactions to target two simple crystal structures: a crystal with simple cubic symmetry and a two-dimensional plane with square symmetry embedded in a three-dimensional space. Finally, we discuss the potential and limits of our method and propose a general model by which a functionally infinite number of different interaction geometries may be constructed and to which our reverse self-assembly method could in principle be applied.Comment: 7 pages, 6 figures. Published in the Journal of Chemical Physic

Accurate radial velocity and metallicity of the Large Magellanic Cloud old globular clusters NGC1928 and NGC1939

We present results obtained from spectroscopic observations of red giants located in the fields of the Large Magellanic Cloud (LMC) globular clusters (GCs) NGC1928 and NGC1939. We used the GMOS and AAOmega+2dF spectrographs to obtain spectra centred on the Ca II triplet, from which we derived individual radial velocities (RVs) and metallicities. From cluster members we derived mean RVs of RVNGC1928 = 249.58±4.65 km s-1 and RVNGC1939 = 258.85±2.08 km s-1, and mean metallicities of [Fe/H]NGC1928 = -1.30±0.15 dex and [Fe/H]NGC1939 = -2.00±0.15 dex. We found that both GCs have RVs and positions consistent with being part of the LMC disc, so that we rule out any possible origin, but in the same galaxy. By computing the best solution of a disc that fully contains each GC, we obtained circular velocities for the 15 known LMC GCs. We found that 11/15 of the GCs share the LMC rotation derived from HST and Gaia DR2 proper motions. This outcome reveals that the LMC disc existed since the very early epoch of the galaxy formation and experienced the steep relatively fast chemical enrichment shown by its GC metallicities. The four remaining GCs turned out to have circular velocities not compatible with an in situ cluster formation, but rather with being stripped from the SMC.Fil: Piatti, Andres Eduardo. Universidad Nacional de Córdoba. Observatorio Astronómico de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Hwang, N.. Korea Astronomy And Space Science Institute; Corea del SurFil: Cole, A. A.. University of Tasmania; AustraliaFil: Angelo, M. S.. Laboratorio Nacional de Astrofisica; BrasilFil: Emptage, B.. University of Tasmania; Australi