All-optical control of molecular fluorescence

We present a quantum electrodynamical procedure to demonstrate the all-optical control of molecular fluorescence. The effect is achieved on passage of an off-resonant laser beam through an optically activated system; the presence of a surface is not required. Following the derivation and analysis of the all-optical control mechanism, calculations are given to quantify the significant modification of spontaneous fluorescent emission with input laser irradiance. Specific results are given for molecules whose electronic spectra are dominated by transitions between three electronic levels, and suitable laser experimental methods are proposed. It is also shown that the phenomenon is sensitive to the handedness of circularly polarized throughput, producing a conferred form of optical activity

Optically controlled resonance energy transfer:Mechanism and configuration for all-optical switching

In a molecular system of energy donors and acceptors, resonance energy transfer is the primary mechanism by means of which electronic energy is redistributed between molecules, following the excitation of a donor. Given a suitable geometric configuration it is possible to completely inhibit this energy transfer in such a way that it can only be activated by application of an off-resonant laser beam: this is the principle of optically controlled resonance energy transfer, the basis for an all-optical switch. This paper begins with an investigation of optically controlled energy transfer between a single donor and acceptor molecule, identifying the symmetry and structural constraints and analyzing in detail the dependence on molecular energy level positioning. Spatially correlated donor and acceptor arrays with linear, square, and hexagonally structured arrangements are then assessed as potential configurations for all-optical switching. Built on quantum electrodynamical principles the concept of transfer fidelity, a parameter quantifying the efficiency of energy transportation, is introduced and defined. Results are explored by employing numerical simulations and graphical analysis. Finally, a discussion focuses on the advantages of such energy transfer based processes over all-optical switching of other proposed forms. © 2008 American Institute of Physics

Laser-controlled fluorescence in two-level systems

The ability to modify the character of fluorescent emission by a laser-controlled, optically nonlinear process has recently been shown theoretically feasible, and several possible applications have already been identified. In operation, a pulse of off-resonant probe laser beam, of sufficient intensity, is applied to a system exhibiting fluorescence, during the interval of excited- state decay following the initial excitation. The result is a rate of decay that can be controllably modified, the associated changes in fluorescence behavior affording new, chemically specific information. In this paper, a two-level emission model is employed in the further analysis of this all-optical process; the results should prove especially relevant to the analysis and imaging of physical systems employing fluorescent markers, these ranging from quantum dots to green fluorescence protein. Expressions are presented for the laser-controlled fluorescence anisotropy exhibited by samples in which the fluorophores are randomly oriented. It is also shown that, in systems with suitably configured electronic levels and symmetry properties, fluorescence emission can be produced from energy levels that would normally decay nonradiatively. © 2010 American Chemical Society

Interparticle interactions:Energy potentials, energy transfer, and nanoscale mechanical motion in response to optical radiation

In the interactions between particles of material with slightly different electronic levels, unusually large shifts in the pair potential can result from photoexcitation, and on subsequent electronic excitation transfer. To elicit these phenomena, it is necessary to understand the fundamental differences between a variety of optical properties deriving from dispersion interactions, and processes such as resonance energy transfer that occur under laser irradiance. This helps dispel some confusion in the recent literature. By developing and interpreting the theory at a deeper level, one can anticipate that in suitable systems, light absorption and energy transfer will be accompanied by significant displacements in interparticle separation, leading to nanoscale mechanical motion

Optical-radar imaging of scale models for studies in asteroid astronomy

During the past five years, delay-Doppler radar has become the primary technique for studying the structure of Earth-crossing asteroids. None of these objects has yet been visited by spacecraft, so ground-truth test cases are lacking. A laboratory system is described that provides optical-radar images at 0.1-mm resolution. These data are analogous to the highest-resolution asteroid radar images currently available and provided realistic test cases for developing signal-processing techniques. The system can be thought of as a 1/188,000 scale model of the Arecibo radar, or a 1/52,800 scale model of the Goldstone radar

Talking with experts - from research to objects: using academic research as the basis of collaborative and cross disciplinary projects for design students

The role of design is changing and after postmodern design, in which design seemed to be more related to production, business and marketing, we are currently looking at ‘the translation of scientific and technological research into tangible objects that change people's lives’ as one of the most fundamental roles of design [1]. In the majority of Higher Education institutions a significant amount of research takes place and there is considerable potential to develop applications from the results of these activities, many of which are not fully exploited. The primary aim of this project was to investigate how design methods can be used to bridge the gap between the abstraction of research and the tangible requirements of everyday life. A project targeted second year students was developed to explore this concept; it was also an opportunity for students to challenge their familiar working methods by being collaborative and interdisciplinary. First they formed teams and identified examples of scientific and engineering research expertise; they then contacted the research active academic staff working in these fields and carried out a video interview. They analysed their findings and gave a presentation outlining their approach and design development for an appropriate context. Finally the teams presented educational videos that explain and promote their design proposals to expert and non-expert audiences. The paper includes several examples of these design proposals and illustrates the benefits of collaboration for students and to researchers who see how their work can be interpreted and developed into real world tangible applications

Chiral discrimination in optical binding

The laser-induced intermolecular force that exists between two or more particles in the presence of an electromagnetic field is commonly termed “optical binding.” Distinct from the single-particle forces that are at play in optical trapping at the molecular level, the phenomenon of optical binding is a manifestation of the coupling between optically induced dipole moments in neutral particles. In other, more widely known areas of optics, there are many examples of chiral discrimination—signifying the different response a chiral material has to the handedness of an optical input. In the present analysis, extending previous work on chiral discrimination in optical binding, a mechanism is identified using a quantum electrodynamical approach. It is shown that the optical binding force between a pair of chiral molecules can be significantly discriminatory in nature, depending upon both the handedness of the interacting particles and the polarization of the incident light, and it is typically several orders of magnitude larger than previously reported