2 research outputs found
Ultrathin Oxide Films by Atomic Layer Deposition on Graphene
In this paper, a method is presented to create and characterize
mechanically robust, free-standing, ultrathin, oxide films with controlled,
nanometer-scale thickness using atomic layer deposition (ALD) on graphene.
Aluminum oxide films were deposited onto suspended graphene membranes
using ALD. Subsequent etching of the graphene left pure aluminum oxide
films only a few atoms in thickness. A pressurized blister test was
used to determine that these ultrathin films have a Young’s
modulus of 154 ± 13 GPa. This Young’s modulus is comparable
to much thicker alumina ALD films. This behavior indicates that these
ultrathin two-dimensional films have excellent mechanical integrity.
The films are also impermeable to standard gases suggesting they are
pinhole-free. These continuous ultrathin films are expected to enable
new applications in fields such as thin film coatings, membranes,
and flexible electronics
Effect of Al<sub>2</sub>O<sub>3</sub> Coating on Stabilizing LiNi<sub>0.4</sub>Mn<sub>0.4</sub>Co<sub>0.2</sub>O<sub>2</sub> Cathodes
Using atomic layer deposition of
Al<sub>2</sub>O<sub>3</sub> coating,
improved high-voltage cycling stability has been demonstrated for
the layered nickel–manganese–cobalt pseudoternary oxide,
LiNi<sub>0.4</sub>Mn<sub>0.4</sub>Co<sub>0.2</sub>O<sub>2</sub>. To
understand the effect of the Al<sub>2</sub>O<sub>3</sub> coating,
we have utilized electrochemical impedance spectroscopy, operando
synchrotron-based X-ray diffraction, and operando X-ray absorption
near edge fine structure spectroscopy to characterize the structure
and chemistry evolution of the LiNi<sub>0.4</sub>Mn<sub>0.4</sub>Co<sub>0.2</sub>O<sub>2</sub> cathode during cycling. Using this combination
of techniques, we show that the Al<sub>2</sub>O<sub>3</sub> coating
successfully mitigates the strong side reactions of the active material
with the electrolyte at higher voltages (>4.4 V), without restricting
the uptake and release of Li ions. The impact of the Al<sub>2</sub>O<sub>3</sub> coating is also revealed at beginning of lithium deintercalation,
with an observed delay in the evolution of oxidation and coordination
environment for the Co and Mn ions in the coated electrode due to
protection of the surface. This protection prevents the competing
side reactions of the electrolyte with the highly active Ni oxide
sites, promoting charge compensation via the oxidation of Ni and enabling
high-voltage cycling stability