6 research outputs found
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Effect of High-Temperature Aging on the Thermal Conductivity of Nanocrystalline Tetragonal Yttria-stabilized Zirconia
The thermal conductivity of yttria-stabilized zirconia (YSZ) thermal barrier coatings increases with high-temperature aging. This common observation has been attributed to the densification of the coatings as porosity sinters out and pores and cracks spheroidize to minimize their surface energy. We show that the thermalconductivity of fully-dense 3 mol. % YO stabilized zirconia (3YSZ) also increases with high-temperature aging, indicating that densification and pore shape changes alone are not responsible for all the observed increase in thermalconductivity of coatings. Instead, there are also increases due to a combination of phase separation and grain growth. The increase in thermal conductivity can be described by a Larson–Miller parameter. It is also found that the increase in thermal conductivity with aging is greatest when measured at room temperature and decreases with increasing measurement temperature. Measured at 1000 °C, the thermal conductivity of zirconia is almost temperature independent and the changes in thermal conductivity with aging are less than 15%, even after aging for 50 h at 1400 °C.Physic
Fabrication of Thin, Luminescent, Single-crystal Diamond Membranes
The formation of single-crystal diamond membranes is an important
prerequisite for the fabrication of high-quality optical cavities in this
material. Diamond membranes fabricated using lift-off processes involving the
creation of a damaged layer through ion implantation often suffer from residual
ion damage, which severely limits their usefulness for photonic structures. The
current work demonstrates that strategic etch removal of the most highly
defective material yields thin, single-crystal diamond membranes with strong
photoluminescence and a Raman signature approaching that of single-crystal bulk
diamond. These optically-active membranes can form the starting point for
fabrication of high-quality optical resonators.Comment: To appear in AP
Local structure evolution in polycrystalline ZnMgO () studied by Raman and by synchrotron x-ray pair distribution analysis
The local structures of ZnMgO alloys have been studied by Raman
spectroscopy and by synchrotron x-ray pair distribution function (PDF)
analysis. Within the solid solution range () of
ZnMgO, the wurtzite framework is maintained with Mg homogeneously
distributed throughout the wurtzite lattice. The Raman line
of ZnMgO displays systematic changes in response to the evolution
of the crystal lattice upon the Mg-substitution. The red-shift and broadening
of the mode are explained by the expansion of hexagonal
-dimensions, and compositional disorder of Zn/Mg, respectively. Synchrotron
x-ray PDF analyses of ZnMgO reveal that the Mg atoms have a
slightly reduced wurtzite parameter and more regular tetrahedral bond
distances than the Zn atoms. For both Zn and Mg, the internal tetrahedral
geometries are independent of the alloy composition.Comment: 10 pages, 12 figures RevTe
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Thermal conductivity of single- and multi-phase compositions in the ZrO2–Y2O3–Ta2O5 system
Compositions in the ZrO2-Y2O3-Ta2O5 system are of interest as low thermal conductivity, fracture resistant oxides for the next generation thermal barrier coatings (TBC). Multiple phases occur in the system offering the opportunity to compare the thermal properties of single, two-phase, and three-phase materials. Despite rather large variations in compositions almost all the solid solution compounds had rather similar thermal conductivities and, furthermore, exhibited only relatively small variations with temperature up to 1000oC. These characteristics are attributed to the extensive mass disorder in all the compounds and, in turn, small interfacial Kapitza (thermal) resistances. More complicated behavior, associated with the transformation from the tetragonal to monoclinic phase, occurs on long-term annealing in air of some of the compositions. However, the phases in two of the compositional regions do not change with annealing in air and their thermal conductivities remain unchanged suggesting they may be suitable for further exploration as thermally stable TBC overcoats.Engineering and Applied Science