The Full Re-Ionization of Helium

Observations of resolved HeII Lyman alpha absorption in spectra of two QSO's suggest that the epoch of helium ionization occurred at z~3. Proximity zones in the spectra of the quasars (z=3.18, 3.285) at 304 A resemble Stromgren spheres, suggesting that the intergalactic medium is only singly ionized in helium. We present models of the proximity effect which include the full physics of the ionization, heating and cooling and an accurately simulated inhomogeneous gas distribution. In these models the underdense intergalactic medium is heated to at least 10,000-20,000 K after cooling to as low as a few 1000 K due to cosmological expansion, with higher temperatures achieved farther away from the quasar due to absorption-hardened ionizing spectra. The quasars turn on for a few times 10^7 years with a fairly steady flux output at 228 A comparable to the 304 A flux output directly observed with HST. The recoveries in the spectra occur naturally due to voids in the IGM and may provide a fairly model-independent probe of the baryon density.Comment: 5 pages, 3 figures, to appear in the proceedings of "After the Dark Ages: When Galaxies were Young (the Universe at 2<z<5)", 9th Annual October Astrophysics Conference in Marylan

Structure/activity relationships applied to the hydrogenation of α,β-unsaturated carbonyls: The hydrogenation of 3-butyne-2-one over alumina-supported palladium catalysts

The gas phase hydrogenation of 3-butyne-2-one, an alkynic ketone, over two alumina-supported palladium catalysts is investigated using infrared spectroscopy in a batch reactor at 373 K. The mean particle size of the palladium crystallites of the two catalysts are comparable (2.4 ± 0.1 nm). One catalyst (Pd(NO3)2/Al2O3) is prepared from a palladium(II) nitrate precursor, whereas the other catalyst (PdCl2/Al2O3) is prepared using palladium(II) chloride as the Pd precursor compound. A three-stage sequential process is observed with the Pd(NO3)2/Al2O3 catalyst facilitating complete reduction all the way through to 2-butanol. However, hydrogenation stops at 2-butanone with the PdCl2/Al2O3 catalyst. The inability of the PdCl2/Al2O3 catalyst to reduce 2-butanone is attributed to the inaccessibility of edge sites on this catalyst, which are blocked by chlorine retention originating from the catalyst’s preparative process. The reaction profiles observed for the hydrogenation of this alkynic ketone are consistent with the site-selective chemistry recently reported for the hydrogenation of crotonaldehyde, an alkenic aldehyde, over the same two catalysts. Thus, it is suggested that a previously postulated structure/activity relationship may be generic for the hydrogenation of α,β-unsaturated carbonyl compounds over supported Pd catalysts

Mapping Low-Density Intergalactic Gas: a Third Helium Lyman-alpha Forest

We present a new HST/STIS spectrum of the z=3.18 quasar PKS 1935-692 and summarize the spectral features shortwards of 304A in the rest frame likely to be caused by foreground HeII Lyman-alpha absorption. In accord with previous results on two other quasars at similar redshifts, we demonstrate a correlation with the HI Lyman-alpha forest absorption, and show that much of the helium absorption is caused by a comparable quantity of more diffuse gas with Omega~0.01, that is not detected in HI. The helium ionization zone around the quasar is detected as well as a void seen in both HI and HeII. The properties of the absorption are in broad agreement with those of the other quasars and with models of the protogalactic gas distribution and ionization at this redshift.Comment: 17 pages including 5 figures. As accepted for publication in The Astronomical Journal (minor revisions

Resolving the Helium Lyman-α\alpha Forest: Mapping Intergalactic Gas and Ionizing Radiation at z≈3z\approx 3

We present a new, high resolution HST/GHRS spectrum of quasar Q0302-003, and use the HeII Lyman-$\alpha$ absorption, together with a high resolution Keck spectrum of the HI Lyman-$\alpha$ forest, to probe the distribution and ionization state of foreground gas just below the quasar redshift $z\approx 3.3$. The main new conclusions from the current data are: 1. The HeII Lyman-$\alpha$ forest is detected; 2. The ``diffuse'' (redshift-space-filling) medium is also detected, and must have a low density ($\Omega\le 0.01 (h/0.7)^{-3/2}$) consistent with standard primordial nucleosynthesis and models of early gas collapse into protogalaxies; 3. The intergalactic ionizing spectrum is soft ($\eta\ge 100$), although the intergalactic helium is probably mostly doubly ionized by $z=3.3$; 4. The helium abundance is within a factor of a few of standard Big Bang predictions, over a large volume of space at high redshift.Comment: AAS Latex, 3 figures, accepted for publication in the Astronomical Journa

Millimeter and Submillimeter Survey of the R Corona Australis Region

Using a combination of data from the Antarctic Submillimeter Telescope and Remote Observatory (AST/RO), the Arizona Radio Observatory Kitt Peak 12m telescope and the Arizona Radio Observatory 10m Heinrich Hertz Telescope, we have studied the most active part of the R CrA molecular cloud in multiple transitions of Carbon Monoxide, HCO$^+$ and 870\micron continuum emission. Since R CrA is nearby (130 pc), we are able to obtain physical spatial resolution as high as 0.01pc over an area of 0.16 pc$^2$, with velocity resolution finer than 1 km/s. Mass estimates of the protostar driving the mm-wave emission derived from HCO$^+$, dust continuum emission and kinematic techniques point to a young, deeply embedded protostar of $\sim$0.5-0.75 M$_\odot$, with a gaseous envelope of similar mass. A molecular outflow is driven by this source that also contains at least 0.8 M$_\odot$ of molecular gas with $\sim$0.5 L$_\odot$ of mechanical luminosity. HCO$^+$ lines show the kinematic signature of infall motions as well as bulk rotation. The source is most likely a Class 0 protostellar object not yet visible at near-IR wavelengths. With the combination of spatial and spectral resolution in our data set, we are able to disentangle the effects of infall, rotation and outflow towards this young object.Comment: 29 pages, 9 figures. Accepted for publication in the Astrophysical Journa

Contributions to the Science of Environmental Impact Assessment: Three Papers on the Arctic Cisco (Coregonus autumnalis) of Northern Alaska

Editor's Introduction -- D. W. Norton; An Assessment of the Colville River Delta Stock of Arctic Cisco--Migrants from Canada? -- B. J. Gallaway, W. B. Griffiths, P. C. Craig, W. J. Gazey, and J. W. Helmericks; Temperature Preference of Juvenile Arctic Cisco (Coregonus autumnalis) From the Alaskan Beaufort Sea -- R. G. Fechhelm, W. H. Neill, and B. J. Gallaway; Modeling Movements and Distribution of Arctic Cisco (Coregonus autumnalis) Relative to Temperature-Salinity Regimes of the Beaufort Sea Near the Waterflood Causeway, Prudhoe Bay, Alaska. -- W. H. Neill, R. G. Fechhelm, B. J. Gallaway, J. D. Bryan, and S. W. Anderson; Notice to Author

Scanning Electron Microscopy Analysis of Murine Renal, Aortic, and Cardiac Tissue

Scanning electron microscopy (SEM) is a tool that provides detailed insight into objects invisible to the human eye. As the name suggests, an electron beam is used to create an image down to the nanometer scale. The beam focuses on the surface of a sample using lenses in the electron column. In this project, we use SEM to study three types of murine tissue. First, we examine the glomerulus, found in the kidney, that is primarily responsible for filtering blood. Following a left renal vein (LRV) stenosis, SEM is used to observe changes to the glomeruli. Differences in the left and right kidney glomeruli are noted, with glomeruli appearing intact from the right kidney, while glomeruli from the left kidney are broken down. These findings are vital for preeclampsia studies, where these glomerular changes are likely a result of renal ischemia induced by the LRV stenosis. Second, cross sections of the murine descending aorta with a type B aortic dissection are examined under SEM. High magnification images reveal the morphology of red blood cell types in the false lumen. These findings will be used for studies in evaluating medical interventions for aortic dissection. Third, we examine tissue from the left ventricle and atrium of the murine heart. SEM can be used to detect if hypertrophy caused by transverse aortic constriction causes changes to cells lining the endocardium. This project demonstrates that SEM provides high resolution and magnification images, revealing new information that is pivotal to current and future biomedical studies