Macrocyclic Antibiotics as Separation Agents

Macrocyclic antibiotics having ring structures with at least 10 members act as separation agents in crystallization, precipitation, filtration, electrophoresis and chromatography. The macrocyclic antibiotics include ansamacrolides, macrolides, marocyclic peptides, polyenes and derivatives thereof. The process has been found to be especially advantageous for separation of optical isomers by electrophoresis and chromatography

Predictive value of respiratory symptoms and bronchial hyperresponsiveness to diagnose asthma in New Zealand

SummaryRespiratory symptoms are often used as the only diagnostic criteria for asthma in epidemiological surveys and the clinical diagnosis of asthma relies primarily on a detailed history. The aim of this study is to predict the diagnostic value of 11 different respiratory symptoms to diagnose asthma, and to determine if bronchial hyperresponsiveness (BHR) improves the predictive value of these respiratory symptoms.A random sample of 1257 subjects aged 20–44 years old in 3 different areas of New Zealand were selected between March 1991 and December 1992 to answer the European Community Respiratory Health Survey questionnaire on respiratory symptoms. Of these, 784 underwent bronchial challenge with methacholine. The prevalence of current doctor diagnosed asthma (DDA) defined as asthma confirmed by a physician and an asthma attack in the last 12 months was 8.3%. Wheezing with dyspnoea is the single best predictor of diagnosed asthma with a sensitivity of 82%, a specificity of 90% and a Youden's index of 0.72. Wheezing alone is more sensitive (94%) but less specific (76%), with a Youden's index of 0.70. The addition of BHR to asthma symptoms decreases sensitivity and increases specificity with a small increase in Youden's index to 0.75. In New Zealand adults, a history of wheezing with BHR best predicts a diagnosis of asthma but wheezing alone or with dyspnoea are the two best symptoms for predicting asthma

Focusing and Diffraction of Light by Periodic Si Micropyramidal Arrays

This research was devoted to modeling of the optical properties of Si micropyramids aimed at designing optimal structures for applications as light concentrators in mid-wave infrared (MWIR) focal place arrays (FPAs). It is shown that completely different optical properties of such structures can be realized using two types of boundary conditions (BCs): i) periodical and ii) perfectly matched layer. The first type (periodical BC) allowed us to describe the Talbot effect under plane wave coherent illumination conditions. This effect was experimentally demonstrated in the proposed structures. The second type (perfectly matched layer BC) allows describing the optical properties of individual micropyramids concentrating or focusing light on the photodetector. The optimal geometries of micropyramids required for maximizing the intensity of photonic nanojets emerging from their truncated tips are determined.Comment: 4 pages, 5 figures, GOMACTech 202

Manganese pigmented anodized copper as solar selective absorber

The study concerns the optical and structural properties of layers obtained by a new efficient surface treatment totally free of chromium species. The process is made up of an anodic oxidation of copper in an alkaline solution followed by an alkaline potassium permanganate dipping post-treatment. Coatings, obtained at the lab and pilot scales, are stable up to 220 °C in air and vacuum, present low emissivity (0.14 at 70 °C) and high solar absorptivity (0.96), i.e. a suitable thermal efficiency (0.84 at 70 °C)

Misteri natal

Surabayaxi, 114 p.; 18 cm

Evidence For Multiple Retention Mechanisms. Cyclodextrin Stationary Phases For The Gas-solid Chromatographic Separation Of Light Hydrocarbons

Cyclodextrin, bonded to silica gel and used as a gas-solid chromatographic (GSC) stationary phase provides a practical and efficient means for separating a wide variety of volatile C1-C7 hydrocarbons at ambient to elevated temperatures. Conditioning the columns at high temperature (300°C) for several hours increased efficiency and resolution. The adsorption of these light hydrocarbons involves multiple retention mechanismns. For unsaturated hydrocarbons, the cyclodextrin GSC column can act as a polar stationary phase analogous to silica gel. However, for saturated hydrocarbons, it acts as a non-polar phase. Evaluation of the columns and an analogous silica gel column with hydrocarbon standards is reported. Capacity factors and chromatograms are presented for compounds analyzed on these GSC stationary phases. © 1993