Pore Scale Observations of Trapped CO2 in Mixed-Wet Carbonate Rock: Applications to Storage in Oil Fields

Geologic CO2 storage has been identified as a key to avoiding dangerous climate change. Storage in oil reservoirs dominates the portfolio of existing projects due to favorable economics. However, in an earlier related work (Al-Menhali and Krevor Environ. Sci. Technol. 2016, 50, 2727−2734), it was identified that an important trapping mechanism, residual trapping, is weakened in rocks with a mixed wetting state typical of oil reservoirs. We investigated the physical basis of this weakened trapping using pore scale observations of supercritical CO2 in mixed-wet carbonates. The wetting alteration induced by oil provided CO2-wet surfaces that served as conduits to flow. In situ measurements of contact angles showed that CO2 varied from nonwetting to wetting throughout the pore space, with contact angles ranging 25° < θ < 127°; in contrast, an inert gas, N2, was nonwetting with a smaller range of contact angle 24° < θ < 68°. Observations of trapped ganglia morphology showed that this wettability allowed CO2 to create large, connected, ganglia by inhabiting small pores in mixed-wet rocks. The connected ganglia persisted after three pore volumes of brine injection, facilitating the desaturation that leads to decreased trapping relative to water-wet systems

On the collapse behaviour of oil reservoir chalk

Oil exploitation in North Sea Ekofisk oilfield started in 1971, the reservoir is located in a 150 m thick layer of porous chalk (n = 40-50%) at a 3000 m depth. Enhanced oil recovery procedure by sea water injection (waterflooding) was initiated in 1987. Starting from this date, seabed subsidence due to chalk compaction evolves at a fairly constant rate (i.e. 40 cm/year). Nowadays, the decrease of the seafloor level is of about 10 m. Reservoir management and production strategies are at the origin of the growing interest of petroleum industry in disposing of a comprehensive description of the chalk mechanical behaviour. In this note the subsidence due to waterflooding is interpreted within a framework taken from the mechanics of unsaturated soils. By considering oil as the non-wetting fluid and water as the wetting fluid, chalk compaction is depicted as a collapse phenomenon due to oil-water suction decrease. A series of suction controlled tests in the osmotic oedometer cell are presented. Water weakening effects and chalk compaction (collapse) seem likely to occur through the lost of strength of the inter-granular links existing in the oil saturated sample. The nature of these links includes both capillary and physico-chemical fluids-chalk interactions, and is well characterised by the oil-water suction