5 research outputs found
First Observation of the Baryon and a New Measurement of the Mass
Using data recorded with the CLEO II and CLEO II.V detector configurations at
the Cornell Electron Storage Rings, we report the first observation and mass
measurement of the charmed baryon, and an updated measurement
of the mass of the baryon. We find
= 231.0 +- 1.1 +- 2.0 MeV, and
= 166.4 +- 0.2 +- 0.3 MeV, where the errors are
statistical and systematic respectively.Comment: 8 pages postscript, also available through
http://w4.lns.cornell.edu/public/CLN
Search for the Familon via , , and Decays
We have searched for the two-body decay of the B meson to a light
pseudoscalar meson and a massless neutral
weakly-interacting particle such as the familon, the Nambu-Goldstone
boson associated with a spontaneously broken global family symmetry. We find no
significant signal by analyzing a data sample containing 9.7 million
mesons collected with the CLEO detector at the Cornell Electron Storage Ring,
and set a 90% C.L. upper limit of and
on the branching fraction for the decays and , respectively. These upper limits correspond to a lower bound of about
GeV on the family symmetry breaking scale involving the third
generation of quarks.Comment: 10 pages postscript, also available through
http://w4.lns.cornell.edu/public/CLN
Evaluation of Some Organic Inhibitors for Stainless Steel Corrosion Using Different Electrochemical and Surface Techniques
Stainless steels have been extensively used in automotive, industrial, electronics, etc., applications. Iron (Fe) and chromium (Cr) are the main elements with weight percentage contribution of 60-75% and 10-25% respectively. Other elements, such as Ni, Co, Mo, Mn, C etc. are also present with variable concentrations. The purpose of this work is to use different electrochemical and surface techniques to study the corrosion behavior of stainless steel type 316 (percent composition of different chemical elements are listed in table 1) in acid media in presence and absence of different thiophene derivatives (list of inhibitors in figure 1). Moreover, other important goals were to study the effect of adding chloride ion to the acidic media on the corrosion behavior of stainless steel, protection efficiency of ihibitors studied, and to determine the temperature coefficient and the adsorption isotherm of the inhibitor on the stainless steel type 316.
Electrochemical techniques such as potentiodynamic polarization, Tafel experiments, polarization resistance and electrochemical spectroscopy were used to evaluate the effect of the inhibitors on the corrosion of stainless steel type 316. Surface analyses were employed to study the surface morphology and structural analysis of the surface using scanning electron microscope(SEM), Fourier Transform infrared(FT-IR), and x-ray diffraction techniques EDAX.
The results showed distinct effects for the different inhibitors used that depend on the molecular structure and the electron density on the sulfur atom of the thiophene ring. The order of inhibition efficiency was 2-thiophene carboxylic hydrazide \u3e 2-thiophene carboxylic acid \u3e 3- thiophene caroxaldhyde \u3e 2-acetyl thiophene. It was concluded that the inhibitors studied were of the mixed type.
The adsorption pattern for the inhibitors at the stainless steel surface followed a Langmuir isotherm model. The thermodynamic parameters of adsorption were calculated. It was concluded that a thin layer of inhibitor is formed at the surface of steel preventing the corrosion of the specimen in the acid medium. It was also suggested that anchoring of the sulfur atom of the thiophene ring to the surface of the stainless steel takes place that allowed a blanket of the inhibitor molecule to cover the surface.
Surface reflectance FT-IR proved the adsorption of the inhibitor molecule at the stainless steel surface. Scanning electron microscopy showed that the presence of inhibitor protected the surface of the stainless steel against pitting in chloride-containing sulfuric acid electrolyte