On the Local and Global Approaches to Quantum Transport and Violation of the Second-law of Thermodynamics

Clausius' statement of the second law of thermodynamics reads: Heat will flow spontaneously from a hot to cold reservoir. This statement should hold for transport of energy through a quantum network composed of small subsystems each coupled to a heat reservoir. When the coupling between nodes is small, it seems reasonable to construct a local master equation for each node in contact with the local reservoir. The energy transport through the network is evaluated by calculating the energy flux after the individual nodes are coupled. We show by analysing the most simple network composed of two quantum nodes coupled to a hot and cold reservoir, that the local description can result in heat flowing from cold to hot reservoirs, even in the limit of vanishing coupling between the nodes. A global derivation of the master equation which prediagonalizes the total network Hamiltonian, and within this framework derives the master equation, is always consistent with the second-law of thermodynamics

Quantum Equivalence and Quantum Signatures in Heat Engines

Quantum heat engines (QHE) are thermal machines where the working substance is quantum. In the extreme case the working medium can be a single particle or a few level quantum system. The study of QHE has shown a remarkable similarity with the standard thermodynamical models, thus raising the issue what is quantum in quantum thermodynamics. Our main result is thermodynamical equivalence of all engine type in the quantum regime of small action. They have the same power, the same heat, the same efficiency, and they even have the same relaxation rates and relaxation modes. Furthermore, it is shown that QHE have quantum-thermodynamic signature, i.e thermodynamic measurements can confirm the presence of quantum coherence in the device. The coherent work extraction mechanism enables power outputs that greatly exceed the power of stochastic (dephased) engines.Comment: v2 contains style and figures improvements. Subsection III.D was adde

Comments on "Cooling by Heating: Refrigerator Powered by Photons"

We comment that the model proposed in Phys. Rev. Lett. 108, 120603 (2012) violates the dynamical version of the third law of thermodynamics. We discuses the different formulations of the third law of thermodynamics and suggest a possible reason for the violation

Quantum Flywheel

A quantum flywheel is studied with the purpose of storing useful work in quantum levels, while additional power is extracted continuously from the device. The flywheel gains its energy form a quantum heat engine. Generally, when a work repository is quantized the work exchange with the engine is accompanied with heat exchange, which may degrade the charging efficiency. In the particular realization of a quantum harmonic oscillator work repository, quantum and thermal fluctuations dominates the dynamics. Quantum monitoring and feedback control are applied to the flywheel, as it is shown to be an essential part of stabilizing and regulating its state of operation, and bringing the system to a steady state. A particular balance between information gained by measuring the system and the information fed back to the system is found to maximize the charging efficiency. The dynamics of the flywheel are described by a stochastic master equation that accounts for the engine, the external driving, the measurement, and the feedback operations

Quantum features and signatures of quantum-thermal machines

The aim of this book chapter is to indicate how quantum phenomena are affecting the operation of microscopic thermal machines, such as engines and refrigerators. As converting heat to work is one of the fundamental concerns in thermodynamics, the platform of quantum-thermal machines sheds light on thermodynamics in the quantum regime. This chapter focuses on the basic features of quantum mechanics, such as energy quantization, the uncertainty principle, quantum coherence and correlations, and their manifestation in microscopic thermal devices. In addition to indicating the peculiar behaviors of thermal-machines due to their non-classical features, we present quantum-thermodynamic signatures of these machines. Any violation of the classical bounds on thermodynamic measurements of these machines is a sufficient condition to conclude that quantum effects are present in the operation of that thermal machine. Experimental setups demonstrating some of the results are also presented