1,064 research outputs found
The crossover from collective motion to periphery diffusion for 2D adatom-islands on Cu(111)
The diffusion of two dimensional adatom islands (up to 100 atoms) on Cu(111)
has been studied, using the self-learning Kinetic Monte Carlo (SLKMC) method
[1]. A variety of multiple- and single-atom processes are revealed in the
simulations, and the size dependence of the diffusion coefficients and
effective diffusion barriers are calculated for each. From the tabulated
frequencies of events found in the simulation, we show a crossover from
diffusion due to the collective motion of the island to a regime in which the
island diffuses through periphery-dominated mass transport. This crossover
occurs for island sizes between 13 and 19 atoms. For islands containing 19 to
100 atoms the scaling exponent is 1.5, which is in good agreement with previous
work. The diffusion of islands containing 2 to 13 atoms can be explained
primarily on the basis of a linear increase of the barrier for the collective
motion with the size of the island
Atomistic studies of thin film growth
We present here a summary of some recent techniques used for atomistic
studies of thin film growth and morphological evolution. Specific attention is
given to a new kinetic Monte Carlo technique in which the usage of unique
labeling schemes of the environment of the diffusing entity allows the
development of a closed data base of 49 single atom diffusion processes for
periphery motion. The activation energy barriers and diffusion paths are
calculated using reliable manybody interatomic potentials. The application of
the technique to the diffusion of 2-dimensional Cu clusters on Cu(111) shows
interesting trends in the diffusion rate and in the frequencies of the
microscopic mechanisms which are responsible for the motion of the clusters, as
a function of cluster size and temperature. The results are compared with those
obtained from yet another novel kinetic Monte Carlo technique in which an open
data base of the energetics and diffusion paths of microscopic processes is
continuously updated as needed. Comparisons are made with experimental data
where available
Self-learning Kinetic Monte-Carlo method: application to Cu(111)
We present a novel way of performing kinetic Monte Carlo simulations which
does not require an {\it a priori} list of diffusion processes and their
associated energetics and reaction rates.
Rather, at any time during the simulation, energetics for all possible
(single or multi-atom) processes, within a specific interaction range, are
either computed accurately using a saddle point search procedure, or retrieved
from a database in which previously encountered processes are stored. This
self-learning procedure enhances the speed of the simulations along with a
substantial gain in reliability because of the inclusion of many-particle
processes.
Accompanying results from the application of the method to the case of
two-dimensional Cu adatom-cluster diffusion and coalescence on Cu(111) with
detailed statistics of involved atomistic processes and contributing diffusion
coefficients attest to the suitability of the method for the purpose.Comment: 18 pages, 9 figure
Doppler-free Yb Spectroscopy with Fluorescence Spot Technique
We demonstrate a simple technique to measure the resonant frequency of the
398.9 nm 1S0 - 1P1 transition for the different Yb isotopes. The technique,
that works by observing and aligning fluorescence spots, has enabled us to
measure transition frequencies and isotope shifts with an accuracy of 60 MHz.
We provide wavelength measurements for the transition that differ from
previously published work. Our technique also allows for the determination of
Doppler shifted transition frequencies for photoionisation experiments when the
atomic beam and laser beam are not perpendicular and furthermore allows us to
determine the average velocity of the atoms along the direction of atomic beam
Emerging strategies of targeting lipoprotein lipase for metabolic and cardiovascular diseases
Although statins and other pharmacological approaches have improved the management of lipid abnormalities, there exists a need for newer treatment modalities especially for the management of hypertriglyceridemia. Lipoprotein lipase (LPL), by promoting hydrolytic cleavage of the triglyceride core of lipoproteins, is a crucial node in the management of plasma lipid levels. Although LPL expression and activity modulation is observed as a pleiotropic action of some the commonly used lipid lowering drugs, the deliberate development of drugs targeting LPL has not occurred yet. In this review, we present the biology of LPL, highlight the LPL modulation property of currently used drugs and review the novel emerging approaches to target LPL
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