44 research outputs found
Forced Solid-State Interactions for the Selective âTurn-Onâ Fluorescence Sensing of Aluminum Ions in Water Using a Sensory Polymer Substrate
Selective and sensitive solid sensory substrates for detecting Al(III) in pure
water are reported. The material is a flexible polymer film that can be handled and exhibits gel
behavior and membrane performance. The film features a chemically anchored salicylaldehyde
benzoylhydrazone derivative as an aluminum ion fluorescence sensor. A novel procedure for
measuring Al(III) at the ppb level using a single solution drop in 20 min was developed. In this
procedure, a drop was allowed to enter the hydrophilic material for 15 min before a 5 min
drying period. The process forced the Al(III) to interact with the sensory motifs within the
membrane before measuring the fluorescence of the system. The limit of detection of Al(III)
was 22 ppm. Furthermore, a water-soluble sensory polymer containing the same sensory
motifs was developed with a limit of detection of Al(III) of 1.5 ppb, which was significantly
lower than the Environmental Protection Agency recommendations for drinking water.Spanish Ministerio de EconomiÌa
y Competitividad-Feder
(MAT2011-22544) and by the ConsejeriÌa
de EducacioÌn - Junta
de Castilla y LeoÌn (BU232U13)
Characterization of competitive interactions in the coexistence of Bt-transgenic and conventional rice
Cyt1Aa from Bacillus thuringiensis subsp. israelensis is toxic to the diamondback moth, Plutella xylostella (Lepidoptera: Plutellidae) and synergizes the activity of Cry1Ac towards a resistant strain.
The Bacillus thuringiensis subsp. israelensis cytolytic protein Cyt1Aa was found to be toxic to an insecticide-susceptible laboratory population of Plutella xylostella. Cry1Ac-resistant populations of P. Xylostella showed various degrees of resistance to Cyt1Aa. Cyt1Aa/Cry1Ac mixtures showed a marked level of synergism in the Cry1Ac-resistant populations