Symmetry of re-entrant tetragonal phase in Ba1-xNaxFe2As2: Magnetic versus orbital ordering mechanism

Magneto-structural phase transitions in Ba1-xAxFe2As2 (A = K, Na) materials are discussed for both magnetically and orbitally driven mechanisms, using a symmetry analysis formulated within the Landau theory of phase transitions. Both mechanisms predict identical orthorhombic space-group symmetries for the nematic and magnetic phases observed over much of the phase diagram, but they predict different tetragonal space-group symmetries for the newly discovered re-entrant tetragonal phase in Ba1-xNaxFe2As2 (x ~ 0.24-0.28). In a magnetic scenario, magnetic order with moments along the c-axis, as found experimentally, does not allow any type of orbital order, but in an orbital scenario, we have determined two possible orbital patterns, specified by P4/mnc1' and I4221' space groups, which do not require atomic displacements relative to the parent I4/mmm1' symmetry and, in consequence, are indistinguishable in conventional diffraction experiments. We demonstrate that the three possible space groups are however, distinct in resonant X-ray Bragg diffraction patterns created by Templeton & Templeton scattering. This provides an experimental method of distinguishing between magnetic and orbital models

Anisotropic Hc2H_{c2} determined up to 92 T and the signature of multi-band superconductivity in Ca10_{10}(Pt4_{4}As8_{8})((Fe1−x_{1-x}Ptx_{x})2_{2}As2_{2})5_{5} superconductor

The upper critical fields, $H_{c2}$($T$), of single crystals of the superconductor Ca$_{10}$(Pt$_{4-\delta}$As$_{8}$)((Fe$_{0.97}$Pt$_{0.03}$)$_{2}$As$_{2}$)$_{5}$ ($\delta$ $\approx$ 0.246) are determined over a wide range of temperatures down to $T$ = 1.42 K and magnetic fields of up to $\mu_{0}H$ $\simeq$ 92 T. The measurements of anisotropic $H_{c2}$($T$) curves are performed in pulsed magnetic fields using radio-frequency contactless penetration depth measurements for magnetic field applied both parallel and perpendicular to the \textbf{ab}-plane. Whereas a clear upward curvature in $H_{c2}^{\parallel\textbf{c}}$($T$) along \textbf{H}$\parallel$\textbf{c} is observed with decreasing temperature, the $H_{c2}^{\parallel\textbf{ab}}$($T$) along \textbf{H}$\parallel$\textbf{ab} shows a flattening at low temperatures. The rapid increase of the $H_{c2}^{\parallel\textbf{c}}$($T$) at low temperatures suggests that the superconductivity can be described by two dominating bands. The anisotropy parameter, $\gamma_{H}$ $\equiv$ $H_{c2}^{\parallel\textbf{ab}}/H_{c2}^{\parallel\textbf{c}}$, is $\sim$7 close to $T_{c}$ and decreases considerably to $\sim$1 with decreasing temperature, showing rather weak anisotropy at low temperatures.Comment: 4pages, 3figures, accepted PRB Rapid Communicatio

A Novel Technique for the Simultaneous Collection of Reflection and Transmission Data from Thin Films in the Extreme Ultraviolet

Studies of thin films in the Extreme Ultraviolet (EUV) are difficult given that most materials readily absorb photons of these energies. By depositing a thin film of the material of interest on a silicon photodiode, transmission measurements can be made throughout the EUV. If the measurements are made in a range of low absorption, the extinction coefficient, k, can be found with relative ease. However, if the material’s absorption is considerable, reflection measurements are needed to supplement the transmission data in order to find the optical constants n and k. The technique developed allows for reflection and transmission measurements to be taken simultaneously, which combined, account for all of the measurable photons from the original beam: (those which cannot be counted are photons absorbed into the thin film material). Also, the technique presented allows for data to be collected from practically all angles of incidence. This technique has been applied to a thin film of scandium oxide (d=65 nm), with measurements taken over wavelengths from 2.5-25 nm, and at angles of incidence 12 degrees from grazing to normal

Enabling Highly Effective Boiling from Superhydrophobic Surfaces

Avariety of industrial applications such as power generation, water distillation, and high-density cooling rely on heat transfer processes involving boiling. Enhancements to the boiling process can improve the energy efficiency and performance across multiple industries. Highly wetting textured surfaces have shown promise in boiling applications since capillary wicking increases the maximum heat flux that can be dissipated. Conversely, highly nonwetting textured (superhydrophobic) surfaces have been largely dismissed for these applications as they have been shown to promote formation of an insulating vapor film that greatly diminishes heat transfer efficiency. The current Letter shows that boiling from a superhydrophobic surface in an initial Wenzel state, in which the surface texture is infiltrated with liquid, results in remarkably low surface superheat with nucleate boiling sustained up to a critical heat flux typical of hydrophilic wetting surfaces, and thus upends this conventional wisdom. Two distinct boiling behaviors are demonstrated on both micro- and nanostructured superhydrophobic surfaces based on the initial wetting state. For an initial surface condition in which vapor occupies the interstices of the surface texture (Cassie- Baxter state), premature film boiling occurs, as has been commonly observed in the literature. However, if the surface texture is infiltrated with liquid (Wenzel state) prior to boiling, drastically improved thermal performance is observed; in this wetting state, the three-phase contact line is pinned during vapor bubble growth, which prevents the development of a vapor film over the surface and maintains efficient nucleate boiling behavior