A New Albite Microanalytical Reference Material from Piz Beverin for Na, Al and Si Determination, and the Potential for New K-Feldspar Reference Materials

Determination of alkali elements is important to Earth scientists, yet suitable and reliable microanalytical reference materials are lacking. This paper proposes a new albite reference material and evaluates the potential for future K-feldspar reference materials. The proposed Piz Beverin albite reference material from Switzerland yields a homogeneous composition at the centimetre- to micrometre-scale for Si, Al and Na with \u3c 2000 μg g-1 total trace elements (mostly heterogeneously distributed Ca, K and Sr). EPMA and LA-ICP-MS measurements confirm a composition of 99.5(2)% albite component, which is supported further by bulk XRF measurements. A round robin evaluation involving nine independent EPMA laboratories confirms its composition and homogeneity for Si, Al and Na. In addition, a set of five distinct clear K-feldspar samples was evaluated as possible reference materials. The first two crystals of adular and orthoclase yield unacceptable inhomogeneities with \u3e 2% relative local variations of Na, K and Ba contents. The three other investigated sets of K-feldspar crystals are yellow sanidine crystals from Itrongay (Madagascar). Despite distinct compositions, EPMA confirms they are each homogeneous at the centimetre to micrometre scale for Si, Al and K and have no apparent inclusions; further investigation to find larger amounts of these materials is therefore justified

Geology, mineralization, mineral chemistry, and ore-fluid conditions of Irankuh Pb-Zn mining district, south of Isfahan

Introduction The Irankuh mining district area located at the southern part of the Malayer-Isfahan metallogenic belt, south of Isfahan, consists of several Zn-Pb deposits and occurrences such as Tappehsorkh, Rowmarmar 5, Kolahdarvazeh, Blind ore, and Gushfil deposits as well as Rowmarmar 1-4 and Gushfil 1 prospects. Based on geology, alteration, form and texture of mineralization, and paragenesis assemblages, Pb-Zn mineralization is Mississippi-type deposit (Rastad, 1981; Ghazban et al., 1994; Ghasemi, 1995; Reichert, 2007; Timoori-Asl (2010); Ayati et al., 2013; Hosseini-Dinani et al., 2015). Geology of the area consists of Jurassic siltstone and shale and different types of Cretaceous dolostone and limestone. The aim of this research is new geological studies such as revision of old geologic map, study of different types of textures and mineral assemblages within carbonate and clastic host rocks, and chemistry of galena, sphalerite, and dolomite. Finally, we combined these results with isotopic and fluid inclusion data and discussed on ore-fluid conditions. Materials and Methods In order to achieve the aims of this work, at first field surveying and sampling were done. Then, 200 thin and 70 polished thin sections were prepared. Some of the samples were selected for microprobe analysis and galena and sphalerite minerals were analyzed by using JEOL- JAX-8230 analyzer at Colorado University, USA. The chemistry of dolomite and fluid inclusion data are used after Boveiri Konari and Rastad (2016) and stable isotope is used after Ghazban et al. (1994). Discussion The Irankuh mineralization is hosted by carbonate rocks (dolostone and limestone) and minor clastic rocks as epigenetic. Mineralization has occurred as breccia, veinlet, open space filling, spoted, dessiminated, and replacement (carbonate hosted rock). The mineral assemblages are Fe-rich sphalerite, galena, minor pyrite, Fe- and Mn-rich dolomite, bituminous, ankrite, calcite ± quartz ± barite within carbonate host rocks, whereas Fe-rich sphalerite, galena, pyrite, minor chalcopyrite, low Fe-dolomite, quartz, bituminous, ± barite ± calcite are important primary minerals at clastic host rocks. There is positive correlation between Ag and Sb values within galena mineral. Sb/Bi ratio in galena is up to 20, which is an indicator of low temperature deposits (Malakhov, 1968). The Irankuh homogenization temperature (170 to 260 ºC) is higher than that of US Mississippi-type deposits (80 to 120 ºC). Based on comparison of Th and Fe and Cd contents in sphalerite from Irankuh and US deposits (Viets et al., 1992), homogenization temperature of deposit has a positive relation with Fe values and a negative relation with Cd contents in sphalerite. Fe content in Irankuh sphalerite has reached up to 5% and Cd value is lower than 2000 ppm. In addition, carbonate hosted rock hydrothermal dolomites that are Fe-rich and ankrite have formed at some places. The evidence shows that Irankuh ore-fluid is Fe-rich. However, clastic hosted rock hydrothermal dolomites are low-Fe due to reaction of Fe and S resulting in pyrite formation. Based on O isotope (16–19 ‰) value from hydrothermal dolomites (Ghazban et al., 1994), ore-fluid has been derived from continental crust. Results Fe-rich sphalerite and dolomite and ankrite are the most important characteristics of Irankuh mining district. Temperature and Fe-rich nature of ore-fluid and mineralogy signatures of Irankuh area can be used for exploration of this type of mineralization in Iran and the world. The Irankuh mining district is MVT type mineralization. Acknowledgements The Research Division of the Ferdowsi University of Mashhad, Iran, supported this study (Project No. 40221.3). Thanks to Bama Co. (especially Mr. Eslami) for the collaborations. 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