The decay of photoexcited quantum systems: a description within the statistical scattering model

The decay of photoexcited quantum systems (examples are photodissociation of molecules and autoionization of atoms) can be viewed as a half-collision process (an incoming photon excites the system which subsequently decays by dissociation or autoionization). For this reason, the standard statistical approach to quantum scattering, originally developed to describe nuclear compound reactions, is not directly applicable. Using an alternative approach, correlations and fluctuations of observables characterizing this process were first derived in [Fyodorov YV and Alhassid Y 1998 Phys. Rev. A 58, R3375]. Here we show how the results cited above, and more recent results incorporating direct decay processes, can be obtained from the standard statistical scattering approach by introducing one additional channel.Comment: 7 pages, 2 figure

Random matrix description of decaying quantum systems

This contribution describes a statistical model for decaying quantum systems (e.g. photo-dissociation or -ionization). It takes the interference between direct and indirect decay processes explicitely into account. The resulting expressions for the partial decay amplitudes and the corresponding cross sections may be considered a many-channel many-resonance generalization of Fano's original work on resonance lineshapes [Phys. Rev 124, 1866 (1961)]. A statistical (random matrix) model is then introduced. It allows to describe chaotic scattering systems with tunable couplings to the decay channels. We focus on the autocorrelation function of the total (photo) cross section, and we find that it depends on the same combination of parameters, as the Fano-parameter distribution. These combinations are statistical variants of the one-channel Fano parameter. It is thus possible to study Fano interference (i.e. the interference between direct and indirect decay paths) on the basis of the autocorrelation function, and thereby in the regime of overlapping resonances. It allows us, to study the Fano interference in the limit of strongly overlapping resonances, where we find a persisting effect on the level of the weak localization correction.Comment: 16 pages, 2 figure

Fano interference and cross-section fluctuations in molecular photodissociation

We derive an expression for the total photodissociation cross section of a molecule incorporating both indirect processes that proceed through excited resonances, and direct processes. We show that this cross section exhibits generalized Beutler-Fano line shapes in the limit of isolated resonances. Assuming that the closed system can be modeled by random matrix theory, we derive the statistical properties of the photodissociation cross section and find that they are significantly affected by the direct processes. We identify a unique signature of the direct processes in the cross-section distribution in the limit of isolated resonances.Comment: 4 pages, 4 figure