Millennial Variability in an Idealized Ocean Model: Predicting the AMOC Regime Shifts

A salient feature of paleorecords of the last glacial interval in the North Atlantic is pronounced millennial variability, commonly known as Dansgaard–Oeschger events. It is believed that these events are related to variations in the Atlantic meridional overturning circulation and heat transport. Here, the authors formulate a new low-order model, based on the Howard–Malkus loop representation of ocean circulation, capable of reproducing millennial variability and its chaotic dynamics realistically. It is shown that even in this chaotic model changes in the state of the meridional overturning circulation are predictable. Accordingly, the authors define two predictive indices which give accurate predictions for the time the circulation should remain in the on phase and then stay in the subsequent off phase. These indices depend mainly on ocean stratification and describe the linear growth of small perturbations in the system. Thus, monitoring particular indices of the ocean state could help predict a potential shutdown of the overturning circulation

Cis-Selective Ring-Opening Metathesis Polymerization with Ruthenium Catalysts

Cis-selective ring-opening metathesis polymerization of several monocyclic alkenes as well as norbornene and oxanorbornene-type monomers using a C–H activated, ruthenium-based metathesis catalyst is reported. The cis content of the isolated polymers depended heavily on the monomer structure and temperature. A cis content as high as 96% could be obtained by lowering the temperature of the polymerization

Sine-Gordon breathers generation in driven long Josephson junctions

We consider a long Josephson junction excited by a suitable external ac-signal, in order to generate control and detect breathers. Studying the nonlinear supratransmission phenomenon in a nonlinear sine-Gordon chain sinusoidally driven, Geniet and Leon explored the bifurcation of the energy transmitted into the chain and calculated a threshold $A (\omega)$ for the external driving signal amplitude, at which the energy flows into the system by breathers modes. I numerically study the continuous sine-Gordon model, describing the dynamics of the phase difference in a long Josephson junction, in order to deeply investigate the "continuous limit" modifications to this threshold. Wherever the energy flows into the system due to the nonlinear supratransmission, a peculiar breather localization areas appear in a $(A, \omega)$ parameters space. The emergence of these areas depends on the damping parameter value, the bias current, and the waveform of driving external signal. The robustness of generated breathers is checked by introducing into the model a thermal noise source to mimic the environmental fluctuations. Presented results allows one to consider a cryogenic experiment for creation and detection of Josephson breathers.Comment: 8 pages, 3 figure

AMOC sensitivity to surface buoyancy fluxes: Stronger ocean meridional heat transport with a weaker volume transport?

Oceanic northward heat transport is commonly assumed to be positively correlated with the Atlantic meridional overturning circulation (AMOC). For example, in numerical “water-hosing” experiments, imposing anomalous freshwater fluxes in the northern Atlantic leads to a slow-down of the AMOC and the corresponding reduction of oceanic northward heat transport. Here, we study the sensitivity of the ocean heat and volume transports to surface heat and freshwater fluxes using a generalized stability analysis. For the sensitivity to surface freshwater fluxes, we find that, while the direct relationship between the AMOC volume and heat transports holds on shorter time scales, it can reverse on timescales longer than 500 years or so. That is, depending on the model surface boundary conditions, reduction in the AMOC volume transport can potentially lead to a stronger heat transport on long timescales, resulting from the gradual increase in ocean thermal stratification. We discuss the implications of these results for the problem of steady state (statistical equilibrium) in ocean and climate GCM as well as paleoclimate problems including millennial climate variability

Thermally Stable, Latent Olefin Metathesis Catalysts

Highly thermally stable N-aryl, N-alkyl N-heterocyclic carbene (NHC) ruthenium catalysts were designed and synthesized for latent olefin metathesis. These catalysts showed excellent latent behavior toward metathesis reactions, whereby the complexes were inactive at ambient temperature and initiated at elevated temperatures, a challenging property to achieve with second-generation catalysts. A sterically hindered N-tert-butyl substituent on the NHC ligand of the ruthenium complex was found to induce latent behavior toward cross-metathesis reactions, and exchange of the chloride ligands for iodide ligands was necessary to attain latent behavior during ring-opening metathesis polymerization (ROMP). Iodide-based catalysts showed no reactivity toward ROMP of norbornene-derived monomers at 25 °C and upon heating to 85 °C gave complete conversion of monomer to polymer in less than 2 h. All of the complexes were very stable to air, moisture, and elevated temperatures up to at least 90 °C and exhibited a long catalyst lifetime in solution at elevated temperatures

Mean energy balance in the tropical Pacific Ocean

The maintenance of the ocean general circulation requires energy input from the wind. Previous studies estimate that the mean rate of wind work (or wind power) acting on the surface currents over the global ocean amounts to 1.1 TW (1 TW = 1012 Watts), though values remain highly uncertain. By analyzing the output from a range of ocean-only models and data assimilations, we show that the tropical Pacific Ocean contributes around 0.2 to 0.4 TW, which is roughly half of the total tropical contribution. Not only does this wind power represent a significant fraction of the total global energy input into the ocean circulation, it is also critical in maintaining the east-west tilt of the ocean thermocline along the equator. The differences in the wind power estimates are due to discrepancies in the wind stress used to force the models and discrepancies in the surface currents the models simulate, particularly the North Equatorial Counter Current and the South Equatorial Current. Decadal variations in the wind power, more prominent in some models, show a distinct decrease in the wind power in the late 1970s, consistent with the climate regime shift of that time and a flattening of the equatorial thermocline. We find that most of the wind power generated in the tropics is dissipated by friction in the mixed layer and in zonal currents with strong vertical and horizontal shears. Roughly 10 to 20% of the wind power (depending on the model) is transferred down the water column through vertical buoyancy fluxes to maintain the thermocline slope along the equator. Ultimately, this fraction of the wind power is dissipated by a combination of vertical and horizontal diffusion, energy advection out of the tropics, and damping by surface heat fluxes. Values of wind power generated in the tropical Pacific by coupled general circulation models are typically larger than those generated by ocean-only models, and range from 0.3 to 0.6 TW. Even though many models simulate a \u27realistic\u27 climate in the tropical ocean, their energy budgets can still vary greatly from one model to the next. We argue that a correct energy balance is an essential measure of how well the models represent the actual ocean physics

Steklov-Lyapunov type systems

In this paper we describe integrable generalizations of the classical Steklov– Lyapunov systems, which are defined on a certain product so(m) × so(m), as well as the structure of rank r coadjoint orbits in so(m)×so(m). We show that the restriction of these systems onto some subvarieties of the orbits written in new matrix variables admits a new r × r matrix Lax representation in a generalized Gaudin form with a rational spectral parameter. In the case of rank 2 orbits a corresponding 2×2 La x pair for the reduced systems enables us to perform a separation of variables