Green's and spectral functions of the small Frolich polaron

According to recent Quantum Monte Carlo simulations the small polaron theory is practically exact in a wide range of the long-range (Frohlich) electron-phonon coupling and adiabatic ratio. We apply the Lang-Firsov transformation to convert the strong-coupling term in the Hamiltonian into the form of an effective hopping integral and derive the single-particle Green's function describing propagation of the small Frohlich polaron. One and two dimensional spectral functions are studied by expanding the Green's function perturbatively. Numerical calculations of the spectral functions are produced. Remarkably, the coherent spectral weight (Z) and effective mass (Z') renormalisation exponents are found to be different with Z'>>Z, which can explain a small coherent spectral weight and a relatively moderate mass enhancement in oxides.Comment: RevTeX, 5 pages, 2 postscript figures, LaTeX processing problems correcte

From Hurwitz numbers to Kontsevich-Witten tau-function: a connection by Virasoro operators

In this letter,we present our conjecture on the connection between the Kontsevich--Witten and the Hurwitz tau-functions. The conjectural formula connects these two tau-functions by means of the $GL(\infty)$ group element. An important feature of this group element is its simplicity: this is a group element of the Virasoro subalgebra of $gl(\infty)$. If proved, this conjecture would allow to derive the Virasoro constraints for the Hurwitz tau-function, which remain unknown in spite of existence of several matrix model representations, as well as to give an integrable operator description of the Kontsevich--Witten tau-function.Comment: 13 page

Spectral analysis of electron transfer kinetics II

Electron transfer processes in Debye solvents are studied using a spectral analysis method recently proposed. Spectral structure of a nonadiabatic two-state diffusion equation is investigated to reveal various kinetic regimes characterized by a broad range of physical parameters; electronic coupling, energy bias, reorganization energy, and solvent relaxation rate. Within this unified framework, several kinetic behaviors of the electron transfer kinetics, including adiabatic Rabi oscillation, crossover from the nonadiabatic to adiabatic limits, transition from the incoherent to coherent kinetic limits, and dynamic bath effect, are demonstrated and compared with results from previous theoretical models. Dynamics of the electron transfer system is also calculated with the spectral analysis method. It is pointed out that in the large reorganization energy case the nonadiabatic diffusion equation exhibits a non-physical behavior, yielding a negative eigenvalue.Comment: submitted for a publication in Journal of Chemical Physic

On the total mean curvature of non-rigid surfaces

Using Green's theorem we reduce the variation of the total mean curvature of a smooth surface in the Euclidean 3-space to a line integral of a special vector field and obtain the following well-known theorem as an immediate consequence: the total mean curvature of a closed smooth surface in the Euclidean 3-space is stationary under an infinitesimal flex.Comment: 4 page

Polaron and bipolaron transport in a charge segregated state of doped strongly correlated 2D semiconductor

The 2D lattice gas model with competing short and long range interactions is appliedused for calculation of the incoherent charge transport in the classical strongly-correlated charge segregated polaronic state. We show, by means of Monte-Carlo simulations, that at high temperature the transport is dominated by hopping of the dissociated correlated polarons, where with thetheir mobility is inversely proportional to the temperature. At the temperatures below the clustering transition temperature the bipolaron transport becomes dominant. The energy barrier for the bipolaron hopping is determined by the Coulomb effects and is found to be lower than the barrier for the single-polaron hopping. This leads to drastically different temperature dependencies of mobilities for polarons and bipolarons at low temperatures

Emergent order in the spin-frustrated system DyxTb2-xTi2O7 studied by ac susceptibility measurements

We report the a.c. susceptibility study of Dy_xTb_{2-x}Ti_2O_7 with x in [0, 2]. In addition to the single-ion effect at Ts (single-ion effect peak temperature) corresponding to the Dy3+ spins as that in spin ice Dy_2Ti_2O_7 and a possible spin freezing peak at Tf (Tf < 3 K), a new peak associated with Tb^{3+} is observed in $\chi_{ac}(T)$ at nonzero magnetic field with a characteristic temperature T^* (Tf < T^* < Ts). T^* increases linearly with x in a wide composition range (0 < x < 1.5 at 5 kOe). Both application of a magnetic field and increasing doping with Dy3+ enhance T^*. The T^* peak is found to be thermally driven with an unusually large energy barrier as indicated from its frequency dependence. These effects are closely related to the crystal field levels, and the underlying mechanism remains to be understood.Comment: 7 pages, 5 figure