Retrospective analysis of surgical treatments of sternoclavicular joint dislocation: literature review

Traumatic injuries to the sternoclavicular joint (SCJ) dislocations account for less than 3% of all joint dislocations. However, instrumentation fixation is frequently associated with high-risk complications that lead to disability. The authors sought to explore historical aspects of various surgical fixation techniques based on specific anatomy of injured segment. The findings are presented in the chronological order briefly describing methods of fixation, the authors and clinical results obtained

Effect of silanol groups on the acidic and catalytic properties of alkylsulphoacidic silicas and SiO2/narion nanocomposites

Sets of silicas covalently modified with alkylsulphoacidic groups (SiO2-SO3H) and nanocomposites of silica with superacidic Nafion(R)\ polymer (SiO2/Nafion) were synthesised. End-capping the silanol groups with trimethylsilyl groups was used to obtain surface hydrophobisation. The materials obtained were characterised by nitrogen and water adsorption measurements, MAS NMR spectroscopy and dielectric relaxation spectroscopy (DRS). The acidity of the materials was tested by P-31 MAS NMR spectroscopic examination of samples with adsorbed triethylphosphine oxide (TEPO). It was demonstrated that end-capping excluded part of the surface silanol groups from interaction with acidic groups, thereby causing the sulphonic groups to exhibit an increased acidity. With SiO2-SO3H, end-capping also increased their catalytic activity in the synthesis of ethyl t-butyl ether (ETBE). However, end-capping had a negligible effect on the catalytic properties of SiO2/Nafion, probably because the catalytic reaction occurred inside the Nafion polymer nanoparticles

Dataset: Fauna of Adult Ground Beetles (Coleoptera, Carabidae) of the National Park “Smolny” (Russia)

(1) Background: Protected areas are “hotspots” of biodiversity in many countries. In such areas, ecological systems are preserved in their natural state, which allows them to protect animal populations. In several protected areas, the Coleoptera biodiversity is studied as an integral part of the ecological monitoring of the ecosystem state. This study was aimed to describe the Carabidae fauna in one of the largest protected areas of European Russia, namely National Park “Smolny”. (2) Methods: The study was conducted in April–September 2008, 2009, 2017–2021. A variety of ways was used to collect beetles (by hand, caught in light traps, pitfall traps, and others). Seasonal dynamics of the beetle abundance were studied in various biotopes. Coordinates were fixed for each observation. (3) Results: The dataset contains 1994 occurrences. In total, 32,464 specimens of Carabidae have been studied. The dataset contains information about 131 species of Carabidae beetles. In this study, we have not found two species (Carabus estreicheri and Calathus ambiguus), previously reported in the fauna of National Park “Smolny”. (4) Conclusions: The Carabidae diversity in the National Park “Smolny” is represented by 133 species from 10 subfamilies. Ten species (Carabus cancellatus, Harpalus laevipes, Carabus hortensis, Pterostichus niger, Poecilus versicolor, Pterostichus melanarius, Carabus glabratus, Carabus granulatus, Carabus arvensis baschkiricus, Pterostichus oblongopunctatus) constitute the majority of the Carabidae fauna. Seasonal dynamics are maximal in spring; the number of ground beetles decreases in biotopes by autumn

Impact of Carbon Fluoroxide Nanoparticles on Cell Proliferation

Cytotoxicity of fluorescent carbon fluoroxide (CFO) nanoparticles (NPs) was studied in a label-free manner on several cancer and non-cancer cell lines. A direct cytotoxic effect of the CFO NPs was clearly observed by a suppression of cell proliferation. The real-time measurement of cell activities allowed to quantify the impact of the uptaken NPs on cell proliferation and after washout of the NPs from the cell culture medium. The results show more toxic effects of the CFO NPs on cancer than on non-cancer cell lines. The notion of NPs biocompatibility must be related to a maximum concentration value of the NPs acceptable for a given cell type. Furthermore, the cytotoxicity effects of NPs should be studied not only during their direct exposure to cells but also after their washout from the culture medium.ISSN:2079-499

Kinetics of Hydrogen Generation from Oxidation of Hydrogenated Silicon Nanocrystals in Aqueous Solutions

Hydrogen generation rate is one of the most important parameters which must be considered for the development of engineering solutions in the field of hydrogen energy applications. In this paper, the kinetics of hydrogen generation from oxidation of hydrogenated porous silicon nanopowders in water are analyzed in detail. The splitting of the Si-H bonds of the nanopowders and water molecules during the oxidation reaction results in powerful hydrogen generation. The described technology is shown to be perfectly tunable and allows us to manage the kinetics by: (i) varying size distribution and porosity of silicon nanoparticles; (ii) chemical composition of oxidizing solutions; (iii) ambient temperature. In particular, hydrogen release below 0 °C is one of the significant advantages of such a technological way of performing hydrogen generation

Scarabaeoidea (Coleoptera) Fauna of the Republic of Mordovia (Russia)

(1) Background: Beetles in the superfamily Scarabaeoidea are one of the most important groups of Coleoptera. They are found in various ecosystems all over the world and belong to coprophagous, necrophagous, saproxylophagous, phyllophagous and rhizophagous types. The aim of the study is to describe the fauna and distribution of Scarabaeoidea in the Republic of Mordovia (central part of European Russia); (2) Methods: The study was conducted from 2003 to 2023. Collection material (specimens from 1972 and 1986) was also used. Specimens were collected using traditional Coleoptera collecting methods (manual collecting, light trap, collection of rotten remains and pitfall traps). For each observation, the coordinates, number of specimens and dates were recorded; (3) Results: The dataset contains 3198 occurrences. We examined 11,011 specimens of Scarabaeoidea. The dataset contains information on 88 species of Scarabaeoidea. Of these, five species (Aphodius pedellus, Nobius serotinus, Phaeaphodius rectus, Planolinus fasciatus and Onthophagus medius) are listed for the region for the first time. Another seven species are additionally known from others taken from the literature (but were not found during the present field survey); (4) Conclusions: Species diversity of Scarabaeoidea of Mordovia accounts for 95 species from 4 families (Geotrupidae, Trogidae, Lucanidae and Scarabaeidae). Ten species (Protaetia marmorata, Anoplotrupes stercorosus, Cetonia aurata, Protaetia cuprea volhyniensis, Oxythyrea funesta, Platycerus caraboides, Serica brunnea, Melolontha hippocastani, Trichius fasciatus and Protaetia fieberi) constitute the main population of Scarabaeoidea fauna given in the dataset. The species diversity of Scarabaeoidea of the Republic of Mordovia is roughly similar in number of species to that of neighboring or more northern regions

Mesoporous silicon carbide: Via nanocasting of Ludox® xerogel

Porous SiC with uniformly sized 12 nm and 22 nm spherical mesopores was synthesized from nanocomposites of polycarbosilane (PCS) preceramic polymer and xerogels of Ludox® SiO2 nanoparticles as templates. The influence of PCS type (Mw 800 and 2000 Da), PCS:SiO2 ratio, pyrolysis temperature 1200-1400 °C, and addition of Ni complex to the preceramic composite was studied with respect to the SiC porous morphology, crystalline structure and chemical properties. We found that the pore walls of Ni-free por-SiC are composed of relatively large (20 nm) crystallites embedded inside a poorly crystalline SiC/SiC1+x phase. Increasing the pyrolysis temperature resulted in an increase of the large crystallites fraction, as well as of the stability with regard to air oxidation; however, some degradation of the porous morphology was noted too. The presence of Ni (1.5% wt relatively to PCS) noticeably improved the crystallinity of por-SiC prepared at 1200-1300 °C, with no degradation of the porous morphology occurring. On the other hand, higher Ni loadings and temperatures led to the transformation of the porous morphology into aggregates of irregularly packed large crystallites.SCOPUS: ar.jinfo:eu-repo/semantics/publishe

Dataset: Biodiversity of Ground Beetles (Coleoptera, Carabidae) of the Republic of Mordovia (Russia)

(1) Background: Carabidae is one of the most diverse families of Coleoptera. Many species of Carabidae are sensitive to anthropogenic impacts and are indicators of their environmental state. Some species of large beetles are on the verge of extinction. The aim of this research is to describe the Carabidae fauna of the Republic of Mordovia (central part of European Russia); (2) Methods: The research was carried out in April-September 1979, 1987, 2000, 2001, 2005, 2007–2022. Collections were performed using a variety of methods (light trapping, soil traps, window traps, etc.). For each observation, the coordinates of the sampling location, abundance, and dates were recorded; (3) Results: The dataset contains data on 251 species of Carabidae from 12 subfamilies and 4576 occurrences. A total of 66,378 specimens of Carabidae were studied. Another 29 species are additionally known from other publications. Also, twenty-two species were excluded from the fauna of the region, as they were determined earlier by mistake (4). Conclusions: The biodiversity of Carabidae in the Republic of Mordovia included 280 species from 12 subfamilies. Four species (Agonum scitulum, Lebia scapularis, Bembidion humerale, and Bembidion tenellum) were identified for the first time in the Republic of Mordovia