Late Tertiary-Quaternary tectonics of the Southern Apennines (Italy): new evidences from the Tyrrhenian slope

This paper summarises the results of combined structural and geomorphological investigations we carried out in two key areas, in order to obtain new data on the structure and evolution of the Tyrrhenian slope of the southern Apennines. Analysis by a stress inversion method of fault slip data from Mesozoic to Quaternary formations allowed the reconstruction of states of stress at different time intervals. By integrating these data with those deriving from the stratigraphic and morphotectonic records, chronology and timing of the sequence of the deformation events was obtained. The tectonic history of the region can be related to four deformation events. Structures related to the first event, that was dominated by a strike-slip regime with a NW–SE oriented σ1 and was active since Mid–Late Miocene, do not significantly affect the present day landscape, as they were strongly displaced and overprinted by subsequent deformation events and/or deleted by erosion. The second and third events, that may be considered as the main responsible for the morphostructural signature of the region, are comparable with the stretching phases recognised offshore and considered to be responsible for the opening and widening of the Tyrrhenian basin. In particular, the second event (with an E–W oriented σ3), took place in the Late Miocene/ earliest Pliocene and was first dominated by a strike-slip regime, that was also responsible for thrusting and folding. Since Late Pliocene, it was dominated by an extensional regime that created large vertical offsets along N–S to NW–SE trending faults. The third event, that was dominated by extension with a NW–SE oriented σ3, started in the Early Pleistocene and was responsible for formation of the horst-and-graben structure with NE–SW trend that characterises the Tyrrhenian margin of the southern Apennines. The fourth deformation event, which is characterised by an extensional regime with a NE–SW trending σ3, started in the late Middle Pleistocene and is currently active

Rhodium-catalyzed hydroformylation of 4-vinylpyridine: 4-ethylpyridine formation via an unusual cleavage of the Rh?C bond by the enolic form of the oxo product.

The hydroformylation of 4-vinylpyridine (4VP) with rhodium catalyst Rh4(CO)12 modified with phosphine ligands (PMe2Ph) is not completely chemoselective to the branched aldehyde 2-(4-pyridyl)propanal (4α), the corresponding hydrogenation product 4-ethylp