102 research outputs found
2-Amino-3-nitropyridinium hydrogen oxalate
In the non-centrosymetric title compound, C5H6N3O2
+·C2HO4
−, the hydrogen oxalate anions form corrugated chains parallel to the c axis, linked by O—H⋯O hydrogen bonds. The 2-amino-3-nitropyridinium cations are anchored between theses chains by N—H⋯O and C—H⋯O hydrogen bonds and van der Waals and electrostatic interactions, creating a three-dimensional network
Bis(2-amino-3-nitropyridinium) dihydrogendiphosphate
The structure of the title compound, 2C5H6N3O2
+·H2P2O7
2−, contains infinite (H2P2O7
2−)n layers stacked perpendicular to the a axis. The 2-amino-3-nitropyridinium cations are arranged in pairs and are anchored between these layers, linking them by N—H⋯O and C—H⋯O hydrogen-bonding and electrostatic interactions between anionic and cationic species to form a three-dimensional network
2-Amino-3-nitropyridinium perchlorate
The title compound, C5H6N3O2
+·ClO4
−, is comprised of discrete perchlorate anions and 2-amino-3-nitropyridinium cations. The anion has a typical tetrahedral geometry while the cation presents a nearly planar [maximum deviation = 0.007 (8) Å] pyridinium ring. Undulating [C5H6N3O2
+]n chains extending along the c-axis direction are linked via N—H⋯O hydrogen bonds. The cations are further connected to the anions by N—H⋯O hydrogen bonds and weak C—H⋯O interactions, leading to the formation of a three-dimensional network
2-Amino-3-nitropyridinium perrhenate
In the title molecular salt, (C5H6N3O2)[ReO4], the cations and tetrahedral anions are linked by trifurcated N—H⋯(O,O,O) and bifurcated N—H⋯(O,O) hydrogen bonds, as well as weak C—H⋯O interactions. This results in alternating corrugated inorganic and organic layers in the crystal
Bis(2-amino-3-nitropyridinium) dichromate(VI)
The title compound, (C5H6N3O2)2[Cr2O7], consists of 2-amino-3-nitropyridinium cations and discrete dichromate anions linked together by N—H⋯O and C—H⋯O hydrogen bonds, forming thick layers parallel to (101). Layer cohesion is ensured by N—H⋯O hydrogen bonding in addition to electrostatic and van der Waals interactions, forming a three-dimensional framework. The dichromate anion is located on a twofold axis that passes through its bridging O atom
Nombres de Betti des surfaces elliptiques réelles
Minor changesInternational audienceWe prove a new bound for the number of connected components of a real regular elliptic surface with a real section and we show the sharpness of this bound. Furthermore, all possible values for the Betti numbers of such a surface are realized
2-Amino-3-nitropyridinium hydrogen selenate
The asymmetric unit of the title compound, C5H6N3O2
+·HSeO4
−, contains two monoprotonated 2-amino-3-nitropyridinium cations and two hydrogen selenate anions which are connected through N—H⋯O and O—H⋯O hydrogen bonds, building chains parallel to the a direction. These chains are further connected to each other by weaker C—H⋯O hydrogen-bonding interactions, leading to the formation of a three-dimensional network
Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)
In the title cobalt(II) complex with 2-methylanilinium and diphosphate, (C7H10N)2[Co(H2P2O7)2(H2O)2], a three-dimensional network is built up from anionic layers of [Co(H2P2O7)2(H2O)2]2− units and 2-methylanilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co2+ ions lie on inversion centers. An intricate network of O—H⋯O and N—H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other interactions, being of electrostatic and van der Waals nature
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