71 research outputs found
(8-Bromo-2,7-dimethoxy-1-naphthyl)(4-chlorophenyl)methanone
In the title compound, C19H14BrClO3, the naphthalene ring system and the benzene ring make a dihedral angle of 77.36 (10)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 75.73 (15)° versus 2.33 (17)°. In the crystal structure, a π–π interaction is formed between naphthalene ring systems, with a centroid–centroid distance of 3.8363 (14) Å and a lateral offset of 1.606 Å. Intermolecular C—H⋯Br and C—H⋯O hydrogen bonds and a C—H⋯π contact are present in the crystal structure
(4-Chlorophenyl)(3,8-dibromo-2-hydroxy-7-methoxy-1-naphthyl)methanone
In the title compound, C18H11Br2ClO3, an intramolecular O—H⋯O=C hydrogen bond occurs, forming a six-membered ring. The naphthalene ring system and the benzene ring make a dihedral angle of 57.36 (9)°. The central carbonyl C—(C=O)—C group is twisted away from the naphthalene ring system and the benzene ring by 18.61 (15) and 26.25 (16)°, respectively. In the crystal structure, two intermolecular Br⋯Cl close contacts [3.4927 (7) and 3.4325 (7) Å] are observed
Methyl 4-(2,7-dimethoxy-1-naphthoyl)benzoate
In the title compound, C21H18O5, the dihedral angle between the naphthalene ring system and the benzene ring is 86.65 (6)°. The bridging carbonyl C—C(=O)—C plane makes dihedral angles of 83.57 (7) and 20.21 (8)°, respectively, with the naphthalene ring system and the benzene ring. The ester O—C=O plane and the benzene ring are almost coplanar, making a dihedral angle of 3.81 (18)°. The two methoxy groups lie essentially in the naphthalene ring plane [C—O—C—C torsion angles = 2.1 (2) and −1.44 (19)°]. In the crystal structure, a centrosymmetric dimer is formed through C—H⋯O bonds connecting the 7-methoxy group and the carbonyl O atom of the ester group. The dimers are further linked by C—H⋯O hydrogen bonds between the methoxycarbonyl group and the bridging carbonyl O atom
1,8-Bis(4-chlorobenzoyl)-7-methoxynaphthalen-2-ol ethanol monosolvate
In the title compound, C25H16Cl2O4·C2H6O, the two 4-chlorobenzoyl groups are in syn orientations with respect to the naphthalene ring system and are approximately parallel to each other: the dihedral angle between the benzene rings is 11.43 (16)°. The conformation around each of the carbonyl C—(C=O)—C groups forms a larger angle to the plane of the naphthalene ring system than that to the benzene ring; the angles of the C=O bond vector with the naphthalene ring system and the benzene ring are 55.4 (3) versus 13.5 (3)° and 52.2 (3) versus 17.9 (3)°. An intramolecular O—H⋯O=C hydrogen bond generates a six-membered ring. In the crystal structure, intermolecular O—H⋯O hydrogen bonds including the ethanol solvent molecule are observed. A C—H⋯O interaction also occurs. The ethyl group of the ethanol molecule is disordered over two positions with site occupancies of 0.63 and 0.37. The crystal studied was an inversion twin
(2-Hydroxy-7-methoxynaphthalen-1-yl)(phenyl)methanone
In the molecule of the title compound, C18H14O3, there is an intramolecular O—H⋯O=C hydrogen bond between the carbonyl and hydroxy groups on the naphthalene ring system. The angles between the C=O bond vector and the least-squares planes of the naphthalene ring system and the phenyl ring are 30.58 (6) and 42.82 (7)°, respectively, while the dihedral angle between the naphthalene ring system and the phenyl ring is 58.65 (5)°. In the crystal, molecules are connected by pairs of intermolecular O—H⋯O=C hydrogen bonds, forming centrosymmetric dimers
1-[(4-Chlorophenyl)(phenylimino)methyl]-7-methoxy-2-naphthol–1,4-diazabicyclo[2.2.2]octane (2/1)
In the crystal structure of the title cocrystal, 2C24H18ClNO2·C6H12N2, the 1,4-diazabicyclo[2.2.2]octane molecule is located on a twofold rotation axis and linked to the two triarylimine molecules by O—H⋯N hydrogen bonds, forming a 2:1 aggregate. C—H⋯Cl interactions are also observed. In the triarylimine molecule, the naphthalene ring system makes dihedral angles of 80.39 (6) and 82.35 (6)°, respectively, with the phenyl and benzene rings. The dihedral angle between these two latter rings is 87.09 (7)°
(4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone
In the title compound, C19H14ClNO5, the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The torsion angle of the carbonyl group and naphthalene ring is 54.68 (19)° (C—C—C—O), and that of nitro group and naphthalene ring is 54.26 (18)° (O—N—C—C). In the crystal, π–π interactions between naphthalene systems [centroid–centroid distances = 3.5633 (9), 3,5634 (9), and 3.9758(9) Å], C—H⋯O hydrogen bonds, intermolecular N—O⋯Cl interactions [2.9937 (12) Å] and C—H⋯π contacts are observed
2-(2,7-Dimethoxy-1-naphthoyl)benzoic acid
In the title compound, C20H16O5, the dihedral angle between the naphthalene ring system and the benzene ring is 67.43 (5)°. The bridging carbonyl C—C(=O)—C plane makes dihedral angles of 82.64 (6) and 41.79 (7)°, respectively, with the naphthalene ring system and the benzene ring. The dihedral angle between the carboxy O—C(=O)—C plane and the benzene ring is 36.38 (7)° and that between the bridging carbonyl C—C(=O)—C plane and the carboxy O—C(=O)—C plane is 51.88 (8)°. The crystal structure is stabilized by intermolecular O—H⋯O and C—H⋯O hydrogen-bonding interactions. An intramolecular C—H⋯O hydrogen bond occurs between a naphthalene H atom and the carbonyl O atom of the carboxy group
2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene
In the title compound, C19H15NO5, the dihedral angle between the naphthalene ring system and the benzene ring is 61.97 (5)°. The dihedral between the naphthalene ring system and the bridging carbonyl C—C(=O)—C plane is 54.68 (6)°, far larger than that [12.54 (7)°] between the phenyl group and the bridging carbonyl group. The nitro group and the phenyl ring are almost coplanar [O—N—C—C torsion angle = 2.94 (19)°]. In the crystal, molecules are linked by C—H⋯π interactions and the phenyl rings are involved in a centrosymmetric π–π interaction with a perpendicular distance of 3.523 Å and a lateral offset of 1.497 Å. In addition, weak intermolecular C—H⋯O hydrogen bonds are formed between an H atom of one methoxy group and a nearby carbonyl O atom
1-(4-Chlorobenzoyl)-2,7-dimethoxynaphthalene
In the title compound, C19H15ClO3, the dihedral angle between the naphthalene ring system and the benzene ring is 72.06 (7)°. The 4-chlorophenyl group and the carbonyl group are almost coplanar. An intermolecular C—H⋯O hydrogen bond is formed between an H atom of the 4-chlorophenyl group and the O atom of one methoxy group, forming a zigzag chain along the a axis
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