Enhanced toluene removal using granular activated carbon and a yeast strain candida tropicalis in bubble-column bioreactors

The yeast strain Candida tropicalis was used for the biodegradation of gaseous toluene. Toluene was effectively treated by a liquid culture of C. tropicalis in abubble-column bioreactor, and the tolueneremoval efficiency increased with decreasing gas flow rate. However, toluene mass transfer from the gas-to-liquid phase was a major limitation for the uptake of toluene by C. tropicalis. The tolueneremoval efficiency was enhanced when granularactivatedcarbon (GAC) was added as a fluidized material. The GAC fluidized bioreactor demonstrated tolueneremoval efficiencies ranging from 50 to 82% when the inlet toluene loading was varied between 13.1 and 26.9 g/m3/h. The yield value of C. tropicalis ranged from 0.11 to 0.21 g-biomass/g-toluene, which was substantially lower than yield values for bacteria reported in the literature. The maximum elimination capacity determined in the GAC fluidized bioreactor was 172 g/m3/h at atoluene loading of 291 g/m3/h. Transient loading experiments revealed that approximately 50% of the toluene introduced was initially adsorbed onto the GAC during an increased loading period, and then slowly desorbed and became available to the yeast culture. Hence, the fluidized GAC mediated in improving the gas-to-liquid mass transfer of toluene, resulting in a high tolueneremoval capacity. Consequently, the GAC bubble-column bioreactor using the culture of C. tropicalis can be successfully applied for the removal of gaseous toluene

Study of timing performance of Silicon Photomultiplier and application for a Cherenkov detector

Silicon photomultipliers are very versatile photo detectors due to their high photon detection efficiency, fast response, single photon counting capability, high amplification, and their insensitivity to magnetic fields. At our institute we are studying the performance of these photo detectors at various operating conditions. On the basis of the experience in the laboratory we built a prototype of a timing Cherenkov detector consisting of a quartz radiator with two $3\times 3$ mm$^2$ MPPCs S10362-33-100C from Hamamatsu Photonics as photodetectors. The MPPC sensors were operated with Peltier cooling to minimize thermal noise and to avoid gain drifts. The test measurements at the DA$\Phi$NE Beam-Test Facility (BTF) at the Laboratori Nazionali di Frascati (LNF) with pulsed 490 MeV electrons and the results on timing performance with Cherenkov photons are presented.Comment: Conference proceedings of 12th Vienna Conference on Instrumentation 201

A Potts model for the distortion transition in LaMnO3_3

The Jahn-Teller distortive transition of \lmo is described by a modified 3-state Potts model. The interactions between the three possible orbits depends both on the orbits and their relative orientation on the lattice. Values of the two exchange parameters which are chosen to give the correct low temperature phase and the correct value for the transition temperature are shown to be consistent with microscopy theory. The model predicts a first order transitions and also a value for the entropy above the transition in good agreement with experiment. The theory with the same parameters also predicts the temperature dependence of the order parameter of orbital ordering agreeing well with published experimental results. Finally, the type of the transition is shown to be close to one of the most disordered phases of the generalised Potts model. The short range order found experimentally above the transition is investigated by this model.Comment: 16 pages, 7 figures and no tables. Re-submitted to Phys. Rev.

Shear flow of angular grains: acoustic effects and non-monotonic rate dependence of volume

Naturally-occurring granular materials often consist of angular particles whose shape and frictional characteristics may have important implications on macroscopic flow rheology. In this paper, we provide a theoretical account for the peculiar phenomenon of auto-acoustic compaction -- non-monotonic variation of shear band volume with shear rate in angular particles -- recently observed in experiments. Our approach is based on the notion that the volume of a granular material is determined by an effective-disorder temperature known as the compactivity. Noise sources in a driven granular material couple its various degrees of freedom and the environment, causing the flow of entropy between them. The grain-scale dynamics is described by the shear-transformation-zone (STZ) theory of granular flow, which accounts for irreversible plastic deformation in terms of localized flow defects whose density is governed by the state of configurational disorder. To model the effects of grain shape and frictional characteristics, we propose an Ising-like internal variable to account for nearest-neighbor grain interlocking and geometric frustration, and interpret the effect of friction as an acoustic noise strength. We show quantitative agreement between experimental measurements and theoretical predictions, and propose additional experiments that provide stringent tests on the new theoretical elements.Comment: 12 pages, 3 figure