SPECTRAL STUDIES AND ANTIMICROBIAL SCREENING FOR SOME NOVEL CHALCONES ANALOGUES

Objective: The present work aim to study the spectral and antimicrobial activity for synthesized chalcones Methods: The synthesized Chalcones were characterized by Physical and spectral methods such as melting point, IR, 1H-NMR and Mass analysis. The synthesized compounds have been screened for their antimicrobial activity. Results: The biological data showed that compounds III, VII had strong activities against the Staphylococcus aureus, Bacillus subtilis, and Pseudomonas aeruginosa, but not activity against fungus. Conclusion: The main purpose to use an easy and useful method to synthesize biologically active chalcone

Performance Analysis and Optimization of a Parabolic Trough Solar Power Plant in the Middle East Region

The Middle East is one among the areas of the world that receive high amounts of direct solar radiation. As such, the region holds a promising potential to leverage clean energy. Owing to rapid urbanization, energy demands in the region are on the rise. Along with the global push to curb undesirable outcomes such as air pollution, emissions of greenhouse gases, and climate change, an urgent need has arisen to explore and exploit the abundant renewable energy sources. This paper presents the design, performance analysis and optimization of a 100 MWe parabolic trough collector Solar Power Plant with thermal energy storage intended for use in the Middle Eastern regions. Two representative sites in the Middle East which offer an annual average direct normal irradiance (DNI) of more than 5.5 kWh/m2/day has been chosen for the analysis. The thermodynamic aspect and annual performance of the proposed plant design is also analyzed using the System Advisor Model (SAM) version 2017.9.5. Based on the analysis carried out on the initial design, annual power generated from the proposed concentrating solar power (CSP) plant design in Abu Dhabi amounts to 333.15 GWh whereas that in Aswan recorded a value of 369.26 GWh, with capacity factors of 38.1% and 42.19% respectively. The mean efficiency of the plants in Abu Dhabi and Aswan are found to be 14.35% and 14.98% respectively. The optimization of the initial plant design is also carried out by varying two main design parameters, namely the solar multiple and full load hours of thermal energy storage (TES). Based on the findings of the study, the proposed 100 MW parabolic trough collector solar power plant with thermal energy storage can contribute to the sustainable energy future of the Middle East with reduced dependency on fossil fuels

X-Ray Photoelectron Spectroscopy Depth Profiling of As-Grown and Annealed Titanium Nitride Thin Films

Titanium nitride thin films were grown on Si(001) and fused silica substrates by radio frequency reactive magnetron sputtering. Post-growth annealing of the films was performed at different temperatures from 300 °C to 700 °C in nitrogen ambient. Films annealed at temperatures above 300 °C exhibit higher surface roughness, smaller grain size and better crystallinity compared to the as-grown film. Bandgap of the films decreased with the increase in the annealing temperature. Hall effect measurements revealed that all the films exhibit n-type conductivity and had high carrier concentration, which also increased slightly with the increase in the annealing temperature. A detailed depth profile study of the chemical composition of the film was performed by x-ray photoelectron spectroscopy confirming the formation of Ti-N bond and revealing the presence of chemisorbed oxygen in the films. Annealing in nitrogen ambient results in increased nitrogen vacancies and non-stoichiometric TiN films

X-Ray Photoelectron Spectroscopy Depth Profiling of As-Grown and Annealed Titanium Nitride Thin Films

Titanium nitride thin films were grown on Si(001) and fused silica substrates by radio frequency reactive magnetron sputtering. Post-growth annealing of the films was performed at different temperatures from 300 °C to 700 °C in nitrogen ambient. Films annealed at temperatures above 300 °C exhibit higher surface roughness, smaller grain size and better crystallinity compared to the as-grown film. Bandgap of the films decreased with the increase in the annealing temperature. Hall effect measurements revealed that all the films exhibit n-type conductivity and had high carrier concentration, which also increased slightly with the increase in the annealing temperature. A detailed depth profile study of the chemical composition of the film was performed by x-ray photoelectron spectroscopy confirming the formation of Ti-N bond and revealing the presence of chemisorbed oxygen in the films. Annealing in nitrogen ambient results in increased nitrogen vacancies and non-stoichiometric TiN films