1 research outputs found
Network Topology of the Interphase between Cross-Linked Polyurethane/Ethylene Propylene Diene Terpolymer Elastomers for Adhesion Applications
Understanding the interfacial phenomena involved in the
adhesion
between elastomer layers on a molecular basis is an important topic
from both fundamental and applied aspects. Nevertheless, this topic
has been poorly addressed experimentally. This report aims at rationalizing
differences in the adhesion behavior of polyurethane (PU) elastomers
cured on an ethylene–propylene–diene terpolymer (EPDM)
substrate, based on a detailed description of their local network-like
topology, determined thanks to 1H solid-state nuclear magnetic
resonance (NMR) spectroscopy. The polyurethanes, composed of the same
fraction of hydroxy-terminated poly(butadiene) and isophorone diisocyanate,
were cured under different reaction conditions: nature and concentration
of the catalyst as well as the cross-linking temperature. The rigid
domains formed by the hard segments, the proportion of elastically
active chains, and the distribution of the topological constraints
in the soft domains were investigated by 1H solid-state
NMR, taking advantage of the magic sandwich echoes and double quantum-based
experiments. The PU network topology within 20 μm thick slices
collected near the interface with the EPDM layer was systematically
compared to the one observed for 60 μm thick slices, located
500 μm from the interface, corresponding to the bulk regions.
Curing at a low temperature (30 °C) with a low amount of catalyst
(0.02 wt %) leads to elastically active poly(butadiene) chains close
to the interface with, on average, higher molecular weights between
topological constraints than the ones in the bulk. Such differences
between interfacial and bulk regions are not observed any longer as
the catalyst concentration is increased to 0.2 wt %. These variations
of the local PU network topology, occurring over several tens of micrometers,
allow one to account for the adhesion testing results