46 research outputs found

    An efficient and novel method for the synthesis of aromatic sulfones under solventfree conditions

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    237-239A manipulative simple and rapid reaction of arensulfonyl chloride with aromatic hydrocarbons is described. The reaction is conducted under Friedel-Crafts conditions in the absences of solvent using aluminium chloride as catalysts

    Oxidation of Alcohols with 1-Butyl-4-aza-1-azoniabicyclo[2.2.2]octane Chlorochromate (BAAOCC) under Nonaqueous Conditions.

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    577-5801-Butyl-4-aza-1-azoniabicyclo[2.2.2]octane chlorochromate (BAAOC) in the presence of AlCl3 affords an efficient and mild system for oxidation of a variety of alcohols, giving the corresponding aldehydes and ketones in refluxing acetonitrile. The experimental procedure is simple and the products are isolated straightforward in good to excellent yields.</i

    1-Benzyl-4-aza-1-azoniabicyclo[2.2.2]­octane tribromide as a regenerable and useful reagent for bromination of phenols under mild conditions

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    796-8001-Benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tribromide has been examined over several phenolic compounds under mild conditions. The reaction gives brominated phenols in good to excellent yields. Straightforward work-up of the reaction yields pure products in several cases.</b
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