7 research outputs found
OPTICAL SET-UP DEVELOPMENT AND SOFTWARE INTERFACE OF 2D-VISIBLE COHERENT SPECTROSCOPY EXPERIMENT TO INVESTIGATE DYNAMICS OF MULTI-CHROMOPHORIC MOLECULAR COMPLEXES
Be social, be agile: team engagement with Redmine
System engineering and project-team management are essential tools to ensure the project success and the
Redmine is a valuable platform for the work organization and for a system engineered approach. We review in
this work the management needs related to our project, and suggest the possibility that they fit to many research
activities with a similar scenario: small team, technical difficulties (or unknowns), intense activity sprints and
long pauses due to external schedule management, a large degree of shared leadership. We will then present
our implementation with the Redmine, showing that the use of the platform resulted in a strong engagement
and commitment of the team. The explicit goal of this work is also to rise, at least internally, the awareness
about team needs and available organizational tools and methods; and to highlight a shareable approach to team management and small scale system engineering
{Co4O4} and {CoxNi4–xO4} Cubane Water Oxidation Catalysts as Surface Cut-Outs of Cobalt Oxides
The future of artificial photosynthesis depends on economic and robust water oxidation catalysts (WOCs). Cobalt-based WOCs are especially promising for knowledge transfer between homogeneous and heterogeneous catalyst design. We introduce the active and stable {CoII4O4} cubane [CoII4(dpy{OH}O)4(OAc)2(H2O)2](ClO4)2 (Co4O4-dpk) as the first molecular WOC with the characteristic {H2O-Co2(OR)2-OH2} edge-site motif representing the sine qua non moiety of the most efficient heterogeneous Co-oxide WOCs. DFT-MD modelings as well as in situ EXAFS measurements indicate the stability of the cubane cage in solution. The stability of Co4O4-dpk under photocatalytic conditions ([Ru(bpy)3]2+/S2O82–) was underscored with a wide range of further analytical methods and recycling tests. FT-IR monitoring and HR-ESI-MS spectra point to a stable coordination of the acetate ligands, and DFT-MD simulations along with 1H/2H exchange experiments highlight a favorable intramolecular base functionality of the dpy{OH}O ligands. All three ligand types enhance proton mobility at the edge site through a unique bioinspired environment with multiple hydrogen-bonding interactions. In situ XANES experiments under photocatalytic conditions show that the {CoII4O4} core undergoes oxidation to Co(III) or higher valent states, which recover rather slowly to Co(II). Complementary ex situ chemical oxidation experiments with [Ru(bpy)3]3+ furthermore indicate that the oxidation of all Co(II) centers of Co4O4-dpk to Co(III) is not a mandatory prerequisite for oxygen evolution. Moreover, we present the [CoIIxNi4–x(dpy{OH}O)4(OAc)2(H2O)2](ClO4)2 (CoxNi4–xO4-dpk) series as the first mixed Co/Ni-cubane WOCs. They newly bridge homogeneous and heterogeneous catalyst design through fine-tuned edge-site environments of the Co centers
Pump-probe XAS investigation of the triplet state of an Ir photosensitizer with chromenopyridinone ligands
The triplet excited state of a new Ir-based photosensitizer with two chromenopyridinone and one bipyridine- based ligands has been studied by pump-probe X-ray absorption near edge structure (XANES) spectroscopy coupled with DFT calculations. The excited state has a lifetime of 0.5 mu s in acetonitrile and is characterized by very small changes of the local atomic structure with an average metal-ligand bond length change of less than 0.01 angstrom. DFT-based calculations allow the interpretation of the XANES in the energy range of similar to 50 eV around the absorption edge. The observed transient XANES signal arises from an additional metal-centered Ir 5d vacancy in the excited state which appears as a result of electron transfer from the metal to the ligand. The overall energy shift of the excited state spectrum originates from the shift of 2p and unoccupied states induced by screening effects. The approach for the analysis of timeresolved spectra of 5d metal complexes is quite general and can also be used if excited and ground state structures are significantly different
{Co<sub>4</sub>O<sub>4</sub>} and {Co<sub><i>x</i></sub>Ni<sub>4–<i>x</i></sub>O<sub>4</sub>} Cubane Water Oxidation Catalysts as Surface Cut-Outs of Cobalt Oxides
The
future of artificial photosynthesis depends on economic and robust
water oxidation catalysts (WOCs). Cobalt-based WOCs are especially
promising for knowledge transfer between homogeneous and heterogeneous
catalyst design. We introduce the active and stable {Co<sup>II</sup><sub>4</sub>O<sub>4</sub>} cubane [Co<sup>II</sup><sub>4</sub>(dpy{OH}O)<sub>4</sub>(OAc)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub> (<b>Co</b><sub><b>4</b></sub><b>O</b><sub><b>4</b></sub><b>-dpk</b>) as the first
molecular WOC with the characteristic {H<sub>2</sub>O-Co<sub>2</sub>(OR)<sub>2</sub>-OH<sub>2</sub>} edge-site motif representing the <i>sine qua non</i> moiety of the most efficient heterogeneous
Co-oxide WOCs. DFT-MD modelings as well as in situ EXAFS measurements
indicate the stability of the cubane cage in solution. The stability
of <b>Co</b><sub><b>4</b></sub><b>O</b><sub><b>4</b></sub><b>-dpk</b> under photocatalytic conditions ([Ru(bpy)<sub>3</sub>]<sup>2+</sup>/S<sub>2</sub>O<sub>8</sub><sup>2–</sup>) was underscored with a wide range of further analytical methods
and recycling tests. FT-IR monitoring and HR-ESI-MS spectra point
to a stable coordination of the acetate ligands, and DFT-MD simulations
along with <sup>1</sup>H/<sup>2</sup>H exchange experiments highlight
a favorable intramolecular base functionality of the dpy{OH}O ligands.
All three ligand types enhance proton mobility at the edge site through
a unique bioinspired environment with multiple hydrogen-bonding interactions.
In situ XANES experiments under photocatalytic conditions show that
the {Co<sup>II</sup><sub>4</sub>O<sub>4</sub>} core undergoes oxidation
to Co(III) or higher valent states, which recover rather slowly to
Co(II). Complementary ex situ chemical oxidation experiments with
[Ru(bpy)<sub>3</sub>]<sup>3+</sup> furthermore indicate that the oxidation
of all Co(II) centers of <b>Co</b><sub><b>4</b></sub><b>O</b><sub><b>4</b></sub><b>-dpk</b> to Co(III) is
not a mandatory prerequisite for oxygen evolution. Moreover, we present
the [Co<sup>II</sup><sub><i>x</i></sub>Ni<sub>4–<i>x</i></sub>(dpy{OH}O)<sub>4</sub>(OAc)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub> (<b>Co</b><sub><b>x</b></sub><b>Ni</b><sub><b>4–<i>x</i></b></sub><b>O</b><sub><b>4</b></sub><b>-dpk</b>) series as the first mixed Co/Ni-cubane WOCs. They newly
bridge homogeneous and heterogeneous catalyst design through fine-tuned
edge-site environments of the Co centers
{Co<sub>4</sub>O<sub>4</sub>} and {Co<sub><i>x</i></sub>Ni<sub>4–<i>x</i></sub>O<sub>4</sub>} Cubane Water Oxidation Catalysts as Surface Cut-Outs of Cobalt Oxides
The
future of artificial photosynthesis depends on economic and robust
water oxidation catalysts (WOCs). Cobalt-based WOCs are especially
promising for knowledge transfer between homogeneous and heterogeneous
catalyst design. We introduce the active and stable {Co<sup>II</sup><sub>4</sub>O<sub>4</sub>} cubane [Co<sup>II</sup><sub>4</sub>(dpy{OH}O)<sub>4</sub>(OAc)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub> (<b>Co</b><sub><b>4</b></sub><b>O</b><sub><b>4</b></sub><b>-dpk</b>) as the first
molecular WOC with the characteristic {H<sub>2</sub>O-Co<sub>2</sub>(OR)<sub>2</sub>-OH<sub>2</sub>} edge-site motif representing the <i>sine qua non</i> moiety of the most efficient heterogeneous
Co-oxide WOCs. DFT-MD modelings as well as in situ EXAFS measurements
indicate the stability of the cubane cage in solution. The stability
of <b>Co</b><sub><b>4</b></sub><b>O</b><sub><b>4</b></sub><b>-dpk</b> under photocatalytic conditions ([Ru(bpy)<sub>3</sub>]<sup>2+</sup>/S<sub>2</sub>O<sub>8</sub><sup>2–</sup>) was underscored with a wide range of further analytical methods
and recycling tests. FT-IR monitoring and HR-ESI-MS spectra point
to a stable coordination of the acetate ligands, and DFT-MD simulations
along with <sup>1</sup>H/<sup>2</sup>H exchange experiments highlight
a favorable intramolecular base functionality of the dpy{OH}O ligands.
All three ligand types enhance proton mobility at the edge site through
a unique bioinspired environment with multiple hydrogen-bonding interactions.
In situ XANES experiments under photocatalytic conditions show that
the {Co<sup>II</sup><sub>4</sub>O<sub>4</sub>} core undergoes oxidation
to Co(III) or higher valent states, which recover rather slowly to
Co(II). Complementary ex situ chemical oxidation experiments with
[Ru(bpy)<sub>3</sub>]<sup>3+</sup> furthermore indicate that the oxidation
of all Co(II) centers of <b>Co</b><sub><b>4</b></sub><b>O</b><sub><b>4</b></sub><b>-dpk</b> to Co(III) is
not a mandatory prerequisite for oxygen evolution. Moreover, we present
the [Co<sup>II</sup><sub><i>x</i></sub>Ni<sub>4–<i>x</i></sub>(dpy{OH}O)<sub>4</sub>(OAc)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub> (<b>Co</b><sub><b>x</b></sub><b>Ni</b><sub><b>4–<i>x</i></b></sub><b>O</b><sub><b>4</b></sub><b>-dpk</b>) series as the first mixed Co/Ni-cubane WOCs. They newly
bridge homogeneous and heterogeneous catalyst design through fine-tuned
edge-site environments of the Co centers
Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays
OLED technology beyond small or expensive devices requires light-emitters, luminophores, based on earth-abundant elements. Understanding and experimental verification of charge transfer in luminophores are needed for this development. An organometallic multicore Cu complex comprising Cu–C and Cu–P bonds represents an underexplored type of luminophore. To investigate the charge transfer and structural rearrangements in this material, we apply complementary pump-probe X-ray techniques: absorption, emission, and scattering including pump-probe measurements at the X-ray free-electron laser SwissFEL. We find that the excitation leads to charge movement from C- and P- coordinated Cu sites and from the phosphorus atoms to phenyl rings; the Cu core slightly rearranges with 0.05 Å increase of the shortest Cu–Cu distance. The use of a Cu cluster bonded to the ligands through C and P atoms is an efficient way to keep structural rigidity of luminophores. Obtained data can be used to verify computational methods for the development of luminophores.ISSN:2041-172