Corrosion polarization behavior and microstructuralanalysis of AA1070 aluminium silicon carbide matrix composites in acid chloride concentrations

The effect of SiC content and NaCl concentration on the corrosion resistance of AA1070 aluminium in 2 M H2SO4 was evaluated with potentiodynamic polarization technique, open circuit potential measurement (OCP) and optical microscopy. Results showed SiC increased the corrosion susceptibility of the alloy at lower NaCl concentrations compared to results obtained at 0% NaCl which showed significant decrease in corrosion rates, with maximum inhibition efficiency of 90.84% at 20% SiC content. The corrosion rates decreased at higher NaCl concentration,with maximum inhibition efficiency of 94.12 and 77.27% at 20% SiC. Alloy samples in 2 M H2SO4/0% NaCl at 0 and 20% SiC visibly decreased in OCP value over wide variation compared to samples with varying NaCl concentration due to loss of passivity. OCP values for alloys at varying NaCl concentration decreased over a very short variation due to repassivation. Statistical data showed silicon carbide to be the only relevant variable responsible for the corrosion rate values with F-values of 8.85 corresponding to a percentage significance of 54.8%. Optical images showed the presence of corrosion pits of smaller dimension, yet deeper on the morphology of the alloy without silicon carbide compared the alloy containing it, whose corrosion pits, seems wider but very shallo

Effect of Al2O3 Reinforcement and Precipitates on Corrosion Behaviour of 2618 and 6061 Aluminum MMCs

https://doi.org/https://doi.org/10.1080/1478422X.2019.1645802The corrosion resistance features of two different Metal Matrix Composites based on 6061 and 2618 aluminium alloys reinforced by 20% Al2O3 particles by stir casting process, were studied in 3.5% NaCl and compared. The composites and their respective base alloys were characterised in terms of microstructure by optical and scanning electron microscopy and in terms of corrosion resistance by polarisation curves and electrochemical impedance. Results show how the presence of Al2O3 has different effects depending on matrix composition. In 6061 MMC, Al2O3 promotes the formation of Mg2Si which has a cathodic behaviour altering the pitting susceptibility of the composite. In 2618 MMC, the high content of Cu induces a strong uniform attack. The subsequent increase in the Open Circuit Potential caused a pitting attack