21 research outputs found
A facile entry to macrocyclic disulfides: an efficient synthesis of redox-switched crown ethers
An interesting sulfur transfer reaction with benzyltriethylammonium tetrathiomolybdate has been used efficiently for the synthesis of macrocyclic disulfides. This methodology has been extended to a high-yield synthesis of ''redox-switched'' crown ethers which have potential application for selective ion transport across liquid membranes
Benzyltriethylammon Tetrathiomolybdate: An Improved Sulfur Transfer Reagent for the Synthesis of Disulfides
Benzyltriethylammonium tetrathiomolybdate has been found to be a superior reagent for the conversion of alkyl halides to the corresponding disulfides in chloroform at room temperature
Highly selective sulfur transfer reaction in the solid state
Benzyltriethylammonium tetrathiomolybdate 1 reacts readily with benzyl halides, alkyl iodides and acyl halides in the solid state to give the corresponding disulfides in good yields and with remarkable selectivity
ChemInform Abstract: Sodium Perborate/Acetic Anhydride: A Convenient Reagent for the Conversion of Cyclic Acetals to Esters
A facile oxidative cleavage of cyclic acetals to their respective esters using an inexpensive reagent system, sodium perborate/acetic anhydride is described
A Facile Conversion of Amides and Lactams to Thioamides and Thiolactams using Tetrathiomolybdate
Chloro iminium salts generated in situ from amides and lactams using or reacted very readily with the new sulfur transfer reagent, benzyltriethylammonium tetrathiomolybdate to afford the corresponding thioamides and thiolactams in exellent yields under mild reaction conditions
Reaction of Azides with Tetrathiomolybdate: Reduction and Imine Formation
This article does not have an abstract
Reductive dimerization of organic thiocyanates to disulfides mediated by tetrathiomolybdate
An interesting reductive dimerization of organic thiocyanates assisted by benzyltriethylammonium tetrathiomolybdate, [(PhCH(2)NEt(3))(2)MoS4], 1, leads to the formation of the corresponding disulfides in high yields
Interesting reaction of 2,2 '-binaphthol with 1,2-dibromoethane: Synthesis of a novel spirodienone
2,2'-Binaphthol 1 reacts with 1,2 dibromoethane in the presence of potassium carbonate to give rise to a novel spirodienone system 3 and its structure has been confirmed by X-ray analysis